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Enhanced Faraday effect of magneto-semiconductor nanoparticles with inner and out specific interactions

Research Project

Project/Area Number 23350057
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionHokkaido University

Principal Investigator

HASEGAWA Yasuchika  北海道大学, 工学(系)研究科(研究院), 教授 (80324797)

Co-Investigator(Kenkyū-buntansha) FUSHIMI Koji  北海道大学, 大学院工学研究院 (20271645)
Project Period (FY) 2011-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
Fiscal Year 2013: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Keywords半導体 / ナノ粒子 / 希土類 / 光磁気 / ナノ結晶 / 磁気特性 / 機能材料 / 表面
Outline of Final Research Achievements

EuS nanocrystals containing paramagnetic Mn(II), Co(II), or Fe(II) ions have been prepared as advanced semiconductor materials with effective optical rotation under a magnetic field, Faraday rotation. Enhanced Faraday rotations of the EuS:M nanocrystals were observed around 550 nm, and their enhanced spin polarization was estimated using electron paramagnetic resonance (EPR) measurements.
Thin films composed of EuS nano particle aggregates on a glass electrode exhibited large magneto optical efficiency and a wide energy gap. The Verdet constant of the thin film was approximately 10 times larger than that of previously reported EuS nanoparticles. Remarkable magneto-optical properties of EuS nanocrystals linked with gold (EuS-Au nanosystem) have been demonstrated. The Faraday rotation angle of the EuS-Au nanosystem is dependent on the Au particle size and interparticle distance between EuS and Au nanocrystals. Enhancement of the Faraday rotation of EuS-Au nanosystems was observed.

Report

(4 results)
  • 2014 Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (17 results)

All 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (7 results) (of which Invited: 3 results) Remarks (2 results)

  • [Journal Article] Enhanced Magneto-optical Properties of Semiconductor EuS Nanocrystals Assisted by Surface Plasmon Resonance of Gold Nanoparticles2013

    • Author(s)
      Y. Hasegawa
    • Journal Title

      Chem. Eur. J.

      Volume: なし Issue: 43 Pages: 14438-14445

    • DOI

      10.1002/chem.201302259

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] EuS Nano-assembles Linked with Photo-functional Naphthalenedithiols2013

    • Author(s)
      Y. Hasegawa
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 579 Issue: 1 Pages: 69-76

    • DOI

      10.1080/15421406.2013.805092

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Semiconductor EuO, EuS, and EuSe Nanocrystals for Future Optical Devices2013

    • Author(s)
      Y. Hasegawa
    • Journal Title

      Chem. Lett.

      Volume: 42 Issue: 1 Pages: 2-7

    • DOI

      10.1246/cl.2013.2

    • NAID

      130004426715

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effective Optical Faraday Rotations of Semiconductor EuS Nanocrystals with Paramagnetic Transition Metal Ions2013

    • Author(s)
      Y. Hasegawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 7 Pages: 2659-2666

    • DOI

      10.1021/ja3106253

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of PbS/EuS Core/shell Nanocrystals2012

    • Author(s)
      T. Nakashima, H. Nakao, A. Tanaka, Y. Hasegawa, T. Kawai
    • Journal Title

      Chem. Lett

      Volume: 41 Issue: 4 Pages: 412-414

    • DOI

      10.1246/cl.2012.412

    • NAID

      130004426555

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 希土類配位高分子の応力発光に関する研究2011

    • Author(s)
      Y.Hasegawa, R.Hieda, K.Miyata, et al
    • Journal Title

      Eur.J.Inorg.Chem.

      Volume: 32 Issue: 32 Pages: 4978-4984

    • DOI

      10.1002/ejic.201100688

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 希土類錯体のCPL発光に関する研究2011

    • Author(s)
      J.Yuasa, T.Ohno, K.Mityata, et al
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 25 Pages: 9892-9902

    • DOI

      10.1021/ja201984u

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Size-controlled Aggregation of Cube-shaped EuS Nanocrystals with Magneto-optic Properties in Solution Phase2011

    • Author(s)
      A. Tanaka, H. Kamikubo, M. Kataoka, Y. Hasegawa, T. Kawai
    • Journal Title

      Langmuir

      Volume: 27 Issue: 1 Pages: 104-108

    • DOI

      10.1021/la103899a

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] EuS-Auナノ複合体の形成による光磁気特性変化2013

    • Author(s)
      川島祥, 中西貴之, 伏見公志, 長谷川靖哉
    • Organizer
      第30回希土類討論会
    • Place of Presentation
      北九州国際会議場(小倉)
    • Related Report
      2013 Annual Research Report
  • [Presentation] プラズモン電場増強下におけるEuS-Auナノ複合体の光磁気特性変化2013

    • Author(s)
      川島祥, 中西貴之, 藤田晃司, 田中勝久, 小泉均, 伏見公志, 長谷川靖哉
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      愛媛大学(松山)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Enhanced Farday Effect of EuS Nanocrystals with Au Nanoparticles2013

    • Author(s)
      A. Kawashima, T. Nakanishi, T. Shibayama, S. Watanabe, K. Fujita, K. Tanaka, H. Koizumi, K. Fushimi, Y. Hasegawa
    • Organizer
      Nagoya Univ.-Tsinhghua Univ.-Toyota Motor Corp.-Hokkaido Univ-.Guangxi Univ.Joint Symposium (NTTH sympo.)
    • Place of Presentation
      Guangxi Univ, Nanning (China)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 希土類ナノ結晶から構成される巨大組織体の光機能創発2013

    • Author(s)
      長谷川靖哉
    • Organizer
      公開講座 物質のひらめきー創発化学
    • Place of Presentation
      東京国際フォーラム(東京都)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Strong luminescent organo-phosphors composed of lanthanide ions and phosphine oxides2012

    • Author(s)
      Y. Hasegawa
    • Organizer
      Challenges in Advanced Chemistry of Asia, 2012 HU-NU-SNU-NIMS/MANA Joint Symposium
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] EuS nano-assembles attached with naphthalenedithiols, Challenges2012

    • Author(s)
      A. Kawashima
    • Organizer
      Challenges in Advanced Chemistry of Asia, 2012 HU-NU-SNU-NIMS/MANA Joint Symposium
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] EuS nanocrystals with Transition-metal ions2011

    • Author(s)
      Y.Hasegawa, et al
    • Organizer
      26th Rare Earth Research Conference (RERC11)
    • Place of Presentation
      New Mexico Consortium (USA)
    • Year and Date
      2011-06-19
    • Related Report
      2011 Annual Research Report
  • [Remarks] 北大院工・先端材料化学研究室

    • URL

      http://www.eng.hokudai.ac.jp/labo/amc/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 北大・先端材料化学研究室

    • URL

      http://www.eng.hokudai.ac.jp/labo/amc/index.html

    • Related Report
      2012 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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