Novel catalytic function of stable 0-valent active species generated from base metal supports
| Project/Area Number |
23350044
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
TOKUNAGA MAKOTO 九州大学, 理学(系)研究科(研究院), 教授 (40301767)
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| Co-Investigator(Kenkyū-buntansha) |
ISHIDA Tamao 九州大学, 大学院・理学研究院, 准教授 (90444942)
HAMASAKI Akiyuki 九州大学, 大学院・理学研究院, 助教 (00515174)
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
Fiscal Year 2013: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
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| Keywords | 固体触媒 / 金ナノ粒子 / 酸化物担体 / コバルト / ニッケル / パラジウム / 金触媒 / パラジウム触媒 / 還元 / 有機合成 / 金 / 活性種 / フィッシャートロプシュ反応 |
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| Research Abstract |
Promotion effect of reduction of base matals was obserbed by the hydrogen reduction in the presence of noble metals including gold and plladium, ehich were supported by deposition-precipitation or co-precipitation method. Hydroformylation, hydroaminomethylation, amidocarbonylation, FT reaction, etc. were able to carried out under milder conditions compared to usual catalysts. In addition, when nickel was used as support metal, Au-Ni alloys were formed and those have high activities for debenzylation.
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Report
(4 results)
Research Products
(40 results)
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[Journal Article] Promotional effect of Au on reduction of Ni(II) to form Au-Ni alloy catalysts for hydrogenolysis of benzylic alcohols2013
Author(s)
Nishikawa, H.; Kawamoto, D.; Yamamoto, Y.; Ishida, T.; Ohashi, H.; Akita, T.; Honma, T.; Hamasaki, A.; Yokoyama, T.; Tokunaga, M
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Journal Title
J. Catal
Volume: 307
Pages: 254-264
DOI
Related Report
Peer Reviewed
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[Journal Article] X 線吸収分光法と197Au Mössbauer 分光法を組み合わせた金属酸化物担持金触媒のキャラクタリゼーション : 金合金生成の確認2012
Author(s)
川本大祐, 西川裕昭, 大橋弘範,陰地宏, 本間徹生, 小林康浩, 濱崎昭行,石田玉青, 岡上吉広, 徳永信, 横山拓史
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Journal Title
X 線分析の進歩
Volume: 43
Pages: 293-302
Related Report
Peer Reviewed
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[Journal Article] 酸化ニッケル担持金触媒の状態分析2012
Author(s)
西川裕昭, 川本大祐, 大橋弘範,陰地宏, 本間徹生, 小林康浩, 岡上吉広,濱崎昭行, 石田玉青, 横山拓史, 徳永信
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Journal Title
X 線分析の進歩
Volume: 43
Pages: 285-292
Related Report
Peer Reviewed
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