Quantum control toward nano-carbon photonics in nano-carbon materials

• Project/Area Number: 23340085
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Condensed matter physics I
• Research Institution: Kyoto University
• Principal Investigator: MATSUDA Kazunari 京都大学, エネルギー理工学研究所, 教授 (40311435)
• Project Period (FY): 2011-04-01 – 2014-03-31
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000); Fiscal Year 2013: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000); Fiscal Year 2012: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000); Fiscal Year 2011: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
• Keywords: 光物性 / カーボンナノチューブ / グラフェン / 励起子 / 発光効率 / トリオン / グラフェンナノ構造

Research Abstract

Nano-carbon materials such as carbon nanotube, graphene, have intriguing electronic and optical properties. In this study, we studied the quantum optical properties of nano-carbon materials toward novel functionalites. We obtained the results, 1) first observation of negative charged exciton (trion) in carbon nanotube by electrochemical doping technique, 2) revealing spatial localization trion with 0-dimensional characteristics, 3) drastic enhancement of photoluminescence quantum yield up to 18%.

Research Products

• [Journal Article] Brightening of excitons in carbon nanotubes on dimensionality modification (2013)
  • Author(s): Y. Miyauchi, M. Iwamura, S. Mouri, T. Kawazoe, M. Ohtsu, and K. Matsuda
  • Journal Title: Nat. Photonics Volume: 6 Pages: 715-719
  • NAID: 120005439161
  • URL: http://www.nature.com/nphoton/journal/v7/n9/abs/nphoton.2013.179.html
  • Peer Reviewed
• [Journal Article] Tunable photoluminescence of monolayer MoS_2 via chemical doping (2013)
  • Author(s): S. Mouri, Y. Miyauchi, and K. Matsuda
  • Journal Title: Nano Lett Volume: 13 Issue: 12 Pages: 5944-5948
  • DOI: 10.1021/nl403036h
  • Peer Reviewed
• [Journal Article] Temperature dependence of photoluminescence spectra in hole-doped single-walled carbon nanotubes: Implications of trion localization (2013)
  • Author(s): 毛利真一郎、宮内雄平、松田一成
  • Journal Title: Physical Revew B 誌 Volume: 87巻 Issue: 4 Pages: 45408-45412
  • DOI: 10.1103/physrevb.87.045408
  • Peer Reviewed
• [Journal Article] Exploring the origin of blue and ultraviolet fluorescence in graphene oxide (2013)
  • Author(s): D. Kozawa, S. Mouri, Y. Miyauchi, and K. Matsuda
  • Journal Title: J. Phys. Chem. Lett Volume: 4 Issue: 12 Pages: 2035-2040
  • DOI: 10.1021/jz400930f
  • Peer Reviewed
• [Journal Article] Rapid single-stage separation of micrometer-long and high-purity semiconducting carbon nanotubes by gel filtration (2013)
  • Author(s): B. Thendie, Y. Miyata, R. Kitaura, Y. Miyauchi, K. Matsuda, and H. Shinohara
  • Journal Title: Appl. Phys. Express Volume: 6 Pages: 65101-65101
  • NAID: 10031181984
  • URL: http://apex.jsap.jp/link?APEX/6/065101/
  • Peer Reviewed
• [Journal Article] Enhancement Mechanism of the Photovoltaic Conversion Efficiency of Single-Walled Carbon Nanotube/Si Solar Cells by HNO_3 Doping (2013)
  • Author(s): F. Wang, D. Kozawa, Y. Miyauchi, K. Hiraoka, S. Mouri, and K. Matsuda
  • Journal Title: Appl. Phys. Express Volume: 6 Pages: 102301-102301
  • URL: http://apex.jsap.jp/link?APEX/6/102301/
  • Peer Reviewed
• [Journal Article] Raman spectroscopy investigations of chemically derived zigzag edge graphene nanoribbons (2013)
  • Author(s): R. Nishinakagawa, K. Matsuda, T. Arai, A. Sawada, and T. Terashima
  • Journal Title: AIP Advances Volume: 3 Issue: 9 Pages: 92111-92111
  • DOI: 10.1063/1.4821281
  • Peer Reviewed
• [Journal Article] Changing photoluminescence spectra of graphene oxide by centrifugation treatments (2013)
  • Author(s): D. Kozawa, Y. Miyauchi, S. Mouri, and K. Matsuda
  • Journal Title: Phys. Stat. Solid. (c) Volume: 10 Issue: 11 Pages: 1600-1603
  • DOI: 10.1002/pssc.201300232
  • Peer Reviewed
• [Journal Article] Brightening of excitons in carbon nanotubes on dimensionality modification (2013)
  • Author(s): Y. Miyauchi, M. Iwamura, S. Mouri, T. Kawazoe, M. Ohtsu, and K. Matsuda
  • Journal Title: Nat. Photonics Volume: 6 Pages: 715-719
  • NAID: 120005439161
  • Peer Reviewed
• [Journal Article] Enhancement Mechanism of the Photovoltaic Conversion Efficiency of Single-Walled Carbon Nanotube/Si Solar Cells by HNO3 Doping (2013)
  • Author(s): F. Wang, D. Kozawa, Y. Miyauchi, K. Hiraoka, S. Mouri, and K. Matsuda
  • Journal Title: Appl. Phys. Express Volume: 6 Pages: 162301-162301
  • Peer Reviewed
• [Journal Article] Suppression of exciton-electron scattering in doped single-walled carbon nanotubes (2012)
  • Author(s): S. Konabe, K. Matsuda, and S. Okada
  • Journal Title: Phys. Rev. Lett Volume: 109 Issue: 18 Pages: 187403-187403
  • DOI: 10.1103/physrevlett.109.187403
  • Peer Reviewed
• [Journal Article] Observation of negative and positive trions in theelectrochemically carrier-doped single-walled carbon nanotubes (2012)
  • Author(s): パク・ジンスン、平兮 康彦、毛利真一郎、宮内雄平、中島直敏、松田一成
  • Journal Title: Jounal of AmericanChemical Society Volume: 134巻 Issue: 35 Pages: 14461-14466
  • DOI: 10.1021/ja304282j
  • Peer Reviewed
• [Journal Article] Dispersion-process effects on the photoluminescence quantum yields of single-walled carbon nanotubes dispersed using aromatic polymers (2012)
  • Author(s): 毛利真一郎、宮内雄平、松田一成
  • Journal Title: Jounal of Physical Chemistry C Volume: 116巻 Issue: 18 Pages: 10282-10286
  • DOI: 10.1021/jp212040y
  • Peer Reviewed
• [Journal Article] Exciton-hole interactions in hole-doped single-walled carbon nanotubes evaluated by absorption spectral changes (2012)
  • Author(s): Shinichiro Mouri
  • Journal Title: Jounal of Applied Physics Volume: 111 Issue: 9 Pages: 943091-943093
  • DOI: 10.1063/1.4710532
  • Peer Reviewed
• [Journal Article] Analysis of the photovoltaic properties of single-walled carbon nanotube/silicon heterojunction solar cells (2012)
  • Author(s): D. Kozawa, K. Hiraoka, Y. Miyauchi, S. Mouri, and K. Matsuda
  • Journal Title: Appl. Phys. Express Volume: 5 Pages: 42304-42304
  • NAID: 10030592800
  • URL: http://iopscience.iop.org/1882-0786/5/4/042304/
  • Peer Reviewed
• [Journal Article] Analysis of the photovoltaic properties of single-walled carbon nanotube/silicon heterojunction solar cells (2012)
  • Author(s): Daichi Kozawa, et al
  • Journal Title: Applied Physics Express Volume: 5
  • Peer Reviewed
• [Journal Article] Dispersion-process effects on the photoluminescence quantum yields of single-walled carbon nanotubes dispersed using aromatic polymers (2012)
  • Author(s): Shinichiro Mouri, et al
  • Journal Title: Journal of Physical Chemistry C
  • Peer Reviewed
• [Journal Article] Raman study on the interlayer interactions and the band structure of bilayer graphene synthesized by alcohol chemical vapor deposition (2011)
  • Author(s): Makoto Okano, et al
  • Journal Title: Applied Physics Letters Volume: 99 Issue: 15
  • DOI: 10.1063/1.3651325
  • Peer Reviewed
• [Presentation] ナノカーボン物質・単原子層物質の顕微蛍光イメージング・分光 (2013)
  • Author(s): 松田一成
  • Organizer: 第78回表面科学研究会
  • Place of Presentation: 東京
  • Year and Date: 2013-10-18
• [Presentation] Nano-carbon optics (2013)
  • Author(s): K. Matsuda
  • Organizer: fundamental physics and application of nano-carbon materials JSAP-MRS Joint Symposia
  • Place of Presentation: Kyoto, Japan
  • Year and Date: 2013-09-19
• [Presentation] 酸化グラフェンの青色・紫外発光のメカニズム (2013)
  • Author(s): 小澤大知, 宮内雄平, 毛利真一郎, 松田一成
  • Organizer: 酸化グラフェンシンポジウム
  • Place of Presentation: 熊本
  • Year and Date: 2013-08-06
• [Presentation] Novel excitonic properties of nano-carbon materials studied by advanced optical spectroscopy (2013)
  • Author(s): K. Matsuda
  • Organizer: The 12th Asia Pacific Physics Conference of APPS (APPC12)
  • Place of Presentation: Makuhari, Japan
  • Year and Date: 2013-07-18
• [Presentation] Excitonic properties of carrier-doped single-walled carbon nanotubes arise from negative and positive trions (2013)
  • Author(s): K. Matsuda
  • Organizer: Workshop of Nanotube Optics and Nanospectroscopy (WONTON'13)
  • Place of Presentation: Santa Fe, USA
  • Year and Date: 2013-06-19
• [Presentation] Novel optical properties of nano-carbon materials (2013)
  • Author(s): K. Matsuda
  • Organizer: New Diamond and Nano Carbons Conference 2013 (NDNC2013)
  • Place of Presentation: Singapore
  • Year and Date: 2013-05-23
• [Presentation] Study of negative and positive trions in the electrochemically carrier-doped single-walled carbon nanotubes (2013)
  • Author(s): K. Matsuda, and Y. Miyauchi
  • Organizer: 223rd The Electrochemical Society (ECS) Meeting
  • Place of Presentation: Tronto, Canada
  • Year and Date: 2013-05-13
• [Presentation] ナノカーボン物質におけるナノ光機能とその応用 (2013)
  • Author(s): 松田一成
  • Organizer: 応用物理学会春季学術講演会
  • Place of Presentation: 神奈川
  • Year and Date: 2013-03-27
• [Presentation] ナノカーボン物質におけるナノ光機能とその応用 (2013)
  • Author(s): 松田一成
  • Organizer: 応用物理学術講演会
  • Place of Presentation: 神奈川工科大学
  • Invited
• [Presentation] ナノカーボン物質のナノ光科学とその応用 (2012)
  • Author(s): 松田一成
  • Organizer: 第2回光科学異分野横断萌芽研究会
  • Place of Presentation: 岡崎
  • Year and Date: 2012-08-06
• [Presentation] ナノカーボン物質のナノ光科学とその応用 (2012)
  • Author(s): 松田一成
  • Organizer: 第2回光科学異分野横断萌芽研究会
  • Place of Presentation: 岡崎コンファレンスセンター
  • Invited
• [Presentation] Study of excitonic properties in carbon nanotubes toward nano-carbon photonics (2011)
  • Author(s): Kazunari Matsuda
  • Organizer: JSPS Japan-France Nano-photonics seminar
  • Place of Presentation: Toba Hotel International (Mie)(招待講演)
  • Year and Date: 2011-11-09
• [Presentation] Novel excitonic properties of carbon nanotubes toward nano-carbon optics (2011)
  • Author(s): Kazunari Matsuda
  • Organizer: 17th Microoptics Conference
  • Place of Presentation: Sendai International Center (Miyagi)
  • Year and Date: 2011-10-31
• [Presentation] Nano-carbon photonics : fudamental physics and application of carbon nanotube (2011)
  • Author(s): Kazunari Matsuda
  • Organizer: JSPS Japan-Germany Nano-photonics seminar
  • Place of Presentation: Kyoto University (Kyoto)(招待講演)
  • Year and Date: 2011-09-26
• [Presentation] ナノカーボン物質の電子物性と光電変換機能 (2011)
  • Author(s): 松田一成
  • Organizer: 第7回有機太陽電池シンポジウム
  • Place of Presentation: Kyoto University (Kyoto)(招待講演)
  • Year and Date: 2011-07-15
• [Presentation] ナノカーボン・フォトニクスに向けて:ナノカーボン物質のナノ光科学 (2011)
  • Author(s): 松田一成
  • Organizer: 平成23年度先端領域若手研究リーダー育成拠点
  • Place of Presentation: 山科大学サイエンスカフェ(山梨県)(招待講演)
  • Year and Date: 2011-07-06
• [Presentation] ナノカーボン物質におけるナノ光科学とその応用 (2011)
  • Author(s): 松田一成
  • Organizer: 北海道大学大学院工学研究院応用物理学部門講演会
  • Place of Presentation: 北海道大学(北海道)(招待講演)
  • Year and Date: 2011-06-11
• [Presentation] ナノカーボン, 単原子層物質の光科学とその応用
  • Author(s): 松田一成
  • Organizer: 日本化学会年会
  • Place of Presentation: 名古屋大学（名古屋市）
  • Invited
• [Presentation] ナノカーボンの光学特性とその応用
  • Author(s): 松田一成
  • Organizer: 新無機膜研究会第72回研究会
  • Place of Presentation: 龍谷大学大阪キャンパス（大阪府）
  • Invited
• [Presentation] カーボンナノチューブ・ナノグラフェンのナノ光科学とその応用
  • Author(s): 松田一成
  • Organizer: ニューダイアモンドフォーラム研究会
  • Place of Presentation: 東京大学（東京都）
  • Invited
• [Presentation] Nano-carbon optics:fundamental physics and application of nano-carbon materials
  • Author(s): K. Matsuda
  • Organizer: JSAP-MRS Joint Symposia
  • Place of Presentation: Kyoto, Japan
  • Invited
• [Presentation] Novel excitonic properties of nano-carbon materials studied by advanced optical spectroscopy
  • Author(s): K. Matsuda
  • Organizer: The 12th Asia Pacific Physics Conference of AAPPS (APPC12)
  • Place of Presentation: Makuhari, Chiba, Japan
  • Invited
• [Presentation] ナノカーボン物質・単原子層物質の顕微蛍光イメージング・分光
  • Author(s): 松田一成
  • Organizer: 第78回表面科学研究会
  • Place of Presentation: 東京工業大学（東京都)
  • Invited
• [Presentation] ナノカーボン, 単原子層物質のナノ光科学とその応用
  • Author(s): 松田一成
  • Organizer: フラーレン・ナノチューブ・グラフェン学会若手研究会
  • Place of Presentation: 大阪大学（大阪府）
  • Invited
• [Presentation] ナノカーボン物質におけるナノ光科学とその応用
  • Author(s): 松田一成
  • Organizer: 九州大学リーディングセミナー
  • Place of Presentation: 九州大学（福岡県）
  • Invited
• [Book] グラフェンナノリボンを用いた赤外光領域におけるプラズモニクス分光研究, トピックス62-4号 (2013)
  • Author(s): 小澤大知, 松田一成
• [Book] カーボンナノチューブの発光効率の向上に成功, 化学 (2013)
  • Author(s): 宮内雄平, 松田一成