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Relaxation of entangled polymers under fast flow

Research Project

Project/Area Number 23350113
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKyoto University

Principal Investigator

MASUBUCHI Yuichi  京都大学, 化学研究所, 准教授 (40291281)

Co-Investigator(Kenkyū-buntansha) WATANABE Hiroshi  京都大学, 化学研究所, 教授 (90167164)
MATSUMIYA Yumi  京都大学, 化学研究所, 助教 (00378853)
UNEYAMA Takashi  京都大学, 化学研究所, 助教 (10524720)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥20,020,000 (Direct Cost: ¥15,400,000、Indirect Cost: ¥4,620,000)
Fiscal Year 2013: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2012: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2011: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Keywords高分子 / レオロジー / 誘電緩和 / シミュレーション / ダイナミクス / モデリング / 粘弾性 / からみあい / 粗視化モデル / 大変形 / 非線形粘弾性 / 粘弾性緩和
Research Abstract

In this study we focused on polymer dynamics under fast flow. We performed viscoelastic and dielectric measurements under fast flow. By particle tracking velocimetry, we confirmed that the dielectric relaxation is not accelerated under fast uniform shear field. To explain this result, we constructed a semi-phenomenological dumbbell model with non-isotropic, flow-rate dependent friction constant for polymer. The flow-rate dependence of the friction was extracted from experimental data for stress relaxation after cessation of fast elongational flows. We implemented the flow-rate dependent friction into a molecular model that is able to semi-quantitatively predict viscoelasticity of polymers under fast flows.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (52 results)

All 2014 2013 2012 2011 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (37 results) (of which Invited: 21 results) Remarks (1 results)

  • [Journal Article] Rheo-Dielectric Responses of Entangled cis-Polyisoprene under Uniform Steady Shear and LAOS2014

    • Author(s)
      K. Horio, T. Uneyama, Y. Matsumiya, Y. Masubuchi, and H. Watanabe
    • Journal Title

      Macromolecules

      Volume: 47 (1) Issue: 1 Pages: 246-255

    • DOI

      10.1021/ma402100t

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Simulating the Flow of Entangled Polymers2014

    • Author(s)
      Yuichi Masubuchi
    • Journal Title

      Annual Review of Chemical and Biomolecular Engineering

      Volume: 5 Issue: 1 Pages: 11-33

    • DOI

      10.1146/annurev-chembioeng-060713-040401

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recovering the reptation dynamics of polymer melts in dissipative particle dynamics simulations via slip-springs2013

    • Author(s)
      M. Langeloth, Y. Masubuchi, M. C. Böhm, and F. Müller-Plathe
    • Journal Title

      J. Chem. Phys.

      Volume: 138 Issue: 10

    • DOI

      10.1063/1.4794156

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stretch/orientation Induced Acceleration in Stress Relaxation in Coarse-grained Molecular Dynamics Simulations2013

    • Author(s)
      Y. Masubuchi, T. Yaoita, Y. Matsumiya, H. Watanabe, G. Ianniruberto and G. Marrucci
    • Journal Title

      Nihon Reoroji Gakkaishi

      Volume: 41 Issue: 1 Pages: 35-37

    • DOI

      10.1678/rheology.41.35

    • NAID

      130004436489

    • ISSN
      0387-1533, 2186-4586
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extensional Rheology of Entangled Polystyrene Solutions Suggests Importance of Nematic Interactions2013

    • Author(s)
      Qian Huang, Nicolas J. Alvarez, Yumi Matsumiya, Henrik K. Rasmussen, Hiroshi Watanabe, and Ole Hassager
    • Journal Title

      ACS Macro Letters

      Volume: 2 Issue: 8 Pages: 741-744

    • DOI

      10.1021/mz400319v

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cross-Correlation Contributions to Orientational Relaxations in Primitive Chain Network Simulations2013

    • Author(s)
      Yuichi Masubuchi
    • Journal Title

      Nihon Reoroji Gakkaishi

      Volume: 41 Issue: 1 Pages: 1-6

    • DOI

      10.1678/rheology.41.1

    • NAID

      130004436485

    • ISSN
      0387-1533, 2186-4586
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nonlinear Stress Relaxation of Scarcely Entangled Chains in Primitive Chain Network Simulations2013

    • Author(s)
      Kenji Furuichi
    • Journal Title

      Nihon Reoroji Gakkaishi

      Volume: 41 Issue: 1 Pages: 13-19

    • DOI

      10.1678/rheology.41.13

    • NAID

      130004436486

    • ISSN
      0387-1533, 2186-4586
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crossover time in relative fluctuations characterizes the longest relaxation time of entangled polymers2012

    • Author(s)
      Uneyama, T., Masubuchi, Y
    • Journal Title

      Journal of Chemical Physics

      Volume: 137 Issue: 15

    • DOI

      10.1063/1.4758320

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Primitive Chain Network Simulation of Elongational Flows of Entangled Linear Chains : Stretch/Orientation-induced Reduction of Monomeric Friction2012

    • Author(s)
      T. Yaoita, T. Isaki, Y. Masubuchi, H. Watanabe, G. Ianniruberto, and G. Marrucci
    • Journal Title

      Macromolecules

      Volume: vol.45 Issue: 6 Pages: 2773-2782

    • DOI

      10.1021/ma202525v

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Primitive chain network simulations for comb-branched polymer under step shear deformations2012

    • Author(s)
      Y. Masubuchi, Y. Matsumiya, H. Watanabe, S. Shiromoto, M. Tsutsubuchi, and Y. Togawa
    • Journal Title

      Rheol. Acta

      Volume: vol.51 Issue: 3 Pages: 192-200

    • DOI

      10.1007/s00397-011-0574-x

    • NAID

      120003988347

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A multiscale simulation of polymer processing using parameter-based bridging in melt rheology2012

    • Author(s)
      Yuichi Masubuchi
    • Journal Title

      Journal of Applied Polymer Science and Engineering

      Volume: 125 Issue: 4 Pages: 2740-2747

    • DOI

      10.1002/app.36593

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anisotropic Mobility Model for Polymers under Shear and its Linear Response Functions2011

    • Author(s)
      T. Uneyama, K. Horio, and H. Watanabe
    • Journal Title

      Phys. Rev. E

      Volume: vol.83 Issue: 6 Pages: 1-15

    • DOI

      10.1103/physreve.83.061802

    • NAID

      120003324601

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Numerical study of chain conformation on shear banding using diffusiveRolie-Poly model2011

    • Author(s)
      C. Chung, T. Uneyama, Y. Masubuchi, and H. Watanabe
    • Journal Title

      Rheol. Acta

      Volume: vol.50 Issue: 9-10 Pages: 753-766

    • DOI

      10.1007/s00397-011-0554-1

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Primitive Chain Network Simulation of Elongational Flows of Entangled Linear Chains : 1. Role of Finite Chain Extensibility2011

    • Author(s)
      T. Yaoita, T. Isaki, Y. Masubuchi, H. Watanabe, G. Ianniruberto, and G. Marrucci
    • Journal Title

      Macromolecules

      Volume: vol.44 Issue: 24 Pages: 9675-9682

    • DOI

      10.1021/ma202166y

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] 高分子ダイナミクスのシミュレーション2014

    • Author(s)
      増渕雄一
    • Organizer
      第12回高分子ナノテクノロジー研究講座
    • Place of Presentation
      産業技術総合研究所(東京)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 分子描像に基づく成形加工シミュレーションの現状2014

    • Author(s)
      増渕雄一
    • Organizer
      プラスチック成形加工学会関西支部第21回講演会
    • Place of Presentation
      大阪市工業研究所
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 高分子レオロジーのシミュレーションの現状と今後の課題2014

    • Author(s)
      増渕雄一
    • Organizer
      先端化学・材料技術部会 コンピュータケミストリ分科会『高分子材料シミュレーション-OCTA活用事例集』出版記念講演会
    • Place of Presentation
      新化学技術推進協会
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Stress relaxation of entangled polystyrene solution after constant-rate, uniaxial elongation2013

    • Author(s)
      Y. Matsumiya, Y. Masubuchi, H. Watanabe, Q. Huang, H. K. Rasmussen, N. J. Alvarez, O. Hassager
    • Organizer
      The Society of Rheology 85th Annual Meeting
    • Place of Presentation
      Montreal, QC, Canada
    • Year and Date
      2013-10-14
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] Comparison of Dielectric and Viscoelastic Relaxation of cis-Polyisoprene : Some Details of Entanglement Dynamics2013

    • Author(s)
      H. Watanabe
    • Organizer
      Telluride Workshop on Polymer Physics
    • Place of Presentation
      Telluride , USA
    • Year and Date
      2013-06-18
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Comparison of Dielectric and Viscoelastic Relaxation of cis-Polyisoprene: Some Details of Entanglement Dynamics2013

    • Author(s)
      Hiroshi Watanabe
    • Organizer
      Telluride Workshop on Polymer Physics
    • Place of Presentation
      Telluride , USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 高分子のレオロジーの基礎2013

    • Author(s)
      増渕雄一
    • Organizer
      高分子基礎研究会
    • Place of Presentation
      東京 神田
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ひずみ硬化の分子論2013

    • Author(s)
      増渕雄一
    • Organizer
      高分子材料自由討論会
    • Place of Presentation
      上山温泉
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] からみあい高分子の多数鎖スリップスプリングモデルシミュレーション2013

    • Author(s)
      畝山多加志,増渕雄一
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 配向伸長状態での高分子の摩擦2013

    • Author(s)
      増渕雄一,渡辺宏
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 仮想バネの導入による DPD 法でのからみあい運動の再現2013

    • Author(s)
      Michael Langeloth, 増渕雄一, Michael C. Boehm, Florian Mueller-Plathe
    • Organizer
      第61回レオロジー討論会
    • Place of Presentation
      山形大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Stress relaxation of entangled polystyrene solution after constant-rate, uniaxial elongation2013

    • Author(s)
      Yumi Matsumiya, Yuichi Masubuchi, Hiroshi Watanabe, Qian Huang, Henrik K.Rasmussen, Nicolas J. Alvarez, Ole Hassager
    • Organizer
      第61回レオロジー討論会
    • Place of Presentation
      山形大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高分子液体のレオロジー2013

    • Author(s)
      増渕雄一
    • Organizer
      日本接着学会レオロジーセミナー3
    • Place of Presentation
      京都
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Multi-chain Slip-spring Model for Entangled Polymer Dynamics2012

    • Author(s)
      Y. Mausbuchi
    • Organizer
      Dynamics of Architecturally Complex Polymers : Current and Future Trends
    • Place of Presentation
      Leeds, UK
    • Year and Date
      2012-12-14
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Fast Molecular Simulation for Entangled Polymers2012

    • Author(s)
      Y. Masubuchi
    • Organizer
      The 5th International Symposium on Designing, Processing and Properties of Advanced Engineering Materials (ISAEM-2012) and The 3rd International Symposium on Advanced Materials Development and Integration of Novel Structural Metallic and Inorganic Materials (AMDI-3)
    • Place of Presentation
      ロワジールホテル豊橋(豊橋)
    • Year and Date
      2012-11-07
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Prediction of Entangled Polymer Rheology by Primitive Chain Network Simulations2012

    • Author(s)
      Y. Masubuchi
    • Organizer
      2012 Japan-Taiwan Bilateral Polymer Symposium - JTBPS '12
    • Place of Presentation
      北九州国際会議場(小倉)
    • Year and Date
      2012-09-06
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Primitive Chain Network Simulations of Enlongational Flows of Entangled Linear Chains : Stretch/orientation induced reduction of segmental friction2012

    • Author(s)
      Y. Masubuchi, H. Watanabe, G. Ianniruberto, and G. Marrucci
    • Organizer
      International Congress on Rheology 2012
    • Place of Presentation
      Lisbon, Portugal
    • Year and Date
      2012-08-09
    • Related Report
      2013 Final Research Report
  • [Presentation] NAPLES : a simulation code for molecular rheology2012

    • Author(s)
      Y. Masubuchi, G. Ianniruberto, F. Greco and G. Marrucci
    • Organizer
      XII Convegno Nazionale della Societa Italiana di Rheologia
    • Place of Presentation
      Ustica, Italy
    • Year and Date
      2012-07-06
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] からみあい高分子の高速粗視化分子シミュレーション2012

    • Author(s)
      増渕雄一
    • Organizer
      JASRI平成23年度GIGNO研究領域創成支援プロジェクト研究会
    • Place of Presentation
      東京工業大学(招待講演)
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高分子ネットワークの粗視化シミュレーション2012

    • Author(s)
      増渕雄一
    • Organizer
      高分子学会ポリマーフロンティア21(11-6)
    • Place of Presentation
      東工大蔵前会館(東京)
    • Year and Date
      2012-03-02
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 高分子ネットワークの粗視化シミュレーション2012

    • Author(s)
      増渕雄一
    • Organizer
      高分子学会ポリマーフロンティア21(11-6)
    • Place of Presentation
      東京工業大学
    • Year and Date
      2012-03-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高分子レオロジーのシミュレーション2011

    • Author(s)
      増渕雄一
    • Organizer
      第9回日本ゴム協会ゴムの力学研究分科会
    • Place of Presentation
      大阪科学技術センター(大阪市)(招待講演)
    • Year and Date
      2011-11-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高分子レオロジーの基礎と物性2011

    • Author(s)
      増渕雄一
    • Organizer
      日本レオロジー学会レオロジーイブニングセミナー2011
    • Place of Presentation
      三井化学(姉ケ崎市)(招待講演)
    • Year and Date
      2011-10-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Combining Dielectric Spectroscopy and Rheology to Study Polymer Dynamics2011

    • Author(s)
      Hiroshi Watanabe
    • Organizer
      Dynacop Summer School
    • Place of Presentation
      ホテルカプリ(イタリア,ナポリ市)(招待講演)
    • Year and Date
      2011-07-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 誘電緩和による高分子セグメントダイナミクスの研究2011

    • Author(s)
      松宮由実
    • Organizer
      JACI高分子シミュレーション技術セミナー
    • Place of Presentation
      カネジュービル(名古屋市)(招待講演)
    • Year and Date
      2011-07-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高分子レオロジーのシミュレーションとその工学的利用2011

    • Author(s)
      増渕雄一
    • Organizer
      高分子学会高分子同友会関西勉強会
    • Place of Presentation
      薬業年金会館(大阪市)(招待講演)
    • Year and Date
      2011-07-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] Combining Dielectric Spectroscopy and Rheology to Study Polymer Dynamics2011

    • Author(s)
      H. Watanabe
    • Organizer
      Dynacop Summer School, "Understanding polymer dynamics : state of the art and challenges
    • Place of Presentation
      Capri, Italy
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] からみあい高分子の一軸伸長シミュレーション

    • Author(s)
      増渕雄一
    • Organizer
      日本レオロジー学会年会
    • Place of Presentation
      東京大学生産技術研究所
    • Related Report
      2012 Annual Research Report
  • [Presentation] Molecular Simulations of Polymeric Materials

    • Author(s)
      増渕雄一
    • Organizer
      山形大学テニュアトラック-WPIジョイントセミナー
    • Place of Presentation
      山形大学工学部
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 高分子レオロジーの予測と工学的応用

    • Author(s)
      増渕雄一
    • Organizer
      平成24年度山形大学テニュアトラックシンポジウム
    • Place of Presentation
      山形大学理学部
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] NAPLES: a simulation code for molecular rheology

    • Author(s)
      Yuichi Masubuchi
    • Organizer
      XII Convegno Nazionale della Societa Italiana di Rheologia
    • Place of Presentation
      Ustica, Italy
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Primitive Chain Network Simulations of Enlongational Flows of Entangled Linear Chains:

    • Author(s)
      Yuichi Masubuchi
    • Organizer
      International Congress on Rheology 2012
    • Place of Presentation
      Lisbon, Portugal
    • Related Report
      2012 Annual Research Report
  • [Presentation] Prediction of Entangled Polymer Rheology by Primitive Chain Network Simulations

    • Author(s)
      Yuichi Masubuchi
    • Organizer
      2012 Japan-Taiwan Bilateral Polymer Symposium
    • Place of Presentation
      北九州国際会議場(小倉)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 高分子液体のレオロジー

    • Author(s)
      増渕雄一
    • Organizer
      日本接着学会レオロジーセミナー
    • Place of Presentation
      大阪市大梅田キャンパス
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Fast Molecular Simulation for Entangled Polymers

    • Author(s)
      Yuichi Masubuchi
    • Organizer
      ISAEM-2012 and AMDI-3
    • Place of Presentation
      ロワジールホテル豊橋
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 伸張状態での高分子の摩擦低下

    • Author(s)
      増渕雄一
    • Organizer
      高分子基礎物性研究会,高分子計算科学研究会,高分子ナノテクノロジー研究会,2012年度合同討論会
    • Place of Presentation
      東工大
    • Related Report
      2012 Annual Research Report
  • [Presentation] Multi-chain Slip-spring Model for Entangled Polymer Dynamics

    • Author(s)
      Yuichi Masubuchi
    • Organizer
      Dynamics of Architecturally Complex Polymers: Current and Future Trends
    • Place of Presentation
      Leeds, UK
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Remarks] Webページ

    • URL

      http://rheology.minority.jp/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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