Construction of the spatiotemporal-molecular switching systems based on the dynamic coordination chemistry of chiral and labile metal complexes
| Project/Area Number |
23350029
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka City University |
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Principal Investigator |
MIYAKE Hiroyuki 大阪市立大学, 大学院理学研究科, 准教授 (00271198)
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥20,410,000 (Direct Cost: ¥15,700,000、Indirect Cost: ¥4,710,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2012: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2011: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
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| Keywords | 金属錯体 / らせん / 不斉 / 置換活性 / 外部刺激 / アニオン / ペプチド / 分子運動 |
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| Research Abstract |
This research work focused on the development of the spatiotemporal-chiral metal complex systems based on the dynamic coordination chemistry of labile metal complexes and the following results have been obtained; (1) helicity inversion programing in a square planar metal complex, (2) multi-switching complex based on the dynamic structural conversion of chiral metal complex, (3) chirality integration and dynamic helicity control in dendritic chiral metal complex, (4) construction of a photo-responsive chiral metal complex, (5) development of the stimuli-responsive chiral metal foldamers, (6) dynamic formation of chiral environment in highly coordinated lanthanide complexes.
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Report
(4 results)
Research Products
(58 results)
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[Journal Article] Chalcogenidobis(ene-1,2-dithiolate) molybdenum(IV) complexes (chalcogenide E = O, S, Se) : Probing MoE and ene-1,2-dithiolate substituent effects on geometric and electronic structure2011
Author(s)
H. Sugimoto, H. Tano, K. Suyama, T. Kobayashi, H. Miyake, S. Itoh, R. P. Mtei, M. L. Kirk
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Journal Title
Dalton Transactions
Volume: 40
Issue: 5
Pages: 1119-1131
DOI
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