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Renaissance of high-Tc superconductivity - Undoped cuprates are a Mott insulator?

Research Project

Project/Area Number 23340098
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

NAITO Michio  東京農工大学, 工学(系)研究科(研究院), 教授 (40155643)

Co-Investigator(Kenkyū-buntansha) UEDA Shinya  東京農工大学, 大学院・工学研究院, 助教 (60442729)
Co-Investigator(Renkei-kenkyūsha) OYANAGI Hiroyuki  産業技術総合研究所, 光技術研究部門, 主幹研究員 (00344432)
YAMAMOTO Hideki  日本電信電話株式会社NTT物性科学基礎研究所, 機能物質科学研究部, 主幹研究員 (70393733)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥19,760,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥4,560,000)
Fiscal Year 2013: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Fiscal Year 2011: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Keywords高温超伝導 / モット絶縁体 / MBE、エピタキシャル / 銅酸化物 / 母物質超伝導 / 母物質超伝導体 / 強相関電子系 / 超伝導材料・素子
Research Abstract

It has been believed for a long time that high-Tc superconductivity in cuprates develops only upon doping holes or electrons in the parent antiferromagnetic Mott insulators. Recently, however, we discovered that T'-RE2CuO4 becomes superconducting without doping. The purpose of this research project is to establish superconductivity in the true "undoped" state of T'-RE2CuO4 and thereby to renovate the previous "doped Mott-insulator" scenario for high-Tc superconductivity. In the course of the research, we achieved, for the first time, superconductivity in bulk samples of undoped T'-La2-xSmxCuO4, which was synthesized via a molten alkaline hydroxide route. The bulk nature of superconductivity was also confirmed by low-energy muSR. Furthermore the systematic comparison of the Hall effect and upper critical fields between undoped T'-RE2CuO4 and electron-doped T'-(RE,Ce)2CuO4 revealed no discontinuity with doping, leading to the conclusion that both are in the same ground state.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (53 results)

All 2014 2013 2012 2011 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (36 results) (of which Invited: 1 results) Book (4 results) Remarks (1 results)

  • [Journal Article] Bulk superconductivity in undoped T′-La1.9Y0.1CuO4 probed by muon spin rotation2014

    • Author(s)
      K. M. Kojima, Y. Krockenberger, I. Yamauchi, M. Miyazaki, M. Hiraishi, A. Koda, R. Kadono, R. Kumai, H. Yamamoto, A. Ikeda, and M. Naito
    • Journal Title

      Physical Review B

      Volume: 89 Issue: 18 Pages: 1805081-1805085

    • DOI

      10.1103/physrevb.89.180508

    • Related Report
      2013 Final Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Improved conductivity of infinite-layer LaNiO_2 thin films by metal organic decomposition2013

    • Author(s)
      Ai Ikeda, Takaaki Manabe, Michio Naito
    • Journal Title

      Physica C

      Volume: 495 Pages: 134-140

    • DOI

      10.1016/j.physc.2013.09.007

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multi-source MBE with high-precision rate control system as a synthesis method sui generis for multi-cation metal oxides2013

    • Author(s)
      H. Yamamoto, Y. Krockenberger, M. Naito
    • Journal Title

      Journal of Crystal Growth

      Volume: 378 Pages: 184-188

    • DOI

      10.1016/j.jcrysgro.2012.12.057

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Emerging superconductivity hidden beneath charge-transfer insulators2013

    • Author(s)
      Y. Krockenberger, H. Irie, O. Matsumoto, K. Yamagami, M. Mitsuhashi, A. Tsukada, M. Naito, H. Yamamoto
    • Journal Title

      Scientific Reports

      Volume: 3 Issue: 1

    • DOI

      10.1038/srep02235

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] RE dependence of superconductivity in parent T'-RE_2CuO_4 - implication on the nature of superconductivity2013

    • Author(s)
      M. Naito, A. Ikeda, T. Manabe
    • Journal Title

      MRS Proceedings

      Volume: vol.1434

    • DOI

      10.1557/opl.2012.1316

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multi-source MBE with high-precision rate control system as a synthesis method sui generis for multi-cation metal oxides2013

    • Author(s)
      H. Yamamoto, Y. Krockenberger, M. Naito
    • Journal Title

      J. Cryst. Growth

      Volume: in press

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unconventional transport and superconducting properties in electron-doped cuprates2012

    • Author(s)
      Y. Krockenberger, H. Yamamoto, A. Tsukada, M. Mitsuhashi, M. Naito
    • Journal Title

      Physical Review

      Volume: 85 Issue: 18

    • DOI

      10.1103/physrevb.85.184502

    • Related Report
      2013 Final Research Report 2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Universal Superconducting Ground State in Nd_<1.85>Ce_<0.15>CuO_4 and Nd_2CuO_42012

    • Author(s)
      Y. Krockenberger, H. Yamamoto, M. Mitsuhashi, M. Naito
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 51 Issue: 1R Pages: 010106-010106

    • DOI

      10.1143/jjap.51.010106

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Temperature dependence of the London penetration depth in Pr_2CuO_4 from millimeter-wave optical experiments2012

    • Author(s)
      A.V.Pronin, T.Fischer, J.Wosnitza, A.Ikeda, M.Naito
    • Journal Title

      Physica C

      Volume: 473 Pages: 11-13

    • DOI

      10.1016/j.physc.2011.11.006

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] XAS study of superconducting thin film single crystals without doping2012

    • Author(s)
      H.Ohyanagi, A.Tsukaad, M.Naito
    • Journal Title

      Proceeding of SPIE

      Volume: 8,263 Pages: 82631F-82631F

    • DOI

      10.1117/12.915983

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Superconductivity in bulk T'-(La,Sm)_2CuO_4 prepared via a molten alkaline hydroxide route2011

    • Author(s)
      S. Asai, S. Ueda, M. Naito
    • Journal Title

      Physica C

      Volume: 471 Issue: 21-22 Pages: 682-685

    • DOI

      10.1016/j.physc.2011.05.026

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] RE dependence of superconductivity in parent T'-RE_2CuO_42011

    • Author(s)
      A. Ikeda, O. Matsumoto, H. Yamamoto, T. Manabe, M. Naito
    • Journal Title

      Physica C

      Volume: 471 Issue: 21-22 Pages: 686-689

    • DOI

      10.1016/j.physc.2011.05.027

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] T*型214銅酸化物薄膜の低エネルギーμSR測定2014

    • Author(s)
      小嶋健児, 平石雅俊, 宮崎正範, 幸田章宏, 門野良典, Andreas Suter, Hubertus Luetkens, Yoshi Krockenberger, 山本秀樹, 池田愛, 内藤方夫
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学
    • Year and Date
      2014-03-27
    • Related Report
      2013 Final Research Report
  • [Presentation] 各種還元法により合成した無限層構造 LaNiO_2薄膜の比較2014

    • Author(s)
      池田愛, 真部高明, 内藤方夫
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学
    • Year and Date
      2014-03-18
    • Related Report
      2013 Final Research Report
  • [Presentation] 各種還元法により合成した無限層構造LaNiO2薄膜の比較2014

    • Author(s)
      池田 愛,真部高明,内藤方夫
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Supression of metal-insulator transition in PrNiO_3 by epitaxial strain2013

    • Author(s)
      A. Ikeda, T. Manabe, M. Naito
    • Organizer
      International Symposium on Superconductivity (ISS2013)
    • Place of Presentation
      Tokyo
    • Year and Date
      2013-11-20
    • Related Report
      2013 Final Research Report
  • [Presentation] 無限層構造Sr_<1-x>La_xCuO_2 (x≦0.05)薄膜の抵抗率異常2013

    • Author(s)
      七尾美子, 池田愛, 内藤方夫
    • Organizer
      第74回応用物理学会春季学術講演会
    • Place of Presentation
      同志社大学
    • Year and Date
      2013-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] 無限層構造LaNiO_2作製に向けた高品位ペロブスカイトLaNiO_3薄膜の作製2013

    • Author(s)
      池田愛, 真部高明, 内藤方夫
    • Organizer
      第74回応用物理学会春季学術講演会
    • Place of Presentation
      同志社大学
    • Year and Date
      2013-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] 無限層構造LaNiO_2薄膜の金属的ふるまい2013

    • Author(s)
      池田愛, 真部高明, 内藤方夫
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      2013-03-27
    • Related Report
      2013 Final Research Report
  • [Presentation] T' 型銅酸化物ノンドープ薄膜のバルク超伝導と表面磁性2013

    • Author(s)
      小嶋健児, 門野良典, 平石雅俊, 宮崎正範, 幸田章宏, Andreas Suter, Hubertus Luetkens, Yoshiharu Krockenberger, 山本秀樹, 池田愛, 内藤方夫
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Year and Date
      2013-03-27
    • Related Report
      2013 Final Research Report
  • [Presentation] 無限層構造LaNiO2作製に向けた高品位ペロブスカイトLaNiO3薄膜の作製2013

    • Author(s)
      池田 愛,真部高明,内藤方夫
    • Organizer
      第74回応用物理学会春季学術講演会
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 無限層構造Sr1-xLaxCuO2 (x ≦ 0.05)薄膜の抵抗率異常2013

    • Author(s)
      七尾美子,池田愛,内藤方夫
    • Organizer
      第74回応用物理学会春季学術講演会
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Supression of metal-insulator transition in PrNiO3 by epitaxial strain2013

    • Author(s)
      Ai Ikeda, Takaaki Manabe, and Michio Naito
    • Organizer
      26th International Symposium on Superconductivity (ISS2013)
    • Place of Presentation
      船堀ホール
    • Related Report
      2013 Annual Research Report
  • [Presentation] Development of new superconductors tailored by MBE2013

    • Author(s)
      H. Yamamoto, Y. Krockenberger, M. Naito
    • Organizer
      Electronic Materials and Applications 2013 (EMA2013)
    • Place of Presentation
      Orlando, USA, Double Tree by Hilton Orlando at Sea World.
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 無限層構造LaNiO2の金属的ふるまい2013

    • Author(s)
      池田 愛,真部高明,内藤方夫
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] T’型銅酸化物ノンドープ薄膜のバルク超伝導と表面磁性2013

    • Author(s)
      小嶋健児、門野良典、平石雅俊、宮崎正範、幸田章宏、Andreas Suter、Hubertus Luetkens、Yoshiharu Krockenberger、山本秀樹、池田愛、内藤方夫
    • Organizer
      第68回物理学会年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Infinite-layer LaNiO_2 Metallic oxide with square-planar coordination2012

    • Author(s)
      A. Ikeda, T. Manabe, M. Naito
    • Organizer
      International Symposium on Superconductivity (ISS2012)
    • Place of Presentation
      Tokyo
    • Year and Date
      2012-12-05
    • Related Report
      2013 Final Research Report
  • [Presentation] The signification of doping in square planar coordinated cuprates2012

    • Author(s)
      クロッケンバーガー賢治, 山本秀樹, 三橋将也, 内藤方夫
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2012-09-12
    • Related Report
      2013 Final Research Report
  • [Presentation] 水素還元及び酸素アニールによるT'-Ln_2CuO_4薄膜の合成2012

    • Author(s)
      池田愛, 山本秀樹, 真部高明, 内藤方夫
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2012-09-12
    • Related Report
      2013 Final Research Report
  • [Presentation] T'-La_2CuO_4の低温合成と超伝導化2012

    • Author(s)
      浅井翔太, 上田真也, 内藤方夫
    • Organizer
      第59回応用物理学会関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-16
    • Related Report
      2013 Final Research Report
  • [Presentation] スパッタリング法による無限層構造SrCuO_2薄膜の配向制御2012

    • Author(s)
      大田広大, 池田愛, 山崎圭介, 内藤方夫
    • Organizer
      第59回応用物理学会関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-16
    • Related Report
      2013 Final Research Report
  • [Presentation] 基板による無限層構造LaNiO_2薄膜の配向制御2012

    • Author(s)
      池田愛, 内藤方夫
    • Organizer
      第59回応用物理学会関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-16
    • Related Report
      2013 Final Research Report
  • [Presentation] 基板による無限層構造LaNiO_2薄膜の配向制御2012

    • Author(s)
      池田愛、内藤方夫
    • Organizer
      第59回応用物理関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] スパッタリング法による無限層構造SrCuO_2薄膜の配向制御2012

    • Author(s)
      大田広大、池田愛、山崎圭介、内藤方夫
    • Organizer
      第59回応用物理関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] T'-La_2CuO_4の低温合成と超伝導化2012

    • Author(s)
      浅井翔太、上田真也、内藤方夫
    • Organizer
      第59回応用物理関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Infinite-layer LaNiO2 Metallic oxide with square-planar coordination2012

    • Author(s)
      A. Ikeda, T. Manabe, M. Naito
    • Organizer
      25th International Symposium on Superconductivity (ISS2012)
    • Place of Presentation
      Tokyo, Funabori Hall.
    • Related Report
      2012 Annual Research Report
  • [Presentation] Multi-source MBE with high-precision rate control system as a synthesis method sui generis for multi-cation metal oxides2012

    • Author(s)
      H. Yamamoto, Y. Krockenberger, M. Naito
    • Organizer
      17th International Conference on Molecular Beam Epitaxy (MBE2012)
    • Place of Presentation
      Nara, Nara Prefectural New Public Hall.
    • Related Report
      2012 Annual Research Report
  • [Presentation] RE dependence of superconductivity in parent T’-RE 2CuO4 - implication on the nature of superconductivity2012

    • Author(s)
      M. Naito, A. Ikeda, H. Yamamoto, T. Manabe
    • Organizer
      2012 MRS Spring Meeting
    • Place of Presentation
      San Francisco, USA, Moscone West Convention Center.
    • Related Report
      2012 Annual Research Report
  • [Presentation] Nd2-xCexCuO4 and Nd2CuO4: Differences and commons in square planar coordinated cuprate superconductors2012

    • Author(s)
      Y. Krockenberger, H. Yamamoto, M. Mitsuhashi, M. Naito
    • Organizer
      10th International Conference on Materials and Mechanisms of Superconductivity (M2S-X)
    • Place of Presentation
      Washington DC, USA, Omni Shoreham Hotel.
    • Related Report
      2012 Annual Research Report
  • [Presentation] 水素還元及び酸素アニールによるT'-Ln2CuO4薄膜の合成2012

    • Author(s)
      池田 愛,山本秀樹,真部高明,内藤方夫
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Ag-assisted low-temperature synthesis of T'-La_2CuO_4 films by metal organic decomposition2011

    • Author(s)
      A. Ikeda, H. Yamamoto, T. Manabe, M. Naito
    • Organizer
      International Symposium on Superconductivity (ISS2011)
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-10-26
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation of superconducting Pr_2CuO_4 and Nd_2CuO_4 by molecular beam epitaxy2011

    • Author(s)
      H. Yamamoto, Y. Krockenberger, M. Mistuhashi, K. Yamagami, M. Naito
    • Organizer
      International Symposium on Superconductivity (ISS2011)
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-10-26
    • Related Report
      2013 Final Research Report
  • [Presentation] T '型ノンドープ薄膜超伝導体の低エネルギーμ SR測定2011

    • Author(s)
      小嶋健児, 平石雅俊, 宮崎正範, 幸田章宏, 門野良典, Andreas Suter , Hubertus Luetkens , Yoshi Krockenberger ,山本秀樹,池田愛,内藤方夫
    • Organizer
      日本物理学会 2011年秋季大会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-22
    • Related Report
      2013 Final Research Report
  • [Presentation] T'-La_2CuO_4塗布膜のAg添加効果2011

    • Author(s)
      池田愛, 山本秀樹, 真部高明, 内藤方夫
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-09-01
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] MBE 薄膜の精密アニールによる母物質超伝導体RE2CuO4 の合成(5)2011

    • Author(s)
      山本秀樹, クロッケンバーガー賢治, 三橋将也, 松本理, 内藤方夫
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-09-01
    • Related Report
      2013 Final Research Report
  • [Presentation] T'-銅酸化物における普遍的な超伝導性2011

    • Author(s)
      クロッケンバーガー賢治, 山本秀樹, 束田昭雄, 三橋将也, 内藤方夫
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-09-01
    • Related Report
      2013 Final Research Report
  • [Presentation] 超伝導現象2011

    • Author(s)
      内藤方夫
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-08-30
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] RE dependence of superconductivity in parent T'-RE_2CuO_4 - implication on the nature of superconductivity

    • Author(s)
      M. Naito, A. Ikeda, H. Yamamoto and T. Manabe
    • Organizer
      2012 MRS Spring Meeting
    • Place of Presentation
      San Francisco
    • Related Report
      2013 Final Research Report
  • [Book] 高温超伝導体(上)-物質と物理-第二版2014

    • Author(s)
      内藤方夫
    • Publisher
      応用物理学会
    • Related Report
      2013 Final Research Report
  • [Book] 超伝導現象と高温超伝導体2013

    • Author(s)
      内藤方夫
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2013 Final Research Report
  • [Book] 「超伝導現象と高温超伝導体」、p.1-p.432013

    • Author(s)
      内藤 方夫(共著)
    • Total Pages
      504
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2012 Annual Research Report
  • [Book] Magnetic mechanism of superconductivity in copper-oxide(edited by D. Das)2011

    • Author(s)
      H. Sato, A. Tsukada, Y. Krockenberger, H. Yamamoto, M. Naito
    • Publisher
      Nova Science Publishers, Inc., New York
    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~naitolab/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-04-06   Modified: 2020-05-15  

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