Developement of New Synthetic Methods for Nitrogen-containing Compounds
Project/Area Number |
23350041
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Synthetic chemistry
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Research Institution | Kyoto University |
Principal Investigator |
MURAKAMI Masahiro 京都大学, 工学(系)研究科(研究院), 教授 (20174279)
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Project Period (FY) |
2011-04-01 – 2014-03-31
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Project Status |
Completed (Fiscal Year 2013)
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Budget Amount *help |
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2013: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2012: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2011: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
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Keywords | 有機合成 / 反応開発 / 遷移金属触媒 / 含窒素化合物 / 合成化学 / 有機化学 / ヘテロ環 / 炭素-水素結合 / 含窒素複素環 / トリアゾール / 脱窒素 / 遷移金属 / メタラサイクル |
Research Abstract |
In this project, we have embarked on the development of new synthetic methods for nitrogen-containing compounds by exploiting transition metal catalysis. For example, we have developed (1) methods to incorporate nitrogen and oxygen, carbon, sulfur into unsaturated molecules, (2) new methods to generate reactive metallacycles and their synthetic applications, (3) new methods to synthesize nitrogen heterocycles via cleavage of a carbon–hydrogen bond. These new methods offer efficient ways to nitrogen-containing compounds that are otherwise difficult to access.
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Report
(4 results)
Research Products
(37 results)
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[Journal Article] Stereoselective Synthesis of 2,3-Dihydropyrroles from Terminal Alkynes, Azides, and α,β-Unsaturated Aldehydes via N-Sulfonyl-1,2,3-triazoles2013
Author(s)
Tomoya Miura, Takamasa Tanaka, Kentaro Hiraga, Scott G. Stewart, and Masahiro Murakami
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Journal Title
Journal of the American Chemical Society
Volume: 135
Issue: 37
Pages: 13652-13655
DOI
Related Report
Peer Reviewed
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