| Budget Amount *help |
¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2013: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2012: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
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| Outline of Final Research Achievements |
We have investigated the development of new and clean synthetic methodologies by using photochemical processes without aid of metal catalysts.
Photochemical generation of carbenes, highly reactive intermediates, from acylsilanes has scarcely been employed for organic synthesis, so far. In this project, we examined application of this photochemical process to organic reactions with appropriate design of reaction systems and succeeded in developing several useful and original synthetic reactions.
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