Development of new synthetic methodologies based on photochemical carbene formation reaction
Project/Area Number |
23350016
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic chemistry
|
Research Institution | Gakushuin University (2013) Tokyo Institute of Technology (2011-2012) |
Principal Investigator |
|
Project Period (FY) |
2011-04-01 – 2015-03-31
|
Project Status |
Completed (Fiscal Year 2014)
|
Budget Amount *help |
¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2013: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2012: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
|
Keywords | カルベン / 光反応 / 炭素骨格形成反応 / アシルシラン / 光異性化 / カップリング / 有機ホウ素化合物 / クロスカップリング / イリド / 付加環化 / ボロン酸 |
Outline of Final Research Achievements |
We have investigated the development of new and clean synthetic methodologies by using photochemical processes without aid of metal catalysts. Photochemical generation of carbenes, highly reactive intermediates, from acylsilanes has scarcely been employed for organic synthesis, so far. In this project, we examined application of this photochemical process to organic reactions with appropriate design of reaction systems and succeeded in developing several useful and original synthetic reactions.
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Report
(4 results)
Research Products
(31 results)