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Construction of the spatiotemporal-molecular switching systems based on the dynamic coordination chemistry of chiral and labile metal complexes

Research Project

Project/Area Number 23350029
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionOsaka City University

Principal Investigator

MIYAKE Hiroyuki  大阪市立大学, 大学院理学研究科, 准教授 (00271198)

Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥20,410,000 (Direct Cost: ¥15,700,000、Indirect Cost: ¥4,710,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2012: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2011: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
Keywords金属錯体 / らせん / 不斉 / 置換活性 / 外部刺激 / アニオン / ペプチド / 分子運動
Research Abstract

This research work focused on the development of the spatiotemporal-chiral metal complex systems based on the dynamic coordination chemistry of labile metal complexes and the following results have been obtained; (1) helicity inversion programing in a square planar metal complex, (2) multi-switching complex based on the dynamic structural conversion of chiral metal complex, (3) chirality integration and dynamic helicity control in dendritic chiral metal complex, (4) construction of a photo-responsive chiral metal complex, (5) development of the stimuli-responsive chiral metal foldamers, (6) dynamic formation of chiral environment in highly coordinated lanthanide complexes.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (58 results)

All 2014 2013 2012 2011 Other

All Journal Article (12 results) (of which Peer Reviewed: 8 results) Presentation (40 results) (of which Invited: 3 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Lanthanide Tris(β-diketonates) as Useful Probes for Chirality Determination of Biological Amino Alcohols in Vibrational Circular Dichroism : Ligand to Ligand Chirality Transfer in Lanthanide Coordination Sphere2014

    • Author(s)
      H. Miyake, K. Terada and H. Tsukube
    • Journal Title

      Chirality

      Volume: 26 Issue: 6 Pages: 293-299

    • DOI

      10.1002/chir.22319

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 分子認識から始まる動的分子プログラミング-錯体化学を基盤としたキラリティー誘起と反転スイッチング2013

    • Author(s)
      三宅弘之
    • Journal Title

      化学

      Volume: 68 (5) Pages: 46-52

    • NAID

      40019676283

    • URL

      http://www.kagakudojin.co.jp/kagaku/web-kagaku03/c6805/c6805-miyake/index.html

    • Related Report
      2013 Final Research Report
  • [Journal Article] Materials-Based Receptors : Design Principle and Applications2013

    • Author(s)
      K. Singh, D. Sareen, P. Kaur, H. Miyake, and H. Tsukube
    • Journal Title

      Chem. Eur. J

      Volume: 19 Issue: 22 Pages: 6914-6936

    • DOI

      10.1002/chem.201300249

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 分子認識から始まる動的分子プログラミング-錯体化学を基盤としたキラリティー誘起と反転スイッチング2013

    • Author(s)
      三宅弘之
    • Journal Title

      化学

      Volume: 68 Pages: 46-52

    • NAID

      40019676283

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Preferential Crystallization of Lanthanoid Tris(β-diketonates) with Bridged Bis(2-pyridylmethyl)amine Ligands toward Separation Application2012

    • Author(s)
      Masafumi Yano
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 85 Issue: 4 Pages: 490-496

    • DOI

      10.1246/bcsj.20110281

    • NAID

      130004153052

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Helicity Inversion from Left- to Right-Handed Square Planar Pd(II) Complexes : Synthesis of a Diastereomer Pair from a Single Chiral Ligand and their Structure Dynamism2012

    • Author(s)
      Hiroyuki Miyake
    • Journal Title

      Chem.Commun.

      Volume: 48 Issue: 31 Pages: 3721-3723

    • DOI

      10.1039/c2cc18154a

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coordination Chemistry Strategies for Dynamic Helicates : Time-Programmable Chirality Switching with Labile and Inert Metal Helicates2012

    • Author(s)
      H. Miyake, and H. Tsukube
    • Journal Title

      Chem. Soc. Rev

      Volume: 41 Issue: 21 Pages: 6977-6991

    • DOI

      10.1039/c2cs35192g

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox Reaction of Bis(dithiolene)sulfidotungsten(IV) Complex with Elemental Sulfur : Functional Analogs of Polysulfide Reductase of Molybdoenzymes2011

    • Author(s)
      H.Sugimoto, R.Tajima, K.Toyota, H.Miyake, S.Itoh
    • Journal Title

      Chemistry Letters

      Volume: 40 Issue: 10 Pages: 1146-1148

    • DOI

      10.1246/cl.2011.1146

    • NAID

      10029683426

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mixed-Metal Complexes Incorporating Platinum and Lanthanide Centers for Selective Binding and Chirality Sensing of Succinates2011

    • Author(s)
      S. Shinoda, A. Mizote, M. Eiraku Masaki, M. Yoneda, H. Miyake, and H. Tsukube
    • Journal Title

      Inorg. Chem.

      Volume: 50 Issue: 13 Pages: 5876-5878

    • DOI

      10.1021/ic200853u

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Generation of bis(dithiolene)dioxo molybdenum(VI) complexes from bis(dithiolene)monooxomolybdenum(IV) complexes by proton-coupled electron transfer in aqueous media2011

    • Author(s)
      H. Sugimoto, H. Tano, H. Miyake, S. Itoh
    • Journal Title

      Dalton Transactions

      Volume: 40 Issue: 10 Pages: 2358-2365

    • DOI

      10.1039/c0dt00763c

    • Related Report
      2013 Final Research Report
  • [Journal Article] Chalcogenidobis(ene-1,2-dithiolate) molybdenum(IV) complexes (chalcogenide E = O, S, Se) : Probing MoE and ene-1,2-dithiolate substituent effects on geometric and electronic structure2011

    • Author(s)
      H. Sugimoto, H. Tano, K. Suyama, T. Kobayashi, H. Miyake, S. Itoh, R. P. Mtei, M. L. Kirk
    • Journal Title

      Dalton Transactions

      Volume: 40 Issue: 5 Pages: 1119-1131

    • DOI

      10.1039/c0dt00871k

    • Related Report
      2013 Final Research Report
  • [Journal Article] Dynamically Capped Rotaxanes: Metal Coordination vs. Acid-Base Pairing in the Chiral End-Capping2011

    • Author(s)
      S. Shinoda, T. Maeda, H. Miyake, and H. Tsukube
    • Journal Title

      Supramol. Chem.

      Volume: 23 Issue: 3-4 Pages: 244-248

    • DOI

      10.1080/10610278.2010.521838

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] カテコールの光酸化による希土類錯体の近赤外発光増強2014

    • Author(s)
      篠田哲史
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] TPEN-Nd(III)錯体を用いたキラリティープローブ法の開発2014

    • Author(s)
      國屋拓郎
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] カドミウム(II)ポルフィリンを基盤とした多点認識型レセプターの合成2014

    • Author(s)
      篠田哲史
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 硝酸アニオンをトリガーとしたトリス(2,2'-ビピリジン)金属錯体のヘリシティー反転とタイムプログラミング2014

    • Author(s)
      阪本達哉
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] キラルメタロフォルダマーの合成とらせん構造の制御2014

    • Author(s)
      藤田愛子
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] テトラアミドサイクレン―希土類錯体の新規合成法の開発2014

    • Author(s)
      佐竹良介
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Stimuli-Responsive Dynamic Molecular Motion in Labile Metal Complexes2013

    • Author(s)
      H. Miyake
    • Organizer
      Department Seminar, Center for Nanoscience, Dept. of Chemistry & Biochemistry, University of Missouri - St
    • Place of Presentation
      Louis, USA
    • Year and Date
      2013-09-06
    • Related Report
      2013 Final Research Report
  • [Presentation] Chirality Induction and Its Dynamic Control in Coordination Chemistry2013

    • Author(s)
      H. Miyake
    • Organizer
      Symmetry Festival
    • Place of Presentation
      Delft, The Netherlands
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 配位化学を活用したキラル分子プログラミング2013

    • Author(s)
      三宅弘之
    • Organizer
      第20回記念シンポジウムモレキュラー・キラリティー2013
    • Place of Presentation
      京都大学 吉田キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] NO3- Responsive Helicity Inversion of Tris(2,2'-bipyridine)-Labile Metal Complexes: Dynamic Chirality Integration from Helical Complex Terminal to Complex Center2013

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      14th International Conference on Chiroptical Spectroscopy
    • Place of Presentation
      Nashville, TN, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Stimuli-Responsive Molecular Motion in Optically Active Metal Complexes2013

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      246th ACS National Meeting & Exposition
    • Place of Presentation
      Indianapolis, IN, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] 配位化学を活用したキラル分子プログラミング2013

    • Author(s)
      三宅弘之
    • Organizer
      第20回記念シンポジウム モレキュラー・キラリティー2013
    • Place of Presentation
      京都大学 吉田キャンパス
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 同位体標識質量分析法による光学活性錯体を用いたアミノ酸の光学純度決定2013

    • Author(s)
      中小路崇
    • Organizer
      第20回記念シンポジウム モレキュラー・キラリティー2013
    • Place of Presentation
      京都大学 吉田キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] TPEN-希土類錯体を活用したアミノ酸アニオンのキラルセンシング2013

    • Author(s)
      國屋拓郎
    • Organizer
      第20回記念シンポジウム モレキュラー・キラリティー2013
    • Place of Presentation
      京都大学 吉田キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 錯体ヘリシティーの反転スイッチング;錯体から錯体へのキラル情報の伝達2013

    • Author(s)
      三宅弘之
    • Organizer
      第10回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      和歌山大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] CD法を活用したTPEN-Nd(III)錯体によるアミノ酸アニオンのキラリティーセンシング2013

    • Author(s)
      三宅弘之
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 外部刺激応答性キラル金属錯体を末端に含むトリス (2,2'-ビピリジン)金属錯体のアロステリックなヘリシティー反転2013

    • Author(s)
      三宅弘之
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] キラルな錯体を活用した動的分子スイッチの開発~キラル情報の伝達・増幅・変換2012

    • Author(s)
      三宅弘之
    • Organizer
      錯体化学若手の会近畿地区勉強会,大学利用施設 UNITY
    • Place of Presentation
      神戸
    • Year and Date
      2012-12-08
    • Related Report
      2013 Final Research Report
  • [Presentation] Coordination Chemistry-Based Approach for Dynamic Helicates2012

    • Author(s)
      H. Miyake
    • Organizer
      Department Seminar, Department of Chemistry, Faculty of Science, Chulalongkorn University
    • Place of Presentation
      THAILAND
    • Year and Date
      2012-10-25
    • Related Report
      2013 Final Research Report
  • [Presentation] Molecular Programming of Helicity Inversion in Coordination Chemistry.2012

    • Author(s)
      H. Miyake
    • Organizer
      Department Seminar, Department of Chemistry
    • Place of Presentation
      Wayne State University, USA
    • Year and Date
      2012-06-08
    • Related Report
      2013 Final Research Report
  • [Presentation] Stimuli-Responsive Dynamic Molecular Motions in Chiral Metal Complexes2012

    • Author(s)
      H. Miyake and H. Tsukube
    • Organizer
      International Conference on Emerging Advanced Nanomaterials 2012 (ICEAN-2012)
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] Helicity Switching Of Dynamic Metal Complexes Toward Supramolecular Synthesis2012

    • Author(s)
      H. Miyake, and H. Tsukube
    • Organizer
      IUPAC 8th International Conference on Novel Materials and their Synthesis (NMS-VIII) & 22nd International Symposium on Fine Chemistry and Functional Polymers (FCFP-XXII)
    • Place of Presentation
      Xi'An, P. R. China
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of a Diastereomer Pair of Square Planar Palladium(II) Complex and its Helicity Inversion2012

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      Symposium on Molecular Chirality ASIA 2012
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Dendrimeric Array of Chiral Metal Complexes: Chirality Integration and Dynamic Inversion2012

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      Symposium on Molecular Chirality ASIA 2012
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Helicity Inversion in a Square Planar Pd(II) Complex2012

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      The 24th International Symposium on Chirality (Chirality 2012)
    • Place of Presentation
      Fort Worth, Texas, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Enantioselective binding characteristics of amino acid to chiral copper(II) complex using electrospray ionization mass spectrometry coupling with the deuterium-labeled method2012

    • Author(s)
      Takashi Nakakoji
    • Organizer
      19th International Mass Spectrometry Conference (IMSC2012)
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Microwave Assisted Direct Syntheses of Optically Active Metal Complexes with Kinetically Inert Metal Centers2012

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      62nd JSCC Symposium
    • Place of Presentation
      Toyama, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Helicity Switching Of Dynamic Metal Complexes Toward Supramolecular Synthesis2012

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      IUPAC 8th International Conference on Novel Materials and their Synthesis (NMS-VIII) & 22nd International Symposium on Fine Chemistry and Functional Polymers (FCFP-XXII)
    • Place of Presentation
      Xi’An, P. R. China
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ナフチルアミド末端を含む多座配位子からなるZn(II)錯体:単核/六核錯体の変換スイッチング2012

    • Author(s)
      三宅弘之
    • Organizer
      第9回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      北海道大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] キラルTPEN-Eu(III)錯体を用いたアミノ酸基質の不斉認識2012

    • Author(s)
      三宅弘之
    • Organizer
      第9回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      北海道大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] TPEN-Eu(III)錯体を活用したアミノ酸誘導体の不斉認識:キラリティーの導入によるバイアス効果の検討2012

    • Author(s)
      三宅弘之
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 光学活性四座配位子を有する銅錯体へのアミノ酸のエナンチオ選択的錯形成挙動2012

    • Author(s)
      中小路崇
    • Organizer
      第23回基礎有機化学討論会
    • Place of Presentation
      京都テルサ
    • Related Report
      2012 Annual Research Report
  • [Presentation] 光学活性銅錯体のアミノ酸に対する光学異性体識別:マススペクトル法によるアプローチ2012

    • Author(s)
      中小路崇
    • Organizer
      日本油学会フレッシュマンサミットOSAKA2012
    • Place of Presentation
      近畿大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] キラルな錯体を活用した動的分子スイッチの開発~キラル情報の伝達・増幅・変換2012

    • Author(s)
      三宅弘之
    • Organizer
      錯体化学若手の会近畿地区勉強会
    • Place of Presentation
      大学利用施設 UNITY、神戸
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 酸塩基刺激を活用したNi(II)錯体のジオメトリースイッチング2012

    • Author(s)
      三宅弘之
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] Supramolecular Programming for Dynamic Molecular Motion in Chiral Metal Complexes2011

    • Author(s)
      H. Miyake
    • Organizer
      Department Seminar, Department of Chemistry
    • Place of Presentation
      University of Warwick, England
    • Year and Date
      2011-07-14
    • Related Report
      2013 Final Research Report
  • [Presentation] Dedox-Triggered Moleculare Motions Coupled with Helicity Switching in Chiral Cobalt Complexes2011

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      The 23rd International Symposium on Chiral Discrimination
    • Place of Presentation
      Liverpool
    • Related Report
      2011 Annual Research Report
  • [Presentation] レドックストリガーを活用したキラルコバルト錯体のマルチ分子運動2011

    • Author(s)
      三宅弘之
    • Organizer
      第7回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      広島大学東広島キャンパス
    • Related Report
      2011 Annual Research Report
  • [Presentation] キノリンアミド含有キラル多座配位子からなるpH応答発光型金属錯体の開発2011

    • Author(s)
      三宅弘之
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] キラルなTPEN型配位子を含む希土類錯体の合成と性質2011

    • Author(s)
      三宅弘之
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2011 Annual Research Report
  • [Book] Supramolecular chemistry strategies for naked-eye detection and sensing2014

    • Author(s)
      K. Singh, P. Kaur, H. Miyake and H. Tsukube, Synergy in Supramolecular Chemistry, (ed) T. Nabeshima
    • Total Pages
      400
    • Publisher
      CRC Press
    • Related Report
      2013 Final Research Report
  • [Book] Synergy in Supramolecular Chemistry2014

    • Author(s)
      Tatsuya Nabeshima
    • Publisher
      CRC Press
    • Related Report
      2013 Annual Research Report
  • [Book] 無機化学演習-大学院入試問題を中心に(化学演習シリーズ 7)2012

    • Author(s)
      中沢浩, 西岡孝訓, 篠田哲史, 廣津昌和, 三宅弘之, 板崎真澄共著, 中沢浩編
    • Total Pages
      215
    • Publisher
      東京化学同人
    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.sci.osaka-cu.ac.jp/chem/func/FC/Top.html

    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 発光性金属錯体及びその用途2011

    • Inventor(s)
      三宅弘之, 北尾和紀, 築部浩
    • Industrial Property Rights Holder
      公立大学 法人大阪市立大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2011-197545
    • Filing Date
      2011-09-09
    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 発光性金属錯体及びその用途2011

    • Inventor(s)
      三宅弘之
    • Industrial Property Rights Holder
      大阪市立大学
    • Industrial Property Number
      2011-197545
    • Filing Date
      2011-09-09
    • Related Report
      2011 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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