• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Structural Formation and Functionality Expression Originated by Polymeric Molecular Entanglements

Research Project

Project/Area Number 23350109
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionGunma University

Principal Investigator

UEHARA Hiroki  群馬大学, 理工学研究院, 准教授 (70292620)

Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2013: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2012: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2011: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Keywords分子鎖絡み合い / 結晶化 / ポリエチレン / 超高分子量 / ナノポーラス膜 / 薄膜 / 溶融延伸 / 医用材料
Research Abstract

In this study, we successfully prepared the nanowrinkled PE membranes with network of 30nm-thickness homogeneous lamellae using a novel entanglement control technique composed of biaxial melt-drawing and melt-shrinking procedures, which were limited for highly entangled ultra-high molecular weight materials. Such a network arrangement of nanowrinkled lamellae spreading not only on membrane surface but also across membrane thickness improves the mechanical properties of both tensile strength and tearing strength. Subsequent cold-drawing causes delamination of the lamellar interfaces, leading to the resultant nanoporous morphology composed of passing-through channels several tens of nanometers in diameter without any solvent processing.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (51 results)

All 2014 2013 2012 2011 Other

All Journal Article (28 results) (of which Peer Reviewed: 26 results) Presentation (19 results) (of which Invited: 3 results) Book (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Robust and Transparent Membrane of Crystalline Silicone via Melt-Drawing Technique2014

    • Author(s)
      Hiroki Uehara, Tomohiro Obana, Masaki Kakiage, Hidekazu Tanaka, Hiroyasu Masunaga, Takeshi Yamanobe, Eiichi Akiyama
    • Journal Title

      J. Mater. Chem. C

      Volume: Vol. 2, No. 2 Pages: 373-381

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] In-situ SAXS Analysis during Uniaxial Drawing of Polyethyleneblock-Polystyrene Copolymer Film2014

    • Author(s)
      Hiroki Uehara, Masaki Kakiage, Hidekazu Tanaka, Takeshi Yamanobe
    • Journal Title

      Key Eng. Mater

      Volume: Vol. 596 Pages: 50-54

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] In-situ NMR Measurement of Novel Silicone Elastomer Obtained by Cross-Linking of Silicones Having Phenylene Backbone and Hyperbranched Molecular Architectures2014

    • Author(s)
      Hiroki Uehara, Masazumi Saitoh, Ryosuke Morita, Eiichi Akiyama, Takeshi Yamanobe
    • Journal Title

      Macromoleucles

      Volume: Vol. 47, No.3 Pages: 888-896

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Non-Solvent Processing for Robust but Thin Membrane of Ultra-High Molecular Weight Polyethylene2014

    • Author(s)
      Hiroki Uehara, Takuya Tamura, Kazuki Hashidume, Hidekazu Tanaka, Takeshi Yamanobe
    • Journal Title

      J. Mater. Chem. A

      Volume: Vol. 2, No. 15 Pages: 5252-5257

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] インプロセスNMR 計測による新規シリコーンの架橋反応追跡とエラストマー特性2014

    • Author(s)
      上原宏樹, 山延健, 秋山映一
    • Journal Title

      プラスチックス

      Volume: 5 月号(印刷中)

    • Related Report
      2013 Final Research Report
  • [Journal Article] Highly Transparent and Robust Poly(tetrafluoroethylene) Membrane Prepared by Biaxial Melt-Drawing2014

    • Author(s)
      Hiroki Uehara et al.
    • Journal Title

      Macromol. Mater. Eng.

      Volume: 299 Issue: 6 Pages: 669-673

    • DOI

      10.1002/mame.201300310

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-situ NMR Measurement of Novel Silicone Elastomer Obtained by Cross-Linking of Silicones Having Phenylene Backbone and Hyperbranched Molecular Architectures2014

    • Author(s)
      Hiroki Uehara et al.
    • Journal Title

      Macromolecules

      Volume: 47 Issue: 3 Pages: 888-896

    • DOI

      10.1021/ma402291e

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non-Solvent Processing for Robust but Thin Membrane of Ultra-High Molecular Weight Polyethylene2014

    • Author(s)
      Hiroki Uehara et al.
    • Journal Title

      J. Mater. Chem. A

      Volume: 2 Issue: 15 Pages: 5252-5257

    • DOI

      10.1039/c3ta15125e

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 走査プローブ顕微鏡を用いたナノ・スクラッチ試験による高分子表面の構造・物性解析2013

    • Author(s)
      上原宏樹, 山延健
    • Journal Title

      成形加工

      Volume: Vol. 25, No. 8 Pages: 367-371

    • NAID

      130007960816

    • Related Report
      2013 Final Research Report
  • [Journal Article] Tetraalkoxyphenanthrene-Fused Dehydroannulenes: Synthesis, Electronic, Optical, and Electrochemical Properties, and Self-Assembly2013

    • Author(s)
      Shin-ichiro Kato et al.
    • Journal Title

      Chemistry - A European Journal

      Volume: 19 Issue: 36 Pages: 12138-12151

    • DOI

      10.1002/chem.201301262

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application and analysis of a DSC-Raman spectroscopy for indium and poly(lactic acid)2013

    • Author(s)
      T. Suzuki et al.
    • Journal Title

      J. Therm. Anal. Calorim.

      Volume: 113 Issue: 3 Pages: 1543-1549

    • DOI

      10.1007/s10973-013-3098-z

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Robust and Transparent Membrane of Crystalline Silicone via Melt-Drawing Technique2013

    • Author(s)
      Hiroki Uehara et al.
    • Journal Title

      J. Mater. Chem. C

      Volume: 2 Issue: 2 Pages: 373-381

    • DOI

      10.1039/c3tc31265h

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-situ SAXS Analysis during Uniaxial Drawing of Polyethylene-block-Polystyrene Copolymer Film2013

    • Author(s)
      Hiroki Uehara et al.
    • Journal Title

      Key Eng. Mater.

      Volume: 596 Pages: 50-54

    • DOI

      10.4028/www.scientific.net/kem.534.71

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanowrinkled and Nanorporous Polyethylene Membrane via Entanglement Arrangement Control2013

    • Author(s)
      Hiroki Uehara
    • Journal Title

      Advanced Functional Materials

      Volume: 22 Issue: 10 Pages: 2048-2057

    • DOI

      10.1002/adfm.201102474

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reconstruction of Calorimetric Curves from X-ray Diffraction Data during the Melting-Recrystallization Process of Polymers : Simultaneous Calorimetric/X-ray Diffraction Measurements of Isotactic Polybutene- 1 in Form III2012

    • Author(s)
      Hiroshi Takahashi, Kenichiro Shimada, Yuzo Yamamoto, Hiroki Uehara
    • Journal Title

      J. Macromol. Sci., Pt.B : Phys

      Volume: Vol. 51, No. 2 Pages: 338-347

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nanowrinkled and Nanorporous Polyethylene Membrane via Entanglement Arrangement Control2012

    • Author(s)
      Hiroki Uehara, Takuya Tamura, Masaki Kakiage, Takeshi Yamanobe
    • Journal Title

      Adv. Funct. Mater

      Volume: Vol. 22, No.10 Pages: 2048-2057

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solid-State 1H-NMR Relaxation Behavior for Ultra-High Molecular Weight Polyethylene Reactor Powders Having Different Morphologies2012

    • Author(s)
      Hiroki Uehara, Hidekazu Tanaka, Takeshi Yamanobe
    • Journal Title

      Polym. J

      Volume: Vol. 44, No.8 Pages: 795-801

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phase Transition of Poly(tetramethyl-psilphenylenesiloxane) As Revealed by In-Situ X-ray and NMR Measurements2012

    • Author(s)
      Hiroki Uehara, Tomohiro Obana, Masaki KakiageHiroki Uehara, Tomohiro Obana, Masaki Kakiage
    • Journal Title

      Macromolecules

      Volume: Vol. 45, No.18 Pages: 7446-7453

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 高分子材料の延伸過程におけるin-situ NMR測定法の開発と応用2012

    • Author(s)
      山延健
    • Journal Title

      高分子論文集

      Volume: 69 Pages: 235-241

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure and molecular mobility of nascent isotactic polypropylene powders2012

    • Author(s)
      Takeshi Yamanobe
    • Journal Title

      Polymer Journal

      Volume: 44 Issue: 8 Pages: 764-771

    • DOI

      10.1038/pj.2012.121

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solid-state 1H-NMR relaxation behavior for ultra-high-molecular-weight polyethylene reactor powders with different morphologies2012

    • Author(s)
      Hiroki Uehara
    • Journal Title

      Polymer Journal

      Volume: 44 Issue: 8 Pages: 795-801

    • DOI

      10.1038/pj.2012.104

    • NAID

      10030931359

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase Transition of Poly(tetramethyl-p-silphenylenesiloxane) As Revealed by In-Situ X-ray and NMR Measurements2012

    • Author(s)
      Hiroki Uehara
    • Journal Title

      Macromolecules

      Volume: 45 Issue: 18 Pages: 7446-7453

    • DOI

      10.1021/ma300881q

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Simultaneous DSC/X-ray measurements for quasi-melting/crystallization behavior of Form III-isotactic Polybutene-12012

    • Author(s)
      Hiroshi Takahashi
    • Journal Title

      J.Macromol.Sci., Pt.B : Phys.

      Volume: 51 Pages: 338-347

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanowrinkled and Nanorporous Polyethylene Membrane via Entanglement Arrangement Control2012

    • Author(s)
      Hiroki Uehara
    • Journal Title

      Adv.Funct.Mater.

      Volume: 22(in press)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Change with Blending of Crystalline/Amorphous Block Copolymers Having Different Types of Microphase Separations2011

    • Author(s)
      Masaki Kakiage, Miho Sekiya, Takeshi Yamanobe, Hiroki Uehara
    • Journal Title

      Polymer

      Volume: Vol. 52, No. 26 Pages: 6146-6153

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Protein Crystallization Induced by Strong Photons-molecules Coupling Fields Photochemical Reaction2011

    • Author(s)
      Susumu Haruta
    • Journal Title

      Journal of Photochemistry and Photobiology A : Chemistry

      Volume: 221 Pages: 268-272

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Change with Blending of Crystalline/Amorphous Block Copolymers Having Different Types of Microphase Separations2011

    • Author(s)
      Masaki Kakiage
    • Journal Title

      Polymer

      Volume: 52 Pages: 6146-6153

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Transparent and Robust Poly(tetrafluoroethylene) Membrane Prepared by Biaxial Melt-Drawing

    • Author(s)
      Hiroki Uehara, Yuuki Arase, Ken Suzuki, Yasumasa Yukawa, Yoshiaki Higuchi, Yasuhiko Matsuoka, Takeshi Yamanobe
    • Journal Title

      Macromol. Mater. Eng.

      Volume: (印刷中)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] 高分子材料の延伸過程におけるインプロセス計測と高性能化・高機能化2013

    • Author(s)
      上原宏樹
    • Organizer
      第22回ポリマー材料フォーラム(高分子学会)
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2013-11-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 超高分子量樹脂の溶融延伸過程における配向結晶化のインプロセス計測2013

    • Author(s)
      上原宏樹, 山延健
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2013-09-13
    • Related Report
      2013 Final Research Report
  • [Presentation] 固体1H-NMRによる超高分子量ポリエチレン重合パウダーの特徴付け2013

    • Author(s)
      上原宏樹, 田中秀和, 山延健
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2013-09-12
    • Related Report
      2013 Final Research Report
  • [Presentation] Nanostructural Formation of UltraHigh Molecular Weight Polyethylene Membranes via Entanglement Arrangement Control2013

    • Author(s)
      Hiroki Uehara, Takeshi Yamanobe
    • Organizer
      10th IUPAC International Conference on Advanced Polymers via Macromolecular Engineering
    • Place of Presentation
      Durham (U. K.)
    • Year and Date
      2013-08-20
    • Related Report
      2013 Final Research Report
  • [Presentation] 汎用性高分子材料のナノ構造制御による高性能化・高機能化2013

    • Author(s)
      上原宏樹
    • Organizer
      第41回東北地区高分子若手研究会夏季ゼミナール(高分子学会東北支部)
    • Place of Presentation
      磐梯熱海温泉・清稜山倶楽部
    • Year and Date
      2013-08-06
    • Related Report
      2013 Final Research Report
  • [Presentation] 溶剤を用いない超高分子量ポリエチレン薄膜・微多孔膜の製造技術2013

    • Author(s)
      上原宏樹
    • Organizer
      第2回JACI/GSCシンポジウム(第13回GSCシンポジウム)
    • Place of Presentation
      メルパルク大阪
    • Year and Date
      2013-06-07
    • Related Report
      2013 Final Research Report
  • [Presentation] Confined Stereo-Complex Crystallization with Property Development of High Molecular Weight Poly(lactic acid) in Block-Copolymer Phase Separation2012

    • Author(s)
      Hiroki Uehara, Shizuka Wada, Makiko Kano, Hidekazu Tanaka, Takeshi Yamanobe
    • Organizer
      International Conference on Advanced Micro-Device Engineering (AMDE 2012)
    • Place of Presentation
      Kiryu (Gunma)
    • Year and Date
      2012-12-07
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] 結晶性高分子の表面偏析による階層構造形成と表面物性2012

    • Author(s)
      上原宏樹, 山延健
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2012-09-20
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] 延伸技術による汎用高分子の構造制御とインプロセス解析2012

    • Author(s)
      上原宏樹
    • Organizer
      高分子学会岡山地区懇話会講演会
    • Place of Presentation
      岡山大学50周年記念館
    • Year and Date
      2012-07-09
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] 溶媒を用いない超高分子量ポリエチレン薄膜・多孔膜の製造方法2012

    • Author(s)
      上原宏樹, 田村拓也, 撹上将規, 山延健
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2012-05-30
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] Structural Deformation during Melt-Drawing of Ultra-High Molecular Weight / Normal Molecular Weight Polyethylene Blend Films with Different Blend Ratios2012

    • Author(s)
      Hiroki Uehara
    • Organizer
      International Conference on Advanced Micro-Device Engineering (AMDE 2012)
    • Place of Presentation
      Kiryu (Gunma)
    • Related Report
      2012 Annual Research Report
  • [Presentation] anoporous Polyethylene Membranes for Glucose Sensors2011

    • Author(s)
      Hiroki Uehara
    • Organizer
      5th European Conference of the International Federation for Medical and Biological Engineering
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2011-09-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Nanoporous Polyethylene Membranes for Glucose Sensors2011

    • Author(s)
      H. Uehara, M. Kakiage, M. Sekiya, D. Sakuma, T. Yamanobe, N. Takano, A. Barraud, E. Meurville, P. Ryser
    • Organizer
      5th European Conference of the International Federation for Medical and Biological Engineering (EMBEC2011)
    • Place of Presentation
      Budapest (Hungary)
    • Year and Date
      2011-09-16
    • Related Report
      2013 Final Research Report
  • [Presentation] 溶剤を用いない超高分子量ポリエチレン薄膜・微多孔膜の製造技術

    • Author(s)
      上原宏樹
    • Organizer
      第2回 JACI/GSCシンポジウム(第13回 GSCシンポジウム)
    • Place of Presentation
      メルパルク大阪
    • Related Report
      2013 Annual Research Report
  • [Presentation] Nanostructural Formation of Ultra-High Molecular Weight Polyethylene Membranes via Entanglement Arrangement Control

    • Author(s)
      Hiroki Uehara
    • Organizer
      10th IUPAC International Conference on Advanced Polymers via Macromolecular Engineering
    • Place of Presentation
      Durham, U.K.
    • Related Report
      2013 Annual Research Report
  • [Presentation] 汎用性高分子材料のナノ構造制御による高性能化・高機能化

    • Author(s)
      上原宏樹
    • Organizer
      第41回東北地区高分子若手研究会夏季ゼミナール(高分子学会東北支部)
    • Place of Presentation
      郡山市
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 固体1H-NMRによる超高分子量ポリエチレン重合パウダーの特徴付け

    • Author(s)
      上原宏樹
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 超高分子量樹脂の溶融延伸過程における配向結晶化のインプロセス計測

    • Author(s)
      上原宏樹
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 高分子材料の延伸過程におけるインプロセス計測と高性能化・高機能化

    • Author(s)
      上原宏樹
    • Organizer
      第22回ポリマー材料フォーラム(高分子学会)
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] 超高分子量ポリエチレンの溶融超延伸過程におけるインプロセス計測とフィルム高性能化, 高分子の結晶制御技術と応用 , 鞠谷雄士編集2012

    • Author(s)
      上原宏樹, 撹上将規, 山延健
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Final Research Report
  • [Book] 高分子の結晶制御技術と応用2012

    • Author(s)
      上原宏樹(分担、鞠谷雄士編)
    • Total Pages
      283
    • Publisher
      シーエムシー出版
    • Related Report
      2012 Annual Research Report
  • [Book] 広がる核磁気共鳴NMRの世界~40人のNMR研究者からの熱いメッセージ~2011

    • Author(s)
      朝倉哲郎
    • Publisher
      コロナ社
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] ポリエチレン製多孔質膜の製造方法およびポリエチレン製多孔質膜2012

    • Inventor(s)
      上原宏樹・山延健・田中秀和
    • Industrial Property Rights Holder
      群馬大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-289287
    • Filing Date
      2012-08-29
    • Related Report
      2013 Final Research Report 2012 Annual Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi