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Creation of metal complexes that utilize naturally abundant calcogen source as reactants in synthetic chenistry

Research Project

Project/Area Number 23350027
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionOsaka University

Principal Investigator

SUGIMOTO Hideki  大阪大学, 工学(系)研究科(研究院), 准教授 (00315970)

Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
Fiscal Year 2013: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2011: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Keywordsルテニウム / オスミウム / モリブデン / タングステン / 硫黄 / セレン / 過酸化水素 / 金属錯体 / 酸素 / 硫黄錯体
Research Abstract

We examined reactions of metal complexes with naturally abundant chalcogen source and catalytic reactions in atom transfer between substrates and the chalcogen source. Mononuclear ruthenium(II) complexes having nitrogen containing tetradentate ligands were synthesized and employed as a catalyst in sulfur atom transfer from inorganic sulfur and norbornen. Mononuclear molybdenum and tungsten complexes having one terminal sulfide or selenido group were prepared as models of molybdenum and tungsten enzyme active sites, where hydrogensulfide and hydrogenselenide ions were used. Their atom transfer reactivity to triphenylphosphines was investigated. Mononuclear osmium complexes with nitrogen containing tetradentate ligands were synthesized and were revealed to catalyze 1,2-dyhydroxylation of alkenes with hydrogen peroxide.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (50 results)

All 2014 2013 2012 2011

All Journal Article (18 results) (of which Peer Reviewed: 8 results,  Open Access: 4 results) Presentation (32 results)

  • [Journal Article]2013

    • Author(s)
      H. Sugimoto, S. Tatemoto, K. Toyota, K. Ashikari, M. Kubo, T. Ogura, S. Itoh
    • Journal Title

      Chem. Comm

      Volume: 43 Pages: 4358-4360

    • Related Report
      2013 Final Research Report
  • [Journal Article]2013

    • Author(s)
      H. Sugimoto, K. Hatakeda, K. Toyota, S. Tatemoto, M. Kubo, T. Ogura, S. Itoh
    • Journal Title

      Dalton Trans

      Volume: 42 Pages: 3059-3070

    • Related Report
      2013 Final Research Report
  • [Journal Article]2013

    • Author(s)
      H. Sugimoto, K. Ahikari, S. Itoh
    • Journal Title

      Inorg. Chem

      Volume: 52 Pages: 543-545

    • Related Report
      2013 Final Research Report
  • [Journal Article]2013

    • Author(s)
      H. Sugimoto, K. Ashikari, S. Itoh
    • Journal Title

      Chem. Asian J

      Volume: 8 Pages: 2154-2160

    • Related Report
      2013 Final Research Report
  • [Journal Article] Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: Low temperature preparation and characterisation2013

    • Author(s)
      Shinobu Itoh, et al.
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 39 Pages: 4358-4360

    • DOI

      10.1039/c2cc35345h

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A new series of bis(ene-1,2-dithiolato)tungsten(IV), -(V), -(VI) complexes as reaction centre models of tungsten enzymes: Preparation, crystal structures and spectroscopic properties2013

    • Author(s)
      Hideki Sugimoto, Kohei Hatakeda, Kazuo Toyota, Susumu Tatemoto, Minoru Kubo, Takashi Ogura, Shinobu Itoh
    • Journal Title

      Dalton Transactions

      Volume: 42 Pages: 3059-3070

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] C–H Bond Activation of the Supporting Ligand in an Osmium(III) Complex with H2O2: Formation of an Organometallic Osmium(IV) Complex2013

    • Author(s)
      Shinobu Itoh, et al.
    • Journal Title

      Inorg. Chem.

      Volume: 52 Issue: 2 Pages: 543-545

    • DOI

      10.1021/ic302169k

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Osmium(III) and Osmium(V) Complexes Bearing a Macrocyclic Ligand: A Simple and Efficient Catalytic System for cis-Dihydroxylation of Alkenes with Hydrogen Peroxide2013

    • Author(s)
      Hideki Sugimoto, Kenji Ashikari, Shinobu Itoh
    • Journal Title

      Chemistry An Asian Journal

      Volume: 8 Issue: 9 Pages: 2154-2160

    • DOI

      10.1002/asia.201300329

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Oxo-carboxylato-molybdenum(VI) complexes possessing dithiolene ligand related to the active site of type II class of DMSOR family of molybdoenzymes2013

    • Author(s)
      Shinobu Itoh, et al.
    • Journal Title

      Dalton Trans.

      Volume: 42 Issue: 45 Pages: 15927-15930

    • DOI

      10.1039/c3dt51485d

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A new series of bis(ene-1,2-dithiolato)tungsten(IV), -(V), -(VI) complexes as reaction centre models of tungsten enzymes: preparation, crystal structures and spectroscopic properties2013

    • Author(s)
      Shinobu Itoh, et al.
    • Journal Title

      Dalton Trans.

      Volume: 42 Issue: 9 Pages: 3059-3070

    • DOI

      10.1039/c2dt32179c

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article]2012

    • Author(s)
      H. Sugimoto, K. Kitayama, S. Mori, S. Itoh, J. Am
    • Journal Title

      Chem. Soc

      Volume: 134 Pages: 19270-19280

    • Related Report
      2013 Final Research Report
  • [Journal Article] (165) An Osmium(III)/Osmium(V) Redox Couple Generating OsV(O)(OH) Center for cis-1,2-Dihydroxylation of Alkenes with H2O2: Os Complex with a Nitrogen- based Tetradentate Ligand2012

    • Author(s)
      Shinobu Itoh, et al.
    • Journal Title

      J Am. Chem. Soc.

      Volume: 134 Issue: 46 Pages: 19270-19280

    • DOI

      10.1021/ja309566c

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heterolytic Alkylhydroperoxide O-O Bond Cleavage by Copper(I) Complexes2012

    • Author(s)
      Tetsuro Tano
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: 2012 Issue: 26 Pages: 4099-4103

    • DOI

      10.1002/ejic.201200555

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article]2011

    • Author(s)
      H. Sugimoto, H. Tano, K. Suyama, T. Kobayashi, H. Miyake, S. Itoh, R. P. Mtei, M. L. Kirk
    • Journal Title

      Dalton Trans

      Volume: 40 Pages: 1119-1131

    • Related Report
      2013 Final Research Report
  • [Journal Article]2011

    • Author(s)
      ・H. Sugimoto, H. Tano, H. Miyake, S. Itoh
    • Journal Title

      Dalton Trans

      Volume: 40 Pages: 2358-2365

    • Related Report
      2013 Final Research Report
  • [Journal Article]2011

    • Author(s)
      H. Sugimoto, K. Kitayama, K. Ashikari, C. Matsunami, N. Ueda, K. Umakoshi, Y. Hosokoshi, Y. Sasaki, S. Itoh
    • Journal Title

      Inorg. Chem

      Volume: 50 Pages: 9014-9023

    • Related Report
      2013 Final Research Report
  • [Journal Article]2011

    • Author(s)
      H. Sugimoto, R. Tajima, K. Toyota, H. Miyake, S. Itoh
    • Journal Title

      Chem. Lett

      Volume: 40 Pages: 1146-1148

    • Related Report
      2013 Final Research Report
  • [Journal Article]2011

    • Author(s)
      H. Sugimoto, M. Z. Ertem, S. Yamaguchi, A. Kunishita, H. Sugimoto, N. Fujieda, T. Ogura, C. J. Cramer, S. Itoh
    • Journal Title

      Dalton Trans

      Volume: 40 Pages: 10326-10336

    • Related Report
      2013 Final Research Report
  • [Presentation] 含窒素四座配位子を有するオスミウム錯体を用いたアルケンの1,2-アミノヒドロキシル化反応2014

    • Author(s)
      杉本秀樹、三上明音、伊東忍
    • Organizer
      日本化学会春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 窒素系4座配位子を用いたオスミウム錯体の構造制御2014

    • Author(s)
      前田和紀、杉本秀樹、伊東忍
    • Organizer
      日本化学会春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] DMSORファミリー活性中心のモデル錯体としてのオキソ-アルコラトモリブデン(VI)錯体の合成と性質2014

    • Author(s)
      佐藤正典、杉本秀樹、朝野香織、鈴木健之、伊東忍
    • Organizer
      日本化学会春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation]2013

    • Author(s)
      三上明音, 杉本秀樹, 伊東忍
    • Organizer
      第63回錯体化学討論会
    • Place of Presentation
      琉球大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2013

    • Author(s)
      佐藤正典, 杉本秀樹, 伊東忍
    • Organizer
      第63回錯体化学討論会
    • Place of Presentation
      琉球大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2013

    • Author(s)
      前田和紀, 杉本秀樹, 伊東忍
    • Organizer
      第94回春季年会
    • Place of Presentation
      筑波大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2013

    • Author(s)
      杉本秀樹 ,芦刈健治, 三上明音, 伊東忍
    • Organizer
      第94回春季年会
    • Place of Presentation
      筑波大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2013

    • Author(s)
      金武孝幸, 杉本秀樹, 伊東忍
    • Organizer
      第94回春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2013

    • Author(s)
      佐藤正典, 杉本秀樹, 伊東忍
    • Organizer
      第94回春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2013

    • Author(s)
      前田和紀, 杉本秀樹, 伊東忍
    • Organizer
      第94回春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2013

    • Author(s)
      三上明音, 杉本秀樹, 伊東忍
    • Organizer
      第94回春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Final Research Report
  • [Presentation] An Osmium(III)/Osmium(V) Redox Couple for cis-1,2-Dihydroxylation of Alkens with H2O22013

    • Author(s)
      Hideki Sugimoto
    • Organizer
      The Sixteenth International Symposium on Relations between Homogeneous and Heterogeneous Catalysis
    • Place of Presentation
      Hokkaido University
    • Related Report
      2013 Annual Research Report
  • [Presentation] 六配位オキソモリブデン(VI)錯体の合成と反応性2013

    • Author(s)
      佐藤正典、杉本秀樹、伊東忍
    • Organizer
      錯体化学討論会
    • Place of Presentation
      琉球大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 環状四座配位子を持つオスミウム五価錯体によるアルケンの触媒的酸化反応2013

    • Author(s)
      杉本秀樹、芦刈健治、三上明音、伊東忍
    • Organizer
      酸化反応討論会
    • Place of Presentation
      筑波大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] オスミウム(III)/(V)レドックスを利用するアルケンの選択的シスジオール化反応2012

    • Author(s)
      杉本秀樹
    • Organizer
      第43回中部化学関係協会支部連合秋季大会
    • Place of Presentation
      名古屋工業大学(招待講演)
    • Year and Date
      2012-11-10
    • Related Report
      2011 Annual Research Report
  • [Presentation]2012

    • Author(s)
      杉本秀樹
    • Organizer
      第43回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      畠田康平 ,杉本秀樹, 伊東忍
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      慶応義塾大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      芦刈健治, 杉本秀樹, 伊東忍
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      慶応義塾大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      三上明音, 杉本秀樹, 伊東忍
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      慶応義塾大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      妻鳥友樹, 杉本秀樹, 伊東忍
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      慶応義塾大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      森聖治, 杉本秀樹, 伊東忍
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      芦刈健治, 杉本秀樹, 伊東忍
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      三上明音, 杉本秀樹, 伊東忍
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      芦刈健治, 杉本秀樹, 伊東忍
    • Organizer
      第45回酸化反応討論会
    • Place of Presentation
      名古屋市立大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      芦刈健治, 三上明音, 杉本秀樹, 伊東忍
    • Organizer
      日本化学会第93回春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      前田和紀, 杉本秀樹, 伊東忍
    • Organizer
      日本化学会第93回春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2012

    • Author(s)
      佐藤正典, 杉本秀樹, 伊東忍
    • Organizer
      日本化学会第93回春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2011

    • Author(s)
      H. Sugimoto, K. Kitayama, S. Itoh
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2011

    • Author(s)
      畠田康平, 杉本秀樹, 久保稔, 倉尚志, 伊東忍
    • Organizer
      第6回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2011

    • Author(s)
      樋口亮史, 杉本秀樹, 伊東忍
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2011

    • Author(s)
      芦刈健治 ,杉本秀樹, 伊東忍
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2013 Final Research Report
  • [Presentation]2011

    • Author(s)
      芦刈健治, 杉本秀樹, 伊東忍
    • Organizer
      第44回酸化反応討論会
    • Place of Presentation
      大阪大学
    • Related Report
      2013 Final Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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