| Project/Area Number |
23350026
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
TAKUMI KONNO 大阪大学, 理学(系)研究科(研究院), 教授 (50201497)
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| Co-Investigator(Renkei-kenkyūsha) |
IGASHIRA Asako 大阪大学, 大学院・理学研究科, 講師 (20379275)
YOSHINARI Nobuto 大阪大学, 大学院・理学研究科, 助教 (10583338)
NAKAZAWA Yasuhiro 大阪大学, 大学院・理学研究科, 教授 (60222163)
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥20,670,000 (Direct Cost: ¥15,900,000、Indirect Cost: ¥4,770,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2012: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2011: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
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| Keywords | イオン結晶 / 結晶工学 / 自己組織化 / 超分子化学 / 超分子科学 |
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| Research Abstract |
In this study, the construction of ionic metallosupramolecular species, in which several complex-ions are self-assembled though multiple supramolecular interactions, together with the creation of metallosupramolecular architectures that show separate aggregation of cations and anions by the high-order aggregation of this class of metallosupramolecules, was investigated. As a result, the metal complexes containing both hydrophilic sulfur-containing amino acids and phenylphosphines was found to function as a multidentate metalloligand available for the construction of desirable metallosupramolecular structures. In addition, a significant insight into multiple supramolecular interactions that lead to the separate aggregation of cations and anions was obtained in this study.
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