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Double Laser Analysis of Emissive Biracials and Development of "Organic Radical Light-Emitting Diode"

Research Project

Project/Area Number 23350023
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionOsaka Prefecture University

Principal Investigator

IKEDA HIROSHI  大阪府立大学, 工学(系)研究科(研究院), 教授 (30211717)

Research Collaborator MATSUI Yasunori  大阪府立大学, 工学研究科, 博士研究員
KIDO Taiki  大阪府立大学, 工学研究科, 大学院生
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000)
Fiscal Year 2013: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2012: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2011: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Keywordsπ電子 / ラジカル / 光反応 / 電子移動反応 / 有機EL / 反応機構 / ラジカルカチオン / 熱発光 / エネルギー移動反応 / 有機EL / 熱ルミネッセンス
Research Abstract

Accurate evaluation of fluorescence properties of the trimethylenemethane (TMM) biradicals is one of the inevitable subjects to develop the organic radical light-emitting diode. However, conventional method is not applicable because the TMM biradicals are short-lived intermediates. In this work, we studied fluorescence properties of the TMM biradicals by employing double laser flash photolysis and various methods to generate the TMM biradicals. Although photoinduced electron-transfer reaction is not effective owing to single electron-transfer quenching of the excited TMM with sensitizer, we successfully evaluated the fluorescence properties of the TMM biradicals by utilizing intra- or intermolecular energy-transfer reaction. In addition, through this study, we discovered an "excited state C-C bond cleavage-emission" phenomenon of methylenecyclopropane derivatives.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (112 results)

All 2014 2013 2012 2011 Other

All Journal Article (34 results) (of which Peer Reviewed: 32 results) Presentation (52 results) (of which Invited: 39 results) Book (18 results) Remarks (8 results)

  • [Journal Article] Theoretical Study Demonstrating that Silylene Bridging Brings about LUMO Energy Lowering without Increasing the Reorganization Energy for Single Electron Transfer2014

    • Author(s)
      Ohta, E.; Ogaki, T.; Aoki, T.; Ikeda, H
    • Journal Title

      Chem. Lett

      Volume: 13(in press)

    • NAID

      130004868152

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pyreno[4,5-b]furan and -[4,5-b :9,10-b']difuran Derivatives as New Blue Fluorophores : Synthesis, Structure, and Electronic Properties2014

    • Author(s)
      Kojima, T.; Yokota, R.; Kitamura, C.; Kurata, H.; Tanaka, M.; Ikeda, H.; Kawase, T.
    • Journal Title

      Chem. Lett

      Volume: 13(in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of a New Benzotriquinane Skeleton via Intramolecular Photocycloaddition Reactions of a Phenylethynes Moiety to a 1-Cyanonaphthalene Ring System2014

    • Author(s)
      Mizuno, K.; Negoro, N.; Nagayama, Y.; Maeda, H.; Ikeda, H.
    • Journal Title

      Photochem. Photobiol. Sci

      Volume: 13 Pages: 145-148

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pyreno[4,5-b]furan and -[4,5-b:9,10-b']difuran Derivatives as New Blue Fluorophores: Synthesis, Structure, and Electronic Properties2014

    • Author(s)
      Kojima, T.; Yokota, R.; Kitamura, C.; Kurata, H.; Tanaka, M.; Ikeda, H.; Kawase, T.
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 5 Pages: 696-698

    • DOI

      10.1246/cl.131198

    • NAID

      130004868121

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Study Demonstrating that Silylene Bridging Brings about LUMO Energy Lowering without Increasing the Reorganization Energy for Single Electron Transfer2014

    • Author(s)
      Ohta, E.; Ogaki, T.; Aoki, T.; Ikeda, H.
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 6 Pages: 755-757

    • DOI

      10.1246/cl.140023

    • NAID

      130004868152

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of a New Benzotriquinane Skeleton via Intramolecular Photocycloaddition Reactions of a Phenylethynes Moiety to a 1-Cyanonaphthalene Ring System2014

    • Author(s)
      Mizuno, K.; Negoro, N.; Nagayama, Y.; Maeda, H.; Ikeda, H.
    • Journal Title

      Photochem. Photobiol. Sci.

      Volume: 13 Issue: 2 Pages: 145-148

    • DOI

      10.1039/c3pp50243k

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 有機ELの開発最前線4,"常識を覆す「有機ラジカルEL」"2014

    • Author(s)
      池田 浩,松井康哲
    • Journal Title

      化学と工業

      Volume: 67 Pages: 335-337

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 特集・ルミネッセンス化学の最前線,"ジアロイルメタナートホウ素二フッ化物で見られる白色フォトルミネッセンス"2014

    • Author(s)
      酒井敦史,田中未來,太田英輔,池田 浩
    • Journal Title

      化学工業

      Volume: 65 Pages: 27-31

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Remarkable Difference in Fluorescence Lifetimes of the Crystalline States of Dibenzoylmethanatoboron Difluoride and Its Diisopropyl Derivative2013

    • Author(s)
      Tanaka, M.; Ohta, E.; Sakai, A.; Yoshimoto, Y.; Mizuno, K.; Ikeda, H
    • Journal Title

      Tetrahedron Lett

      Volume: 54 Pages: 4380-4384

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Pentadecaphenylenes, Their Inclusion Properties, and Nanostructure Formation with C602013

    • Author(s)
      Rahman, M. J.; Shimizu, H.; Araki, Y.; Ikeda, H.; Iyoda, M
    • Journal Title

      Chem. Commun

      Volume: 49 Pages: 9251-9253

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Basic Properties of Tetrathieno[2,3-a :3′,2′-c:2″,3″-f:3‴,2‴-h]nap hthalene : A New π-Conjugated System Obtained by Photoinduced Electrocyclization-Dehydrogenation Reactions of Tetra(3-thienyl)ethene2013

    • Author(s)
      Yamamoto, A.; Ohta, E.; Kishigami, N.; Tsukahara, N.; Tomiyori, Y.; Sato, H.; Matsui, Y.; Kano, Y.; Mizuno, K.; Ikeda, H
    • Journal Title

      Tetrahedron Lett

      Volume: 54 Pages: 4049-4053

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Lifetime and Efficiency of Triplet-Triplet Fluorescence from the Excited State of a TMM Biradical Determined Using Transient Emission Spectroscopy on Two-color Two-laser Flash Photolysis2013

    • Author(s)
      Matsui, Y.; Kawahara, D.; Ohta, E.; Ikeda, H
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 15 Pages: 7064-7069

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 3,14-Bis(p-nitrophenyl)-17,17-dipenyltetrabenzo[ a,c,g,i]-fluorene : A New Fluorophore Displaying Both Remarkable Solvatochromism and Crystalline-induced Emission2013

    • Author(s)
      Ueda, Y.; Tanigawa, Y.; Kitamura, C.; Ikeda, H.; Yoshimoto, Y.; Tanaka, M.; Mizuno, K.; Kurata, H.; Kawase, T
    • Journal Title

      Chem. Asian J

      Volume: 8 Pages: 392-399

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 3,14-Bis(p-nitrophenyl)-77, 17-dipentyltetrabenzo [a,c,g,i] fluorene : A New Fluorophore Displaying Both Remarkable Solvatochromism and Crystalline-Induced Emission2013

    • Author(s)
      Ueda, U.; Tanigawa, Y.; Kitamura, C.; Ikeda, H.; Yoshimoto, Y.; Tanaka, M.; Mizuno K.; Kurata, H.; Kawase, T.
    • Journal Title

      Chem. Asian J.

      Volume: 8(印刷中) Issue: 2 Pages: 392-399

    • DOI

      10.1002/asia.201200976

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Pentadecaphenylenes, Its Inclusion Properties, and Nanostructure Formation with C602013

    • Author(s)
      M. J. Rahman, H. Shimizu, Y. Araki, H. Ikeda, M. Iyoda
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 81 Pages: 9251-9253

    • DOI

      10.1039/c3cc42922a

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Lifetime and Efficiency of Triplet-Triplet Fluorescence from the Excited State of a TMM Biradical Determined Using Transient Emission Spectroscopy on Two-color Two-laser Flash Photolysis2013

    • Author(s)
      Matsui, Y.; Kawahara, D.; Ohta, E.; Ikeda, H.
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 15 Issue: 19 Pages: 7064-7069

    • DOI

      10.1039/c3cp50581b

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Basic Properties of Tetrathieno[2,3-a:3',2'-c:2'',3''-f:3''',2'''-h]naphthalene: A New π-Conjugated System Obtained by Photoinduced Electrocyclization-Dehydrogenation Reactions of Tetra(3-thienyl)ethene2013

    • Author(s)
      Yamamoto, A.; Ohta, E.; Kishigami, N.; Tsukahara, N.; Tomiyori, Y.; Sato, H.; Matsui, Y.; Kano, Y.; Mizuno, K.; Ikeda, H.
    • Journal Title

      Tetrahedron Lett.

      Volume: 54 Issue: 31 Pages: 4049-4053

    • DOI

      10.1016/j.tetlet.2013.05.090

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Remarkable Difference in Fluorescence Lifetimes of the Crystalline States of Dibenzoylmethanatoboron Difluoride and Its Diisopropyl Derivative2013

    • Author(s)
      Tanaka, M. ; Ohta, E. ; Sakai, A. Yoshimoto, Y. ; Mizuno, K. ; Ikeda, H.
    • Journal Title

      Tetrahedron Letter

      Volume: 54 Issue: 33 Pages: 4380-4384

    • DOI

      10.1016/j.tetlet.2013.05.120

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] トピックス,"メチレンシクロプロパン誘導体の「励起状態C-C結合開裂-発光」の発見"2013

    • Author(s)
      松井康哲,木戸大希,太田英輔,池田 浩
    • Journal Title

      光化学

      Volume: 44 Pages: 150-153

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] White Light Emission from a Single Component System : Remarkable Concentration Effects on the Fluorescence of 1,3-Diaroylmethanatoboron Difluoride2012

    • Author(s)
      Sakai, A.; Tanaka, M.; Ohta, E.; Yoshimoto, Y.; Mizuno, K.; Ikeda, H
    • Journal Title

      Tetrahedron Lett

      Volume: 53 Pages: 4138-4141

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] DFT Studies of Unique Stereoelectronic Effects of Substituents on Divergent Reaction Pathways of Methylenecyclobutanone Radical Cations2012

    • Author(s)
      Kano, Y.; Tanaka, F.; Ohta, E.; Mizuno, K.; Ikeda, H.
    • Journal Title

      Tetrahedron

      Volume: 68 Pages: 5564-5571

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] White Light Emission from a Single Component System : Remarkable Concentration Effects on the Fluorescence of 1,3-Diaroylmethanatoboron Difluoride2012

    • Author(s)
      Sakai, A; Tanaka, M.; Ohta, E.; Yoshimoto, Y.; Mizuno, K.; Ikeda, H.
    • Journal Title

      Tetrahedron Lett.

      Volume: 53 Issue: 32 Pages: 4138-4141

    • DOI

      10.1016/j.tetlet.2012.05.122

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Basic Properties of Organic Radicals and Their Functionalization —From Examples in the Past to Organic Radical Light-Emitting Diode in the Future—2012

    • Author(s)
      松井康哲,水野一彦,池田 浩
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: 70 Issue: 5 Pages: 434-441

    • DOI

      10.5059/yukigoseikyokaishi.70.434

    • NAID

      40019322699

    • ISSN
      0037-9980, 1883-6526
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Density Functional Theory Study of Silole-fused Tetramethyleneethane Biradicals with Orbital Interactions2012

    • Author(s)
      Y.Kano, K.Mizuno, H.Ikeda
    • Journal Title

      Journal of Physical Organic Chemistry

      Volume: 24 Issue: 10 Pages: 921-928

    • DOI

      10.1002/poc.1891

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] エキシプレックス発光性有機結晶:1,4-ジシアノナフタレン-アレーン連結ダイアドの分子間および分子内エキシプレックスの生成2012

    • Author(s)
      松井康哲, 水野一彦, 池田浩
    • Journal Title

      有機合成化学協会誌

      Volume: 70(印刷中)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design, Generation, and Characterization of a 1,5-Hexadiene Bearing Two Lophyl Radicals as a Probe of the Stepwise Mechanism for the Cope Rearrangement2011

    • Author(s)
      Ikeda, H.; Matsuo, K.; Matsui, Y.; Matsuoka, M.; Mizuno, K
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 84 Pages: 537-543

    • NAID

      10028241864

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Probable Hydrogen-Bonded Meisenheimer Complex : An Unusually High SNAr Reactivity of Nitroaniline Derivatives with Hydroxide Ion in Aqueous Media2011

    • Author(s)
      Imoto, M.; Matsui, Y.; Takeda, M.; Tamaki, A.; Taniguchi, H.; Mizuno, K.; Ikeda, H
    • Journal Title

      J. Org. Chem

      Volume: 76 Pages: 6356-6361

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Density Functional Theory Study of Silole-fused Tetramethyleneethane Biradicals with Orbital Interactions2011

    • Author(s)
      Kano, Y.; Mizuno, K.; Ikeda, H
    • Journal Title

      J. Phys. Org. Chem

      Volume: 24 Pages: 921-928

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Twisted Molecular Geometry and Localized Electronic Structure of the Triplet Excited gem-Diphenyltrimethylenemethane Biradical : Substituent Effects on Thermoluminescence and Related Theoretical Calculations2011

    • Author(s)
      Matsui, Y.; Namai, H.; Akimoto, I.; Kan'no, K.-i.;Mizuno, K.; Ikeda, H
    • Journal Title

      Tetrahedron

      Volume: 67 Pages: 7431-7439

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Design, Generation, and Characterization of a 1,5-Hexadiene Bearing Two Lophyl Radicals as a Probe of the Stepwise Mechanism for the Cope Rearrangement2011

    • Author(s)
      Ikeda, H.; Matsuo, K.; Matsui, Y.; Matsuoka, M.; Mizuno, K.
    • Journal Title

      Bull.Chem.Soc.Jpn.

      Volume: 84 Issue: 5 Pages: 537-543

    • DOI

      10.1246/bcsj.20110029

    • NAID

      130004152904

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Probable Hydrogen-Bonded Meisenheimer Complex : An Unusually High S_NAr Reactivity of Nitroaniline Derivatives with Hydroxide Ion in Aqueous Media2011

    • Author(s)
      Imoto, M.; Matsui, Y.; Takeda, M.; Tamaki, A.; Taniguchi, H.; Mizuno, K.; Ikeda, H.
    • Journal Title

      J.Org.Chem.

      Volume: 76 Issue: 15 Pages: 6356-6361

    • DOI

      10.1021/jo2007219

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Twisted Molecular Geometry and Localized Electronic structure of the Triplet Excited gem-Diphenyltrimethylenemethane Biradical : SUbstituent Effects on Thermoluminescence and Related Theoretical Calculations2011

    • Author(s)
      Matsui, Y.; Namai, H.; Akimoto, I.; Kan'no, K.; Mizuno, K.; Ikeda, H.
    • Journal Title

      Tetrahedron

      Volume: 67 Issue: 38 Pages: 7431-7439

    • DOI

      10.1016/j.tet.2011.06.052

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 常識を打ち破る「有機ラジカルEL」2011

    • Author(s)
      池田浩
    • Journal Title

      化学工業

      Volume: 62 Pages: 30-35

    • Related Report
      2011 Annual Research Report
  • [Journal Article] エキシプレックス発光性有機結晶:1,4-ジシアノナフタレン-アレーン連結ダイアドの分子間および分子内エキシプレックスの生成2011

    • Author(s)
      井本充隆, 竹田元則, 池田浩, 松井康哲, 水野一彦
    • Journal Title

      化学工業

      Volume: 62 Pages: 48-52

    • Related Report
      2011 Annual Research Report
  • [Presentation] 熱ルミネッセンスおよび有機ラジカル EL をもたらす励起ビラジカルの三重項-三重項蛍光2014

    • Author(s)
      池田浩
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-03-29
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 熱ルミネッセンスおよび有機ラジカルEL をもたらす励起ビラジカルの三重項-三重項蛍光2014

    • Author(s)
      池田 浩
    • Organizer
      日本化学会第94春季年会(2014) 特別企画「ルミネッセンス化学アンサンブル:新学理から花開く革新的発光化学」
    • Place of Presentation
      名古屋(名古屋大学)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機ホウ素錯体および電荷移動錯体の結晶構造と発光挙動2013

    • Author(s)
      池田浩
    • Organizer
      東海コンファレンス 2013 in岐阜-光を利用した物質の構造制御と機能化-
    • Place of Presentation
      岐阜
    • Year and Date
      2013-12-25
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 有機光化学および電子移動化学におけるヘテロ原子の活用~私の有機典型元素化学 事始め~2013

    • Author(s)
      池田浩
    • Organizer
      第40回有機典型元素化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2013-12-05
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Spectroscopic and Exploratory Study of the Radical Cation Possessing One-electron σ Bond2013

    • Author(s)
      Ikeda, H
    • Organizer
      The 9th Korea-Japan Symposium on Frontier Photoscience (KJFP-2013)
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2013-11-27
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Spectroscopic and Exploratory Study of the Radical Cation Possessing a Oneelectron σ Bond2013

    • Author(s)
      Ikeda, H.; Ohta, E.; Kuramoto, Y.; Asada, N.; Mizuno, K.
    • Organizer
      The 11th International Symposium on Organic Reaction 2013 (ISOR-11)
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2013-11-21
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Spectroscopic and Exploratory Study of the Radical Cation Possessing a One-electron σ Bond2013

    • Author(s)
      Ikeda, H
    • Organizer
      Seminar of Physical Organic Chemistry at National Chiao Tung University
    • Place of Presentation
      Hsinchu, Taiwan
    • Year and Date
      2013-11-19
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 6員環状1,4-ラジカルカチオンにおける理論上最大の軌道相互作用 : 過渡吸収測定と古典的理論研究2013

    • Author(s)
      池田浩
    • Organizer
      大阪大学大学院工学研究科 中野雅由研究室セミナー
    • Place of Presentation
      大阪
    • Year and Date
      2013-10-04
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 熱ルミネッセンスにヒントを得た「有機ラジカルEL」の開発研究2013

    • Author(s)
      池田浩
    • Organizer
      九州大学大学院博士課程教育リーディングプログラム 分子システムデバイスコース 第14回分子システムデバイスセミナー
    • Place of Presentation
      福岡
    • Year and Date
      2013-07-24
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Thermo- and Electroluminescence of Organic π Diradical2013

    • Author(s)
      Ikeda, H.
    • Organizer
      The 11th International Symposium on Functional π-Electron Systems (Fπ-11)
    • Place of Presentation
      Arcachon, France
    • Year and Date
      2013-06-06
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 熱ルミネッセンスにヒントを得た有機ラジカルEL の開発2013

    • Author(s)
      池田浩
    • Organizer
      第131回ラドテック研究会講演会
    • Place of Presentation
      東京
    • Year and Date
      2013-04-23
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 有機発光三題 -媒体に依存するボロン錯体,電荷移動錯体,そしてビラジカルの発光-2013

    • Author(s)
      池田浩
    • Organizer
      繊維学会北陸支部先端技術研究会講演
    • Place of Presentation
      福井
    • Year and Date
      2013-03-06
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 熱ルミネッセンスにヒントを得た有機ラジカルELの開発2013

    • Author(s)
      池田 浩
    • Organizer
      第131回ラドテック研究会講演会
    • Place of Presentation
      東京(学士会館)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Thermo- and Electroluminescence of Organic π Diradical2013

    • Author(s)
      Hiroshi Ikeda
    • Organizer
      The 11th International Symposium on Functional π-electron systems (Fπ-11)
    • Place of Presentation
      France (Arcachon, the Palais des Congres)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 熱ルミネッセンスにヒントを得た「有機ラジカルEL」の開発研究2013

    • Author(s)
      池田 浩
    • Organizer
      九州大学大学院博士課程教育リーディングプログラム 第14回分子システムデバイスセミナー
    • Place of Presentation
      伊都(九州大学)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 6員環状1,4-ラジカルカチオンにおける 理論上最大の軌道相互作用: 過渡吸収測定と古典的理論研究2013

    • Author(s)
      池田 浩
    • Organizer
      大阪大学大学院工学研究科 中野雅由研究室セミナー
    • Place of Presentation
      大阪(大阪大学)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Spectroscopic and Exploratory Study of the Radical Cation Possessing a One-Electron sigma Bond2013

    • Author(s)
      Hiroshi Ikeda
    • Organizer
      Seminar of Physical Organic Chemistry at National Chiao Tung University
    • Place of Presentation
      Taiwan (Hsinchu, NCTU)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Spectroscopic and Exploratory Study of the Radical Cation Possessing a One-Electron sigma Bond2013

    • Author(s)
      Hiroshi Ikeda, Eisuke Ohta, Yutaro Kuramoto, Naoya Asada, and Kazuhiko Mizuno
    • Organizer
      The International Symposium on Organic Reaction 2013 (ISOR-11)
    • Place of Presentation
      Taiwan (Taipei, Howard International House)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Spectroscopic and Exploratory Study of the Radical Cation Possessing a One-Electron sigma Bond2013

    • Author(s)
      Hiroshi Ikeda
    • Organizer
      The 9th Korea-Japan Symposium on Frontier Photoscience-2013
    • Place of Presentation
      Korea (Soul, Hoam Faculty House)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機光化学および電子移動化学におけるヘテロ原子の活用 ~私の有機典型元素化学 事始め~2013

    • Author(s)
      池田 浩
    • Organizer
      第40回 有機典型元素化学討論会
    • Place of Presentation
      東大阪(近畿大学)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機ホウ素錯体および電荷移動錯体の結晶構造と発光挙動2013

    • Author(s)
      池田 浩
    • Organizer
      東海コンファレンス 2013 in 岐阜 -光を利用した物質の構造制御と機能化-
    • Place of Presentation
      岐阜(岐阜大学)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機発光三題 ー媒体に依存するボロン錯体,電荷移動錯体,そしてビラジカルの発光ー2013

    • Author(s)
      池田 浩
    • Organizer
      繊維学会北陸支部 先端技術研究会
    • Place of Presentation
      福井(福井大学)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ルミネッセンス化学アンサンブル:多彩な発光機能の基礎と実用展開―趣旨説明2013

    • Author(s)
      池田 浩
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      草津(立命館大学)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Spectroscopic and Theoretical Evidence for a Radical Cation with a One-electron σ-Bond Generated by PET Reaction2012

    • Author(s)
      Ikeda, H,; Asada, N.; Ohta, E.; Oshima, M.; Mizuno, K.
    • Organizer
      7th Asian Photochemistry Conference 2012
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2012-10-22
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 光誘起電子移動反応から熱ルミネッセンス,そして有機ラジカル EL への展開2012

    • Author(s)
      池田浩
    • Organizer
      住友化学(株)筑波開発研究所講演会
    • Place of Presentation
      筑波
    • Year and Date
      2012-10-21
    • Related Report
      2013 Final Research Report
  • [Presentation] 高い発光特性をもつレドックス感応性開殻化学種の創製と機能2012

    • Author(s)
      池田浩
    • Organizer
      「感応性化学種が拓く新物質科学」第1回公開シンポジウム
    • Place of Presentation
      宇治
    • Year and Date
      2012-09-20
    • Related Report
      2013 Final Research Report
  • [Presentation] Generation of the Ground and Excited State Biradicals by Controlling BET Step in PET Reactions2012

    • Author(s)
      Ikeda, H.
    • Organizer
      光化学討論会2012
    • Place of Presentation
      東京
    • Year and Date
      2012-09-12
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 有機ラジカルカチオンから生まれる新しい化学現象 ~熱ルミネッセンス,有機ラジカルEL,一電子σ結合を例に~2012

    • Author(s)
      池田浩
    • Organizer
      第44回構造有機化学若手の会
    • Place of Presentation
      札幌
    • Year and Date
      2012-08-03
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation]2012

    • Author(s)
      池田浩
    • Organizer
      第44回構造有機化学若手の会夏の学校
    • Place of Presentation
      定山渓万世閣・ホテルミリオーネ大会議室(北海道)(未定)(招待講演)(講演確定)
    • Year and Date
      2012-08-03
    • Related Report
      2011 Annual Research Report
  • [Presentation] ねじれた π空間がもたらす革新的「有機ラジカルEL」と 特異な軌道相互作用2012

    • Author(s)
      池田浩
    • Organizer
      「高次π空間の創発と機能開発」第8回公開シンポジウム
    • Place of Presentation
      加賀
    • Year and Date
      2012-07-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Spectroscopic and DFT Evidence for a Radical Cation Possessing a One-electron σ-Bond2012

    • Author(s)
      Ikeda, H.; Asada, N.; Osahima M.; Mizuno, K
    • Organizer
      XXIV IUPAC Symposium on Photochemistry
    • Place of Presentation
      Coimbra, Portugal
    • Year and Date
      2012-07-16
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 熱ルミネッセンスと有機ラジカル EL-学生が見つけた大発見-2012

    • Author(s)
      池田浩
    • Organizer
      福井大学大学院工学研究科講演会
    • Place of Presentation
      福井
    • Year and Date
      2012-06-27
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation]2012

    • Author(s)
      池田浩
    • Organizer
      福井大学大学院工学研究科生物応用化学専攻
    • Place of Presentation
      福井大学大学院工学研究科生物応用化学専攻講義室(福井県)(未定)(招待講演)(講演確定)
    • Year and Date
      2012-06-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 熱ルミネッセンスと有機ラジカルEL-学生が見つけてくれた大発見-2012

    • Author(s)
      池田浩
    • Organizer
      信州大学教育学部講演会
    • Place of Presentation
      信州大学教育学部講義室(長野県)(招待講演)
    • Year and Date
      2012-01-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 熱ルミネッセンスと有機ラジカルEL ー学生が見つけた大発見ー2012

    • Author(s)
      池田 浩
    • Organizer
      福井大学大学院工学研究科生物応用化学専攻 第333回化学セミナー
    • Place of Presentation
      福井(福井大学)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 有機ラジカルカチオンから生まれる新しい化学現象 ~熱ルミネッセンス,有機ラジカルEL,一電子σ結 合を例に~2012

    • Author(s)
      池田 浩
    • Organizer
      第44回 構造有機化学若手の会 夏の学校
    • Place of Presentation
      札幌(定山渓万世閣)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Generation of the Ground and Excited State Biradicals by Controlling BET Step in PET Reactions2012

    • Author(s)
      Ikeda, H.
    • Organizer
      Annual Meeting on Photochemistry 2012
    • Place of Presentation
      東京(東京工業大学)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 光誘起電子移動反応から,熱ルミネッセンス,そして有機ラジカルELへの展開2012

    • Author(s)
      池田 浩
    • Organizer
      住友化学工業(株)筑波研究所講演会
    • Place of Presentation
      つくば(住友化学工業(株))
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Spectroscopic and Theoretical Evidence for a Radical Cation with a One-Electron σ-Bond Generated by PET Reaction2012

    • Author(s)
      Ikeda, H.; Asada, N.; Ohta, E.; Oshima, M.; K. Mizuno
    • Organizer
      7th Asian Photochemistry Conference 2012 (APC2012)
    • Place of Presentation
      吹田(大阪大学)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 光誘起電子移動反応から,熱ルミネッセンス,そして「有機ラジカルEL」への展開 ー学生が見つけた大発見ー2012

    • Author(s)
      池田 浩
    • Organizer
      平成24年兵庫県立大学大学院工学研究科物質系工学専攻講演会 分子ナノテクノロジーセンター第4回講演会
    • Place of Presentation
      姫路(兵庫県立大学)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 熱ルミネッセンスと有機ラジカル EL-学生が見つけてくれた大発見-2011

    • Author(s)
      池田浩
    • Organizer
      信州大学教育学部講演会
    • Place of Presentation
      長野
    • Year and Date
      2011-12-20
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 発光三題:熱ルミネッセンス,有機ラジカルEL,そして有機ボロン錯体の固体発光2011

    • Author(s)
      池田浩
    • Organizer
      奈良先端科学技術大学第171回光ナノサイエンス特別講義
    • Place of Presentation
      奈良先端科学技術大学物質創成科学研究科大講義室(奈良県)(招待講演)
    • Year and Date
      2011-12-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] 発光三題 : 熱ルミネッセンス,有機ラジカル EL,そして有機ボロン錯体の固体発光2011

    • Author(s)
      池田浩
    • Organizer
      奈良先端科学技術大学第171回光ナノサイエンス特別講義
    • Place of Presentation
      奈良
    • Year and Date
      2011-11-25
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 府大発で世界初!有機ラジカルELの秘密2011

    • Author(s)
      池田浩
    • Organizer
      大阪府立大学産官学共同研究会第72回テクノラボツアー
    • Place of Presentation
      大阪府立大学中百舌鳥キャンパスB5-1B-38(大阪府)(招待講演)
    • Year and Date
      2011-11-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Spectroscopic Observation of Radical Cations Possessing One-electron σ-Bonds : Photoinduced Electron-Transfer Reactions of Diarylated Cage Compounds2011

    • Author(s)
      Ikeda, H.
    • Organizer
      10th International Symposium on Organic Reactions (ISOR10)
    • Place of Presentation
      横浜
    • Year and Date
      2011-11-23
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Spectroscopic Observation of Radical Cations Possessing One-electron σ-Bonds : Photoinduced Electron-Transfer Reactions of Diarylated Case Compounds2011

    • Author(s)
      Ikeda, H.
    • Organizer
      10th International Symposium on Organic Reactions (ISOR10)
    • Place of Presentation
      慶応大学日吉キャンパス想創館(神奈川県)(招待講演)
    • Year and Date
      2011-11-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Spectroscopic and DFT Evidence for a Radical Cation Possessing a One-Electron σ-Bond2011

    • Author(s)
      *Ikeda, H.; Asada, N.; Oshima, M.; Mizuno, K
    • Organizer
      The 8th Korea-Japan Symposium on Frontier Photoscience (KJFP 2011)
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2011-10-30
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Spectroscopic and DFT Evidence for a Radical Cation Possessing a One-Electron σ-Bond2011

    • Author(s)
      Ikeda, H., Asada, N.Oshima, M.Mizuno, K.
    • Organizer
      The 8^<th> Korea-Japan Symposium on Frontier Photoscience (KJFP 2011)
    • Place of Presentation
      Room B, International Conference Hall, Kunkuk University, Seoul(韓国)(招待講演)
    • Year and Date
      2011-10-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 有機ボロン錯体の固体発光特性と結晶構造-有機ボロン錯体の固体発光特性と結晶構造-2011

    • Author(s)
      池田浩
    • Organizer
      近畿化学協会ヘテロ原子部会平成23年度第2回懇話会
    • Place of Presentation
      和歌山
    • Year and Date
      2011-10-04
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 有機ボロン錯体の固体発光特性と結晶構造-置換基の嵩高さが制御する励起マルチマーとピエゾクロミズム-2011

    • Author(s)
      池田浩
    • Organizer
      近畿化学協会ヘテロ原子部会平成23年度第2回懇話会
    • Place of Presentation
      花王(株)エコテクノロジーリサーチセンター(和歌山県)(招待講演)
    • Year and Date
      2011-10-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] 有機光電子移動反応の機構解明と発光化学への展開2011

    • Author(s)
      池田浩
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      2011-09-08
    • Related Report
      2013 Final Research Report
  • [Presentation] 有機光電子移動反応の機構解明と発光化学への展開2011

    • Author(s)
      池田浩
    • Organizer
      2011年光化学討論会光化学協会賞受賞講演会
    • Place of Presentation
      宮崎市民プラザオルブライトホール(宮崎県)(招待講演)
    • Year and Date
      2011-09-08
    • Related Report
      2011 Annual Research Report
  • [Book] 光化学の事典 -だれでもわかる光化学の初歩-,光化学協会編2014

    • Author(s)
      池田浩(分担執筆)
    • Publisher
      朝倉書店
    • Related Report
      2013 Final Research Report
  • [Book] 常識を覆す「有機ラジカル EL」化学と工業2014

    • Author(s)
      池田浩, 松井康哲
    • Publisher
      日本化学会
    • Related Report
      2013 Final Research Report
  • [Book] ジアロイルメタナートホウ素二フッ化物で見られる白色フォトルミネッセンス,化学工業2014

    • Author(s)
      酒井敦史 ,田中未來, 太田英輔, 池田浩
    • Publisher
      化学工業社
    • Related Report
      2013 Final Research Report
  • [Book] メチレンシクロプロパン誘導体の「励起状態 C-C 結合開裂-発光」の発見,光化学2014

    • Author(s)
      松井康哲, 木戸大希, 太田英輔, 池田浩
    • Publisher
      光化学協会
    • Related Report
      2013 Final Research Report
  • [Book] 光化学の事典 ーだれでもわかる光化学の初歩ー "第4章 さまざまな化合物の光化学,44.1 炭化水素ー(1)オレフィンの光化学反応"2014

    • Author(s)
      池田 浩
    • Publisher
      朝倉書店
    • Related Report
      2013 Annual Research Report
  • [Book] 高次π空間の創発と機能開発, 赤阪 健・大須賀篤弘・福住俊一・神取秀樹監修2013

    • Author(s)
      狩野佑介 ,太田英輔, 池田浩
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Final Research Report
  • [Book] 分子光化学の原理,井上晴夫,伊藤攻監訳2013

    • Author(s)
      水野一彦, 池田浩, 太田英輔, 狩野佑介, 松井康哲, 真嶋哲朗, 藤塚守,(分担翻訳)
    • Publisher
      丸善出版
    • Related Report
      2013 Final Research Report
  • [Book] 高次π空間の創発と機能開発 "第3章 高次π空間を利用した革新的機能開発,1.「ねじれたπ空間」がもたらす基底および励起ラジカル種の特異な軌道相互作用"2013

    • Author(s)
      狩野佑介,太田英輔,池田 浩(分担執筆).赤阪健・大須賀篤弘・福住俊一・神取秀樹監修
    • Total Pages
      245
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Annual Research Report
  • [Book] 分子光化学の原理,"第6章 有機光化学の分子理論"2013

    • Author(s)
      水野一彦,池田 浩,太田英輔,狩野佑介,松井康哲,真嶋哲朗,藤塚 守(分担執筆),井上晴夫・伊藤攻監訳
    • Total Pages
      433
    • Publisher
      丸善出版
    • Related Report
      2013 Annual Research Report
  • [Book] 光化学の事典 ーだれでもわかる光化学の初歩ー(光化学協会,分担執筆,"第4章 様々な化合物の光化学,4.1節 炭 化水素(1)「オレフィン,環状オレフィンの光化学」)2013

    • Author(s)
      太田英輔,池田 浩
    • Total Pages
      2
    • Publisher
      朝倉書店
    • Related Report
      2012 Annual Research Report
  • [Book] 高次n空間の創発と機能開発(赤阪健・大須賀篤弘・福住俊一・神取秀樹監修,分担執筆,第3章 高次π空間を利用し た革新的機能開発,1.「ねじれたπ空間」がもたらす基底および励起ラジカル種の特異な軌道相互作用)2013

    • Author(s)
      狩野佑介,太田英輔,池田 浩
    • Total Pages
      6
    • Publisher
      シーエムシー出版
    • Related Report
      2012 Annual Research Report
  • [Book] 特集号「有機合成がリードする材料の科学と機能」,"有機ラジカルの基礎特性とその機能化-過去の研究例から未来の有機ラジカル EL まで-"有機合成化学協会誌2012

    • Author(s)
      松井康哲, 水野一彦, 池田浩
    • Publisher
      有機合成化学協会
    • Related Report
      2013 Final Research Report
  • [Book] 第4章様々な化合物の光化学,4.1節炭化水素(1)「オレフィン,環状オレフィンの光化学」,光化学の事典-だれでもわかる光化学の初歩-(光化学協会編)2012

    • Author(s)
      太田英輔, 池田浩
    • Publisher
      朝倉書店(印刷中)
    • Related Report
      2011 Annual Research Report
  • [Book] 常識を打ち破る「有機ラジカルEL」2011

    • Author(s)
      池田浩
    • Publisher
      化学工業
    • Related Report
      2013 Final Research Report
  • [Book] エキシプレックス発光性有機結晶 : 1,4-ジシアノナフタレン-アレーン連結ダイアドの分子間および分子内エキシプレックスの生成2011

    • Author(s)
      井本充隆, 竹田元則, 池田浩, 松井康哲, 水野一彦
    • Publisher
      化学工業
    • Related Report
      2013 Final Research Report
  • [Book] "第1章 ジアリールエテンの極限性能,5.テトラチエニルエテン誘導体のフォトおよびエレクトロクロミック特性",フォトクロミズムの新展開と光メカニカル機能材料,入江正浩・関 隆広監修2011

    • Author(s)
      川邊晶文, 水野一彦, 池田浩
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Final Research Report
  • [Book] 熱ルミネッセンスの発見と革新的「有機ラジカル EL」の開発2011

    • Author(s)
      池田浩
    • Publisher
      科研費ニュース
    • Related Report
      2013 Final Research Report
  • [Book] "第1章ジアリールエテンの極限性能,5.テトラチエニルエテン誘導体のフォトおよびエレクトロクロミック特性",フォトクロミズムの新展開と光メカニカル機能材料(入江正浩・関隆広監修)(分担執筆)2011

    • Author(s)
      川邊晶文, 水野一彦, 池田浩
    • Total Pages
      9
    • Publisher
      シーエムシー出版
    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka5/index.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 2013年光化学討論会にて優秀学生発表賞(ポスター)を受賞(2013年9月).木戸大希(発表当時,修士課程1年)"分子間エネルギー移動反応により引き起こされるメチレンシクロプロパン誘導体の「励起状態C-C結合開裂-発光」"(受賞)

    • Related Report
      2013 Final Research Report
  • [Remarks] 第24回基礎有機化学討論会にてポスター賞を受賞(2013年9月).木戸大希(発表当時,修士課程1年)."分子間エネルギー移動反応を利用したメチレンシクロプロパン誘導体の発光機構"(受賞)

    • Related Report
      2013 Final Research Report
  • [Remarks] 日本化学会第93春季年会(2013)にて学生講演賞を受賞(2013年4月).松井康哲(発表当時,博士課程3年)."分子子内三重項エネルギー移動反応とダブルレーザー法を利用した励起トリメチレンメタンビラジカルの発生"(受賞)

    • Related Report
      2013 Final Research Report
  • [Remarks] 第5回 GSC(グリーンサスティナブルケミストリー)にてStudent Travel Grant Awardsを受賞(2011年6月).松井康哲(応募当時,博士課程2年)."ラジカルを利用した低炭素型有機EL発光子"(受賞)

    • Related Report
      2013 Final Research Report
  • [Remarks] 大阪府立大学大学院 工学研究科 物質・化学系専攻 応用化学分野 物質創成化学研究グループ

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka5/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 大阪府立大学大学院工学研究科物質・化学系専攻応用化学分野 物質創成化学研究グループ 池田浩研究室

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka5/index.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka5/ikeda/list_of_pub.html

    • Related Report
      2011 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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