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Development of functional iron titanium complex oxide films by control of mixed-valence state

Research Project

Project/Area Number 23350092
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionOkayama University

Principal Investigator

FUJII Tatsuo  岡山大学, 自然科学研究科, 教授 (10222259)

Co-Investigator(Kenkyū-buntansha) NAKANISHI Makoto  岡山大学, 大学院自然科学研究科, 助教 (10584085)
ICHIKAWA Kazunori  神戸市立工業高等専門学校, 准教授 (90509936)
TAKADA Jun  岡山大学, 大学院自然科学研究科, 教授 (60093259)
中西 真  岡山大学, 自然科学研究科, 助教 (10284085)
Project Period (FY) 2011-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2012: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2011: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Keywords鉄チタン複酸化物 / 混合原子価状態 / 酸化物磁性半導体 / エピタキシャル薄膜 / スパッタ法 / 高分解能電子顕微鏡観察 / イルメナイト / 希土類鉄酸化物 / ゲルマニウム置換 / 高圧合成 / メスバウアー分光 / 高分解能TEM / ホール測定 / X線構造解析 / 異方性 / ヘマタイト / ホール効果 / 微細加工
Outline of Final Research Achievements

In this study, we synthesized a single-phase of various mixed valence oxides including a hematite - ilmenite solid solution system, and surveyed their magnetic and electronic properties. Epitaxial thin films of their oxides were fabricated successfully in order to reveal and control the effects of crystal orientation and a lattice distortion on their structural and charge transfer properties. The morphology, microstructure and electric transport properties of hematite - ilmenite solid solution films were strongly influenced by the crystalline orientation. Not only the structural anisotropy of crystalline solids but also the lattice mismatch between the substrates and films played the important roles in their properties.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (22 results)

All 2015 2014 2013 2012 2011

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 1 results) Presentation (16 results) (of which Invited: 3 results)

  • [Journal Article] Microstructural Properties of (11-20)-oriented Hematite-Ilmenite Solid Solution Films2015

    • Author(s)
      Tatsuo Fujii, Tomohiro Mino, Shunsuke Kanamaru, Makoto Nakanishi, Hideki Hashimoto, Jun Takada
    • Journal Title

      Thin solid films

      Volume: 未定 Pages: 245-249

    • DOI

      10.1016/j.tsf.2015.04.028

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Mossbauer spectrum of high-pressure synthesized ilmenite-type FeGeO32014

    • Author(s)
      T. Fujii, D. Nakatsuka, M. Nakanishi, J. Takada, T. Yoshino
    • Journal Title

      Hyperfine Interactions

      Volume: in press Issue: 1-3 Pages: 1-5

    • DOI

      10.1007/s10751-014-1014-y

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, magnetic and electric properties of (110)-oriented ordered Fe2-xTixO3 thin films2014

    • Author(s)
      T. Matsumoto, N. Suzuki, S. Kanamaru, H. Hashimoto, M. Nakanishi, T. Fujii, and J. Takada
    • Journal Title

      Proceedings of 11th International Conference on Ferrites

      Volume: in press Pages: 1-3

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-pressure synthesis, crystal structure and magnetic property of ilmenite-type FeGeO32013

    • Author(s)
      D. Nakatsuka, T. Yoshino, J. Kano, H. Hashimoto, M. Nakanishi, J. Takada, T. Fujii
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 190 Pages: 520-524

    • DOI

      10.1016/j.jssc.2012.11.020

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation and superparamagnetic behaviors of LaFeO_3 nanoparticles2012

    • Author(s)
      Tatsuo Fujii
    • Journal Title

      Hyperfine Interactions

      Volume: (印刷中) Issue: 1-3 Pages: 97-100

    • DOI

      10.1007/s10751-011-0423-4

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and anomalous magnetic properties of LaFeO_3 nanoparticles by hot soap method2011

    • Author(s)
      Tatsuo Fujii
    • Journal Title

      MATERIALS CHEMISTRY AND PHYSICS

      Volume: 129 Issue: 3 Pages: 805-809

    • DOI

      10.1016/j.matchemphys.2011.05.015

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] スパッタ法による新規強誘電体薄膜YbFe2O4薄膜の作製2015

    • Author(s)
      沼田知也、中西真、狩野旬、藤井達生、池田直
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-03-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] (100)配向エピタキシャルFe2-xTixO3薄膜の作製2015

    • Author(s)
      福富大地、松本龍樹、橋本英樹、中西真、狩野旬、藤井達生
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-03-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] スパッタ法による新規電子強誘電体YbFe2O4薄膜の作製2014

    • Author(s)
      沼田知也、中西真、狩野旬、藤井達生、池田直
    • Organizer
      粉体粉末冶金協会平成26年度秋季大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2014-10-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] Microstructural Properties of (11-20)-oriented Hematite-Ilmenite Solid Solution Films2014

    • Author(s)
      Tatsuo Fujii, Tomohiro Mino, Shunsuke Kanamaru, Makoto Nakanishi, Hideki Hashimoto, Jun Takada
    • Organizer
      16th international conference on thin films
    • Place of Presentation
      Dubrovnik, Croatia
    • Year and Date
      2014-10-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] (001)配向エピタキシャルFe2-xTixO3薄膜の作製と特性評価2014

    • Author(s)
      福富大地, 松本龍樹, 橋本英樹, 中西真, 藤井達生
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] スパッタ法による鉄チタン複酸化物薄膜の作製と混合原子価制御2013

    • Author(s)
      藤井 達生
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] スパッタ法により作製した鉄チタン複酸化物薄膜の作製と混合原子価制御2013

    • Author(s)
      藤井 達生
    • Organizer
      第15回表面技術フォーラム
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Preparation, magnetic and electric properties of (110)-oriented ordered Fe2-xTixO3 thin films2013

    • Author(s)
      T. Matsumoto, N. Suzuki, S. Kanamaru, H. Hashimoto, M. Nakanishi, T. Fujii, and J. Takada
    • Organizer
      11th International Conference on Ferrites
    • Place of Presentation
      沖縄コンベンションセンター
    • Related Report
      2013 Annual Research Report
  • [Presentation] Mossbauer spectrum of high-pressure synthesized ilmenite-type FeGeO32013

    • Author(s)
      T. Fujii, D. Nakatsuka, M. Nakanishi, J. Takada, T. Yoshino
    • Organizer
      International Conference on the Applications of Mössbauer effect 2013
    • Place of Presentation
      Opatija Croatia
    • Related Report
      2013 Annual Research Report
  • [Presentation] High Resolution X-ray Fluorescence Spectra of Titanium lons in Ilmenite Crystals2012

    • Author(s)
      Fujii Tatsuo
    • Organizer
      AnaltiX-2012
    • Place of Presentation
      北京国際会議中心(中国)(招待講演)
    • Year and Date
      2012-03-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] 微細加工したFe_<2-x>Ti_xO_3薄膜の構造と電気伝導特性2012

    • Author(s)
      金丸俊介
    • Organizer
      第50回セラミックス基礎科学討論会
    • Place of Presentation
      国際ファッションセンター(東京都)
    • Year and Date
      2012-01-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] イルメナイト型FeGeO_3の高圧合成2012

    • Author(s)
      中塚大輔
    • Organizer
      第50回セラミックス基礎科学討論会
    • Place of Presentation
      国際ファッションセンター(東京都)
    • Year and Date
      2012-01-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] イルメナイト-ヘマタイト固溶体薄膜の作製とユビキタス磁性酸化物半導体への展開2012

    • Author(s)
      藤井達生
    • Organizer
      紛体粉末冶金協会平成24年度春季大会
    • Place of Presentation
      京都工芸繊維大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] High-resolution TEM observations on (110)-oriented epitaxial Fe2-xTixO3 thin films2012

    • Author(s)
      Tatsuo FUJII
    • Organizer
      IUMRS-ICEM2012
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] Preparation and electrical conduction property of (110)-oriented ordered Fe2-xTixO3 thin films2012

    • Author(s)
      Naoki Suzuki
    • Organizer
      IUMRS-ICEM2012
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] Structural properties of high-pressure synthesized ilmenite-type-FeGeO32012

    • Author(s)
      Daisuke Nakatsuka
    • Organizer
      IUMRS-ICEM2012
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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