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Development of determination method of inorganic ions by electrospray ionization mass spectrometry

Research Project

Project/Area Number 23350030
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionGunma University

Principal Investigator

TSUNODA Kin-ichi  群馬大学, 理工学研究院, 教授 (30175468)

Co-Investigator(Kenkyū-buntansha) HOTTA Hiroki  奈良教育大学, 教育学部, 准教授 (80397603)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2013: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2011: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Keywordsエレクトロスプレーイオン化質量分析法 / 無機微量分析 / オンライン脱塩法 / オキソ酸イオン / 三元錯体
Research Abstract

A determination method of inorganic ions by electrospray ionization mass spectrometry (ESIMS) has been developed. Several sample pretreatment systems including an on-line desalting system based on electrodialysis were developed to eliminate matrix effects of samples. Chromate analyses of some samples were achieved by directly measuring hydrogen chromate ion (m/z 117) by ESIMS. Moreover, it was found that dehydration reaction of inorganic oxo acids and carboxylates occurs at the interface of electrospray and their products give strong mass signals. Thus, their applications to the trace determination of the oxo acids are now being studied. New determination methods of CN- and SCN- were developed based on ternary complex formation reactions.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (30 results)

All 2013 2012 2011

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (27 results) (of which Invited: 2 results)

  • [Journal Article] Determination of Divalent Trace Metals in Soil Sample Using Electrospray Ionization Mass Spectrometry2012

    • Author(s)
      Hiroki Hotta, Yuta Kogure, and Kin-ichi Tsunoda
    • Journal Title

      Analytical Methods

      Volume: 4 Issue: 4 Pages: 1160-1162

    • DOI

      10.1039/c2ay05898g

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of Chromium(III), Chromium(VI) and Total Chromium in Chromate and Trivalent Chromium Conversion Coatings by Electrospray Ionization Mass Spectrometry2012

    • Author(s)
      Hiroki Hotta, Katsuya Yata, Kamurul Fakir Bin Kamarudin, Shota Kurihara, Kin-ichi Tsunoda, Natsuo Fumumoto, Isao Kojima, Shin-ichi Kinugasa
    • Journal Title

      Talanta

      Volume: 88 Pages: 533-536

    • DOI

      10.1016/j.talanta.2011.11.028

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New Determination Methods of Halides and Cyanide Ions by Electrospray Ionization Mass Spectrometry Based on Ternary Complex Formation2011

    • Author(s)
      Hiroki Hotta, Shota Kurihara, Keita Johno, Masaomi Kitazume, Kiichi Sato, and Kin-ichi Tsunoda
    • Journal Title

      Analytical Sciences

      Volume: 27 Issue: 9 Pages: 953

    • DOI

      10.2116/analsci.27.953

    • NAID

      130004442064

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] 電気透析を利用したフロー型脱塩セルの開発2013

    • Author(s)
      関達矢, 青木宏仁, 出口真由美, 堀田弘樹, 村田博康, 森勝伸, 角田欣一
    • Organizer
      第62回分析化学年会
    • Place of Presentation
      近畿大学東大阪キャンパス
    • Year and Date
      2013-09-10
    • Related Report
      2013 Final Research Report
  • [Presentation] インターフェースにおける脱水反応を利用するエレクトロスプレーイオン化質量分析法による無機オキソ酸の定量法の開発2013

    • Author(s)
      小島弘誓, 栗原翔太, 霜鳥一輝, 佐藤記一, 角田欣一
    • Organizer
      第3回CSJ 化学フェスタ2013
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2013 Final Research Report
  • [Presentation] エレクトロスプレーイオン化質量分析のための電気透析を利用した脱塩セルの開発2013

    • Author(s)
      堀田弘樹, 青木宏仁, 出口真由美, 村田博康, 角田欣一
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      北海道大学函館キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] エレクトロスプレーイオン化質量分析法による種々の無機オキソ酸の測定法の開発2013

    • Author(s)
      小島弘誓, 栗原翔太, 霜鳥一輝, 佐藤記一, 角田欣一
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      北海道大学函館キャンパス
    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Annual Research Report
  • [Presentation] 電気透析を利用したフロー型脱塩セルの開発2013

    • Author(s)
      関 達矢、青木宏仁、出口真由美、堀田弘樹、村田博康、森 勝伸、角田欣一
    • Organizer
      日本分析化学会第62年会
    • Place of Presentation
      近畿大学東大阪キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Determination of Inorganic Oxo Acids By Electrospray Ionization Mass Spectrometry Using Dehydration Reaction at the Interface2013

    • Author(s)
      Hirochika Kojima, Shota Kurihara, Kazuki Shimotori, Kiichi Sato, Kin-ichi Tsunoda
    • Organizer
      RSC Tokyo International Conference 2013
    • Place of Presentation
      幕張メッセ、千葉
    • Related Report
      2013 Annual Research Report
  • [Presentation] インターフェースにおける脱水反応を利用するエレクトロスプレーイオン化質量分析法による無機オキソ酸の定量法の開発2013

    • Author(s)
      小島弘誓、栗原翔太、霜鳥一輝、佐藤記一、角田欣一
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      タワーホール船堀、東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Separation of chromate in soil by ion exchange chromatography for the determination of chromium(VI) by electrospray ionization mass spectrometry2012

    • Author(s)
      Shota Kurihara, Kiichi Sato, Kin-ichi Tsunoda
    • Organizer
      RSC Tokyo International Conference
    • Place of Presentation
      Chiba
    • Year and Date
      2012-09-06
    • Related Report
      2013 Final Research Report
  • [Presentation] マイクロフロー全電解を利用した質量分析の検出感度向上に関する検討2012

    • Author(s)
      堀田弘樹, 亀山大輔, 加東遼, 前川奈央, 角田欣一, 荒川隆一
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学角間キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] 陽イオン交換・陰イオン交換カラムを用いるアルミニウム- 有機酸錯体の蛍光検出HPLC 測定2012

    • Author(s)
      霜鳥一輝, 佐藤記一, 角田欣一
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学角間キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] Separation of aluminum-organic acid complexes by cation exchange and anion exchange chromatography2012

    • Author(s)
      Kazuki Shimotori, Kiichi Sato, Kin-ichi Tsunoda
    • Organizer
      RSC-Tokyo International Conference 2012
    • Place of Presentation
      Makuhari Messe, Chiba
    • Related Report
      2013 Final Research Report
  • [Presentation] ESI-MS によるCrIII,CrVIおよび全Cr の定量法の開発2012

    • Author(s)
      栗原翔太, 堀田弘樹, 矢田勝也, カムルル・ファキル・ビンカマルディン, 佐藤記一, 角田欣一
    • Organizer
      第72回分析化学討論会
    • Place of Presentation
      鹿児島大学郡元キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] 陽イオン交換・陰イオン交換クロマトグラフィーによるアルミニウム-有機酸錯体の分離2012

    • Author(s)
      霜鳥一輝, 佐藤記一, 角田欣一
    • Organizer
      第72回分析化学討論会
    • Place of Presentation
      鹿児島大学郡元キャンパス
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] ESI-MSによるCrIII,CrVIおよび全Crの定量法の開発2012

    • Author(s)
      栗原翔太
    • Organizer
      第72回分析化学討論会
    • Place of Presentation
      鹿児島大学郡元キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] Separation of chromate in soil by ion exchange chromatography for the determination of chromium(VI) by electrospray ionization mass spectrometry2012

    • Author(s)
      Shota Kurihara
    • Organizer
      RSC Tokyo International Conference 2012
    • Place of Presentation
      幕張メッセ国際会議場(千葉)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Separation of aluminum-organic acid complexes by cation exchange and anion exchange chromatography2012

    • Author(s)
      Kazuki Shimotori
    • Organizer
      RSC Tokyo International Conference 2012
    • Place of Presentation
      幕張メッセ国際会議場(千葉)
    • Related Report
      2012 Annual Research Report
  • [Presentation] マイクロチップ電気泳動におけるビーズを用いたDNAの特異的検出法の開発2012

    • Author(s)
      霜鳥一輝
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学角間キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] Rie Saito and Kazuki Shimotori, : Application of Electrospray Ionization Mass Spectrometry to the Determination of Inorganic Ions in Environmental Samples2011

    • Author(s)
      Kin-ichi Tsunoda, Hiroki Hotta, Kiichi Sato, Shota Kurihara
    • Organizer
      CJK2011 : 2011China-Japan-Korea Symposium of Analytical Science on Food, Environment, and Nano-Technology
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2011-11-02
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Application of Electrospray Ionization Mass Spectrometry to the Determination of Inorganic Ions in Environmental Samples,, Jeju, Korea (2011.11.2)2011

    • Author(s)
      Kinichi Tsunoda, Hiroki Hotta, Kiichi Sato, Shota Kurihara, Rie Saito, Kazuki Shimotori
    • Organizer
      CJK2011 : 2011China-Japan-Korea Symposium of Analytical Science on Food, Environment, and Nano-Technology
    • Place of Presentation
      済州島、韓国(Invited)
    • Year and Date
      2011-11-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] ESI-MS による三元錯体生成を利用した微量シアン化物イオンの定量法の開発2011

    • Author(s)
      栗原翔太, 堀田弘樹, 佐藤記一, 角田欣一
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-14
    • Related Report
      2013 Final Research Report
  • [Presentation] ツバキ科植物試料中アルミニウムの分離とESI-MS によるスペシエーション分析2011

    • Author(s)
      霜鳥一輝・北爪政臣・堀田弘樹・佐藤記一・角田欣一
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-14
    • Related Report
      2013 Final Research Report
  • [Presentation] ESI-MSによる三元錯体生成を利用した微量シアン化物イオンの定量法の開発2011

    • Author(s)
      ○栗原翔太・堀田弘樹・佐藤記一・角田欣一
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] ツバキ科植物試料中アルミニウムの分離とESI-MSによるスペシエーション分析2011

    • Author(s)
      ○霜鳥一輝・北爪政臣・堀田弘樹・佐藤記一・角田欣一
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] ESI-MSによる重金属の定量のための固相抽出法を用いた前処理方法の検討2011

    • Author(s)
      ○齊藤理恵・堀田弘樹・佐藤記一・角田欣一
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] Separation of Aluminum Species in Camellia Plant Samples and Speciation Analysis for Aluminum by Electrospray Ionization Mass Spectrometry2011

    • Author(s)
      Kazuki Shimotori, Masaomi Kitazume, Hiroki Hotta, Kiichi Sato, Kin-ichi Tsunoda
    • Organizer
      JAIMA Conference 2011
    • Place of Presentation
      Makuhari
    • Year and Date
      2011-09-08
    • Related Report
      2013 Final Research Report
  • [Presentation] Electrospray ionization mass spectrometry for the determination of inorganic ions in environmental samples2011

    • Author(s)
      Kin-ichi Tsunoda
    • Organizer
      ICAS-2011
    • Place of Presentation
      Kyoto
    • Year and Date
      2011-05-23
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Electrospray ionization mass spectrometry for the determination of inorganic ions in environmental samples2011

    • Author(s)
      Kin-ichi Tsunoda
    • Organizer
      ICAS-2011
    • Place of Presentation
      京都国際会議場(Invited)
    • Year and Date
      2011-05-23
    • Related Report
      2011 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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