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Development of New Materials for Organic Thin-Film Solar Cells Based on Combination of Group 14 Inorganic Elements and pi-Electron Systems

Research Project

Project/Area Number 23350097
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic industrial materials
Research InstitutionHiroshima University

Principal Investigator

OHSHITA Joji  広島大学, 工学(系)研究科(研究院), 教授 (90201376)

Co-Investigator(Kenkyū-buntansha) OOYAMA Yousuke  広島大学, 大学院・工学研究院, 准教授 (60403581)
MIZUMO Tomonobu  広島大学, 大学院・工学研究院, 助教 (90436676)
Co-Investigator(Renkei-kenkyūsha) HARIMA Yutaka  広島大学, 大学院・工学研究院, 教授 (20156524)
KUNUGI Yoshihito  東海大学, 工学部, 教授 (90243518)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥20,410,000 (Direct Cost: ¥15,700,000、Indirect Cost: ¥4,710,000)
Fiscal Year 2013: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2011: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Keywords機能性有機材料 / 有機薄膜太陽電池 / 有機ケイ素化学 / 機能高分子 / 機能性色素
Research Abstract

Conjugated polymers containing Si- or Ge-bridged pi-electron systems were prepared. Photo energy transfer and film hole mobility of the polymers were examined, showing the potential utility of the polymers as host materials of bulk hetero junction-type organic thin film solar cells. Of those, D-A type polymers that contain bridged bithiophene units as the donor, exhibited good photovoltaic properties as blend films with PC71BM. The maximal power conversion efficiency reached 6.38%.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (56 results)

All 2014 2013 2012 2011 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (40 results) (of which Invited: 8 results) Remarks (3 results)

  • [Journal Article] Effects of substituents and molecular weight on the optical, thermal, and photovoltaic properties of alternating dithienogermole-dithienylbenzothiadiazole polymers2014

    • Author(s)
      F. -B. Zhang, J. Ohshita, M. Miyazaki, D. Tanaka, Y. Morihara
    • Journal Title

      Polym. J

      Volume: (印刷中) Issue: 9 Pages: 628-631

    • DOI

      10.1038/pj.2014.35

    • NAID

      40020178751

    • Year and Date
      2014-05-28
    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of D-A Polymer with Disilanobithiophene as New Donor Component and Application to High-voltage Bulk Heterojunction Polymer Solar Cell2014

    • Author(s)
      J. Ohshita, M. Nakashima, D. Tanaka, Y. Morihara, H. Fueno, K. Tanaka
    • Journal Title

      Polym. Chem

      Volume: 5 Pages: 346-349

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and photo-induced energy and electron transfer of new donor-silicon-acceptor polymers2014

    • Author(s)
      J. Ohshita, F. Kaneko, D. Tanaka, Y. Ooyama
    • Journal Title

      Asian J. Org. Chem

      Volume: (印刷中) Issue: 2 Pages: 170-175

    • DOI

      10.1002/ajoc.201300288

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of poly(disilanylenetetracyanobutadienyleneoligothi enylene) s as new donor- acceptor type organosilicon polymers2014

    • Author(s)
      J. Ohshita, T. Kajihara, D. Tanaka, Y. Ooyama
    • Journal Title

      J. Organomet. Chem.

      Volume: 749 Pages: 255-260

    • DOI

      10.1016/j.jorganchem.2013.10.007

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of D-A Polymer with Disilanobithiophene as New Donor Component and Application to High-voltage Bulk Heterojunction Polymer Solar Cell2014

    • Author(s)
      J. Ohshita
    • Journal Title

      Polym. Chem.

      Volume: 5 Issue: 2 Pages: 346-349

    • DOI

      10.1039/c3py01157g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of substituents and molecular weight on the optical, thermal, and photovoltaic properties of alternating dithieno-germole-dithienylbenzothiadiazole polymers2014

    • Author(s)
      F.-B. Zhang
    • Journal Title

      Polymer Journal

      Volume: 印刷中

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Dithienometallole-Pyridinochalcogenadi azole Alternate Polymers2013

    • Author(s)
      J. Ohshita, M. Miyazaki, Fei-Bao. Zhang, D. Tanaka, Y. Morihara
    • Journal Title

      Polym. J

      Volume: 45 Issue: 9 Pages: 979-984

    • DOI

      10.1038/pj.2013.13

    • NAID

      10031193288

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Optical Properties of Organosiliconeoligothiophene Branched  Polymers2013

    • Author(s)
      J. OHSHITA, Y. TOMINAGA, D. TANAKA, T. MIZUMO, Y. FUJITA and Y. KUNUGI
    • Journal Title

      Journal of Organometallic Chemistry

      Volume: 736 Pages: 50-54

    • DOI

      10.1016/j.jorganchem.2013.03.007

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Dithienometallole-Pyridinochalcogenadiazole Alternate Polymers2013

    • Author(s)
      Joji Ohshita
    • Journal Title

      Polymer Journal

      Volume: 未定

    • NAID

      10031193288

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and optical properties of spirobi- (dithienometallole) s and spirobi(dithienothiametalline) s2012

    • Author(s)
      K. -H. Lee, J. Ohshita, D. Tanaka, Y. Tominaga, A. Kunai
    • Journal Title

      J. Organomet. Chem

      Volume: 710 Pages: 53-58

    • DOI

      10.1016/j.jorganchem.2012.03.012

    • NAID

      120005308240

    • Related Report
      2013 Final Research Report 2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reactions of Silicon-Bridge Dithienylbiphenyls. Fine Turning of Electronic States by Bridging Silicon Chain Lengths2012

    • Author(s)
      J. Ohshita, K. Murakami, D. Tanaka, H. Yoshida
    • Journal Title

      Heterocycles

      Volume: 86 Issue: 2 Pages: 1167-1176

    • DOI

      10.3987/com-12-s(n)72

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Dithienogermole-containing π-Conjugated Polymers and Applications to Photovoltaic Cells2011

    • Author(s)
      J. Ohshita, Y. -M. Hwang, T. Mizumo, H. Yoshida, Y. Ooyama, Y. Harima, Y. Kunugi
    • Journal Title

      Organometallics

      Volume: 30 Issue: 12 Pages: 3233-3236

    • DOI

      10.1021/om200081b

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] characterization, and photovoltaic applications of dithieno germoledithienylbenzothiadiazole and -dithienylthiazolothiazole copolymers2011

    • Author(s)
      Y. -M. Hwang, J. Ohshita, Y. Harima, T. Mizumo, Y. Ooyama, Y. Morihara T. Izawa, T. Sugioka, A. Fujita, Synthesis
    • Journal Title

      Polymer

      Volume: 52 Issue: 18 Pages: 1360-1360

    • DOI

      10.1016/j.polymer.2011.07.009

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] ジシラン架橋ビチオフェンをドナーとする新規D-A型ポリマーの合成2014

    • Author(s)
      中島真実, 大下浄治, 田中大樹
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] Donor-Si-Acceptor型ポリマーの合成と分子内電荷移動及びエネルギー移動2013

    • Author(s)
      金子文弥, 大下浄治, 大山陽介, 田中大樹
    • Organizer
      第32回無機高分子研究討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of D-A Conjugated Polymers Having the Disilane Bridged Bithiophene Structure2013

    • Author(s)
      中島真実, 大下浄治, 村上和也, 田中大樹, 田中一義, 笛野博之
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 光捕集機能を有するケイ素架橋ポリマーの合成2013

    • Author(s)
      金子文弥, 大下浄治, 大山陽介, 田中大樹
    • Organizer
      第37回有機電子移動化学討論会
    • Place of Presentation
      岡山
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 光捕集機能を有するケイ素架橋ポリマーの合成2013

    • Author(s)
      金子文弥, 大下浄治, 大山陽介, 田中大樹
    • Organizer
      第2回JACI/GSCシンポジウム
    • Place of Presentation
      大阪
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] ジシラン架橋ビチオフェン骨格を有するD-A型ポリマー2013

    • Author(s)
      中島真実, 大下浄治, 村上和也, 田中大樹
    • Organizer
      第2回JACI/GSCシンポジウム
    • Place of Presentation
      大阪
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 光捕集機能をもつ新規D-Si-A型ポリマーの合成2013

    • Author(s)
      金子文弥, 大下浄治, 大山陽介, 田中大樹
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Related Report
      2013 Final Research Report
  • [Presentation] Donor-Si-Acceptor 型ポリマーの合成と分子内電荷移動及びエネルギー移動2013

    • Author(s)
      金子文弥
    • Organizer
      第32回無機高分子研究討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Donor-Si-Acceptor 型ポリマーの合成と分子内電荷移動及びエネルギー移動の評価2013

    • Author(s)
      金子文弥
    • Organizer
      2013年日本化学会中国四国支部大会
    • Place of Presentation
      広島
    • Related Report
      2013 Annual Research Report
  • [Presentation] 金子文弥2013

    • Author(s)
      光捕集機能をもつ新規D-Si-A型ポリマーの合成
    • Organizer
      日本化学会第93回春季年会
    • Place of Presentation
      滋賀
    • Related Report
      2012 Annual Research Report
  • [Presentation] 14族元素の特性を活かした有機太陽電池材料へのアプローチ2012

    • Author(s)
      大下浄治
    • Organizer
      物質・デバイス領域共同研究拠点H24年度物質機能化学研究領域第1回研究集会
    • Place of Presentation
      福岡
    • Year and Date
      2012-11-29
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] ジシラン架橋したビフェニル・ビチオフェンを含むπ共役ポリマーの合成2012

    • Author(s)
      中島真実, 村上和也, 大下浄治
    • Organizer
      第6回有機π電子系シンポジウム
    • Place of Presentation
      愛媛
    • Related Report
      2013 Final Research Report
  • [Presentation] Applications of Dithienometalloles as Polymer Solar Cell Materials2012

    • Author(s)
      J. Ohshita
    • Organizer
      第3回機能性物質創成研究拠点国際シンポジウム
    • Place of Presentation
      つくば
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Invited
  • [Presentation] アクセプターとしてテトラシアノブタジエニル基を用いたD-A型有機ケイ素ポリマーの合成2012

    • Author(s)
      梶原知成, 小田祐一郎, 田中大樹, 大山陽介, 大下浄治
    • Organizer
      第31回無機高分子研究討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] ジチエノグルモールを有する新規共役系高分子の合成と有機薄膜太陽電池への応用2012

    • Author(s)
      宮崎真行, 大下浄治, 張飛豹, 田中大樹
    • Organizer
      第31回無機高分子研究討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] Si-Si結合へのベンザインの挿入反応を用いた新規環状有機ケイ素化合物の合成2012

    • Author(s)
      村上和也, 大下浄治, 吉田拡人, 大山陽介, 水雲智信
    • Organizer
      第59回有機金属化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2013 Final Research Report
  • [Presentation] ドナー-ケイ素-アクセプター型化合物の合成と光学的特性の評価2012

    • Author(s)
      金子文弥, 大下浄治, 田中大樹, 大山陽介, 水雲智信, 播磨裕
    • Organizer
      第36回有機電子移動化学討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis, Characterization and Photovoltaic Applications of Dithienogermole-containing Polymers2012

    • Author(s)
      Fei-Bao Zhang, J. Ohshita, Y. Morihara, A. Fujita, H. Ogi
    • Organizer
      THE 10TH INTERNATIONAL CONFERENCE ON HETEROATOM CHEMISTRY
    • Place of Presentation
      京都
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] Synthesis of Dithienometalole-Pyridinothiadiazol e Alternate Polymers for Organic Photovoltaics2012

    • Author(s)
      M. Miyazaki, J. Ohshita, Y. Morihara, A. Fujita, H. Ogi
    • Organizer
      THE 10TH INTERNATIONAL CONFERENCE ON HETEROATOM CHEMISTRY
    • Place of Presentation
      京都
    • Related Report
      2013 Final Research Report
  • [Presentation] 電子供与性基と電子求引性基を有する非対称型ジチエノシロール誘導体の合成と発光特性2012

    • Author(s)
      冨永勇太, 水雲智信, 大下浄治
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] Synthesis of Dithienometalole-Pyridinothiadiazole Alternate Polymers for Organic Photovoltaics2012

    • Author(s)
      Masayuki Miyazaki
    • Organizer
      THE 10TH INTERNATIONAL CONFERENCE ON HETEROATOM CHEMISTRY
    • Place of Presentation
      京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] ドナー-ケイ素-アクセプター型化合物の合成と光学的特性の評価2012

    • Author(s)
      金子文弥
    • Organizer
      第36回 有機電子移動化学討論会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] Si-Si結合へのベンザインの挿入反応を用いた新規環状有機ケイ素化合物の合成2012

    • Author(s)
      村上和也
    • Organizer
      第59回 有機金属化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2012 Annual Research Report
  • [Presentation] ジチエノグルモールを有する新規共役系高分子の合成と有機薄膜太陽電池への応用2012

    • Author(s)
      宮﨑真行
    • Organizer
      第31回 無機高分子研究討論会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] アクセプターとしてテトラシアノブタジエニル基を用いたD-A型有機ケイ素ポリマーの合成2012

    • Author(s)
      梶原知成
    • Organizer
      第31回 無機高分子研究討論会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] ジシラン架橋したビフェニル・ビチオフェンを含むπ共役ポリマーの合成2012

    • Author(s)
      中島真実
    • Organizer
      第6回有機π電子系シンポジウム
    • Place of Presentation
      愛媛
    • Related Report
      2012 Annual Research Report
  • [Presentation] 有機ケイ素ユニットをコアとする星型オリゴチオフェン類の合成と高分子化2012

    • Author(s)
      大下浄治
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 14族元素の特性を活かした有機太陽電池材料へのアプローチ2012

    • Author(s)
      大下浄治
    • Organizer
      物質・デバイス領域共同研究拠点 平成24年度物質機能化学研究領域部会第1回研究集会
    • Place of Presentation
      福岡
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Synthesis of Dithienometalloles as New Conjugated Materials2012

    • Author(s)
      J.Ohshita
    • Organizer
      The 7th International Symposium on Integrated Synthesis
    • Place of Presentation
      兵庫(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of Dithienometalloles as New Conjugated Materials2011

    • Author(s)
      J. Ohshita
    • Organizer
      The 7th International Symposium on Integrated Synthesis
    • Place of Presentation
      兵庫
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] ドナーアクセプター構造を有する新規有機ケイ素ポリマーの合成と有機太陽電池への応用2011

    • Author(s)
      田中大樹, 大下浄治, 大山陽介, 播磨裕, 森原靖, 伊澤隆文, 杉岡尚
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] ジチエノゲルモールを含むπ共役ポリマーの合成と薄膜太陽電池への応用2011

    • Author(s)
      大下浄治
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Related Report
      2013 Final Research Report
  • [Presentation] 電子求引性置換基を有するジチエノシロール誘導体の合成と発光特性2011

    • Author(s)
      冨永勇太, 水雲智信, 大下浄治, 小林憲史, 東村秀之
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] Synthesis and Applications of Dithienometalloles2011

    • Author(s)
      J. Ohshita
    • Organizer
      The 6th Japan-Taiwan Bilateral Symposium on Architecture of Functional Organic Molecules
    • Place of Presentation
      東広島
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Synthesis, Optical Properties, and Functionalities of Dithienometalloles2011

    • Author(s)
      J. Ohshita
    • Organizer
      The 14th Asian Chemical Congress
    • Place of Presentation
      バンコク(タイ)
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Synthesis and Functionalities of Dithienosiloles and Related Compounds2011

    • Author(s)
      J. Ohshita
    • Organizer
      27th Workshop on Silicon Chemistry
    • Place of Presentation
      Wonju(韓国)
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Synthesis, Optical Properties, and Functionalities of Dithienometalloles2011

    • Author(s)
      J.Ohshita
    • Organizer
      The 14tli Asian Chemical Congress
    • Place of Presentation
      バンコク(タイ)(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis and Applications of Dithienometalloles2011

    • Author(s)
      J.Ohshita
    • Organizer
      The 6th Japan-Taiwan Bilateral Symposium on Architecture of Functional Organic Molecules
    • Place of Presentation
      東広島(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis and Functionalities of Dithienosiloles and Related Compounds2011

    • Author(s)
      J.Ohshita
    • Organizer
      27th Workshop on Silicon Chemistry
    • Place of Presentation
      Wonju, Korea(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] ジチエノゲルモールを含むπ共役ポリマーの合成と薄膜太陽電池への応用2011

    • Author(s)
      大下浄治
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山(依頼講演)
    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://home.hiroshima-u.ac.jp/orgmtrls/Ohshita_Group/Ohshita_Group-Home.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 広島大学有機材料化学研究室

    • URL

      http://home.hiroshima-u.ac.jp/orgmtrls/Ohshita_Group/Ohshita_Group-Home.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://home.hiroshima-u.ac.jp/orgmtrls/Ohshita_Group/Ohshita_Grdup-Home.html

    • Related Report
      2011 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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