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Clarification of Determining Factors of Irreversibility Fields in High-Tc Superconductors with Short Coherence Length

Research Project

Project/Area Number 23360007
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionThe University of Tokyo

Principal Investigator

SHIMOYAMA Jun-ichi  東京大学, 工学(系)研究科(研究院), 准教授 (20251366)

Co-Investigator(Kenkyū-buntansha) YAMAMOTO Akiyasu  東京大学, 大学院工学系研究科, 助教 (20581995)
KISHIO Kohji  東京大学, 大学院工学系研究科, 教授 (50143392)
OGINO Hiraku  東京大学, 大学院工学系研究科, 助教 (70359545)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2012: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2011: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Keywords超伝導 / 臨界電流特性 / 不可逆磁場 / 超伝導体 / 結晶粒界 / 化学組成
Research Abstract

Relationships among synthesis conditions, microstructure and critical current properties across the grain boundaries were studies for randomly oriented sintered bulks of cuprate and iron-based superconductors. Addition of reductive post-annealing process and achieving carrier overdoped state were found to be quite effective for dramatic enhancement of intergrain Jc of both Y123 and (Bi,Pb)2223 superconductors. This improvement is explained by the effect of an increase in condensation energy by a control of cation composition and an increase in coherence length along the c-axis direction. Irreversibility field of Y123 was also largely improved by adopting above method. For iron-based superconductors, improvement of intergrain Jc was succeeded by reduction of impurity phases and addition of Sn metal. Intergrain critical current properties achieved in this study are highest for each material as randomly oriented sintered bulks and further enhancement can be expected by densification.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (51 results)

All 2014 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (43 results) (of which Invited: 4 results)

  • [Journal Article] Enhancement of intergrainular current density of Sm based oxypnictide superconductors with Sn2014

    • Author(s)
      S.J.Singh, J.Shimoyama, A.Yamamoto, H.Ogino, K.Kishio
    • Journal Title

      Supercond. Sci. Technol.

      Volume: 27 (印刷中)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Potential of iron-based superconductors for practical future materials2014

    • Author(s)
      J.Shimoyama
    • Journal Title

      Supercond. Sci. Technol.

      Volume: 27 Issue: 4 Pages: 44020-44020

    • DOI

      10.1088/0953-2048/27/4/044002

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Influences of material processing on the microstructure and inter-granular current properties of polycrystalline bulk Ba(Fe,Co)_2As_22014

    • Author(s)
      Y.Hayashi, A.Yamamoto, H.Ogino, J.Shimoyama and K.Kishio
    • Journal Title

      Physica C

      Volume: (in press) Pages: 28-32

    • DOI

      10.1016/j.physc.2014.01.010

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Significant enhancement of the intergrain coupling in lightly F-doped SmFeAs0 superconductors2013

    • Author(s)
      S. J. Singh, J. Shimoyama, A. Yamamoto, H. Ogino and K. Kishio
    • Journal Title

      Supercond. Sci. Technol.

      Volume: 26 Issue: 6 Pages: 0650061-0650067

    • DOI

      10.1088/0953-2048/26/6/065006

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Critical Current Properties of c-axis Oriented Hg(Re)1223 Bulks2013

    • Author(s)
      T.Ozaki, J.Shimoyama, A.Yamamoto, H.Ogino, K.Kishio
    • Journal Title

      IEEE Trans. Appl. Supercond.

      Volume: 23 Issue: 3 Pages: 6800404-6800404

    • DOI

      10.1109/tasc.2012.2235520

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Bi(Pb)2223 tapes by low PO2 sintering2013

    • Author(s)
      R.Tajima, J.Shimoyama, A.Yamamoto, H. Ogino, K.Kishio , T.Nakashima, S.Kobayashi,K.Hayashi
    • Journal Title

      IEEE Trans. Appl. Supercond.

      Volume: 23 Pages: 6400604-6400604

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Bi(Pb)2223 tapes by low PO2 sintering2013

    • Author(s)
      R. Tajima, J. Shimoyama, A. Yamamoto, H. Ogino, K. Kishio,T. Nakashima, S. Kobayashi,K. Hayashi
    • Journal Title

      IEEE Trans. Appl. Supercond.

      Volume: 23 Pages: 6400604-6400604

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Critical Current Properties of c-axis oriented Bi(Pb)2223 Bulks2012

    • Author(s)
      K.Obata, J.Shimoyama, A.Yamamoto, H.Ogino, K.Kishio, S.Kobayashi, K.Hayashi
    • Journal Title

      Physics Proceedia

      Volume: 36 Pages: 665-668

    • DOI

      10.1016/j.phpro.2012.06.264

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] RE123焼結体、溶融凝固バルクへのCaドープ効果2014

    • Author(s)
      下山 淳一,栗山陽介,廣田哲也,山本 明保, 荻野 拓, 岸尾 光二
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      相模原
    • Year and Date
      2014-03-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Y123溶融凝固バルクにおけるCaドープ効果2014

    • Author(s)
      栗山 陽介,下山 淳一,瀬戸山 結衣,山木 修,山本 明保,荻野 拓,岸尾 光二
    • Organizer
      第89低温工学・超電導学会
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 密度制御によるRE123焼結体の臨界電流特性の改善2014

    • Author(s)
      下山 淳一、廣田 哲也、今 康一、市川 直樹、稲森 聡、内藤 恭吾
    • Organizer
      第89低温工学・超電導学会
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2013 Annual Research Report
  • [Presentation] RE123焼結体の粒間臨界電流特性の支配因子2013

    • Author(s)
      下山淳一, 廣田哲也, 今康一, 市川直樹, 稲森聡, 内藤恭吾
    • Organizer
      第88回低温工学・超電導学会
    • Place of Presentation
      名古屋
    • Year and Date
      2013-12-05
    • Related Report
      2013 Final Research Report
  • [Presentation] 磁場配向法によるc 軸配向Hg(Re)1212焼結体の作製2013

    • Author(s)
      椎野匠、下山淳一, 山本明保, 荻野拓, 岸尾光二
    • Organizer
      第88回低温工学・超電導学会
    • Place of Presentation
      名古屋
    • Year and Date
      2013-12-05
    • Related Report
      2013 Final Research Report
  • [Presentation] Ba122多結晶体における相・組織形成と粒界臨界電流特性の評価2013

    • Author(s)
      林 雄二郎,山本 明保,荻野 拓,下山 淳一,岸尾 光二
    • Organizer
      第88回低温工学・超電導学会
    • Place of Presentation
      名古屋
    • Year and Date
      2013-12-05
    • Related Report
      2013 Final Research Report
  • [Presentation] Potentials of iron-based superconductors for practical materials in future2013

    • Author(s)
      J.Shimoyama
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2013)
    • Place of Presentation
      Genov, Italy
    • Year and Date
      2013-09-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Control of Grain Boundary Properties of RE123 Sintered Bulks by Reductive Post-annealing2013

    • Author(s)
      T.Hirota, J.Shimoyama, A.Yamamoto, H.Ogino, K.Kishio
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2013)
    • Place of Presentation
      Genova , Italy
    • Year and Date
      2013-09-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Influence of microstructure on the intergranular current transport properties of Ba(Fe,Co)_2As_2 polycrystalline bulks2013

    • Author(s)
      Y.Hayashi, A.Yamamoto, H.Ogino, J.Shimoyama, K.Kishio
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2013)
    • Place of Presentation
      Genova,Italy
    • Year and Date
      2013-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Transport properties of Fe based superconductors: SmFeAs(O,F) and (Fe_2As_2)(Ca_4(Mg,Ti)_3O_8)2013

    • Author(s)
      S.J.Singh, H.Ogino, J.Shimoyama, A.Yamamoto, K.Kishio
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2013)
    • Place of Presentation
      Genova,Italy
    • Year and Date
      2013-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Study of fluorine doped Sm1111 arsenide oxide superconductors2013

    • Author(s)
      S.J.Singh, J.Shimoyama, A.Yamamoto, H.Ogino, K.Kishio
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      長野
    • Year and Date
      2013-09-06
    • Related Report
      2013 Final Research Report
  • [Presentation] 微細なY123粉末を原料とした高臨界電流特性Y123焼結体の開発2013

    • Author(s)
      下山淳一, 廣田哲也, 今康一, 市川直樹, 稲森聡, 内藤恭吾
    • Organizer
      第87回低温工学・超電導学会
    • Place of Presentation
      東京
    • Year and Date
      2013-05-14
    • Related Report
      2013 Final Research Report
  • [Presentation] Derivable Potentials of HTS by Chemical Methods toward More Versatile Materials2013

    • Author(s)
      J.Shimoyama, A.Yamamoto, K.Kishio, H. Ogino
    • Organizer
      Materials Research Society 2013 Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2013-04-03
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 後熱処理によるRE123焼結体の臨界電流特性の制御2013

    • Author(s)
      下山 淳一,廣田哲也, 山本 明保, 荻野拓, 岸尾 光二
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      厚木
    • Year and Date
      2013-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 微細混合粉末を原料としたCoドープBa122多結晶バルクの作製2013

    • Author(s)
      林 雄二郎,山本 明保,荻野 拓,下山 淳一,岸尾 光二
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      厚木
    • Year and Date
      2013-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] Derivable Potentials of HTS by Chemical Methods toward More Versatile Materials2013

    • Author(s)
      J. Shimoyama, K. Kishio. A. Yamamoto, H. Ogino
    • Organizer
      Materials Research Society 2013 Spring Meeting
    • Place of Presentation
      サンフランシスコ (USA)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Relationships among Crystal Structure, Chemical Composition and Superconducting Properties of Layered Cuprates and Iron-Arsenides2012

    • Author(s)
      J.Shimoyama, A.Yamamoto, H.Ogino, K.Kishio
    • Organizer
      IUMRS-ICEM2012
    • Place of Presentation
      横浜
    • Year and Date
      2012-09-24
    • Related Report
      2013 Final Research Report
  • [Presentation] "Grain Boundary Engineering by Post Annealing for Cuprate2012

    • Author(s)
      J. Shimoyama, A. Yamamoto, H. Ogino, K. Kishio, T. Kagiyama, S. Kobayashi
    • Organizer
      Materials Research Society 2012 Spring Meeting
    • Place of Presentation
      サンフランシスコ (USA)
    • Related Report
      2012 Annual Research Report
  • [Presentation] "Formation of Bi(Pb)2223 phase by sintering in a short time under low partial pressure of oxygen"2012

    • Author(s)
      R. Tajima, J. Shimoyama, A. Yamamoto, H. Ogino, K. Kishio
    • Organizer
      ICEC24-ICMC2012
    • Place of Presentation
      福岡国際会議場(福岡市
    • Related Report
      2012 Annual Research Report
  • [Presentation] "後熱処理による銅酸化物超伝導体焼結体の臨界電流特性の制御"2012

    • Author(s)
      下山 淳一、廣田哲也、椎野匠、山本 明保、荻野 拓、岸尾 光二
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学(松山市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] "Relationships among Crystal Structure, Chemical Composition and Superconducting Properties of Layered Cuprates and Iron-Arsenides"2012

    • Author(s)
      J. Shimoyama, H. Ogino, A. Yamamoto, K. Kishio
    • Organizer
      IUMRS-ICEM2012
    • Place of Presentation
      パシフィコ横浜(横浜市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] "RE123およびBi2223焼結体における粒間、粒内の臨界電流特性"2012

    • Author(s)
      下山 淳一, 廣田 哲也, 椎野 匠, 山本 明保, 荻野 拓, 岸尾 光二
    • Organizer
      第86回(2012年度秋季)低温工学・超電導学会
    • Place of Presentation
      いわて県民情報交流センター(盛岡市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 低圧純酸素雰囲気下におけるRE123溶融凝固バルクの作製2011

    • Author(s)
      杵村陽平, 下山淳一, 山本明保, 荻野拓, 岸尾光二
    • Organizer
      第85回(2011年度秋季)低温工学・超電導学会
    • Place of Presentation
      金沢歌劇座(金沢市、日本)
    • Year and Date
      2011-11-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] c軸配向Bi(Pb)2223バルクの加圧焼成条件と臨界電流特性の関係2011

    • Author(s)
      小畑圭亮, 下山淳一, 田島諒介, 山本明保, 荻野拓, 岸尾光二、小林慎一, 林和彦
    • Organizer
      第85回(2011年度秋季)低温工学・超電導学会
    • Place of Presentation
      金沢歌劇座(金沢市、日本)
    • Year and Date
      2011-11-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] Bi2223焼結体における粒間、粒内の臨界電流特性2011

    • Author(s)
      下山淳一, 小畑圭亮, 田島諒介, 山本明保, 荻野拓, 岸尾光二、鍵山知宏, 小林慎一
    • Organizer
      第85回(2011年度秋季)低温工学・超電導学会
    • Place of Presentation
      金沢歌劇座(金沢市、日本)
    • Year and Date
      2011-11-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] Critical Current Properties of c-axis oriented Bi(Pb)2223 Bulks2011

    • Author(s)
      K.Obata, J.Shimoyama, A.Yamamoto, H.Ogino, K.Kishio, S.Kobayashi, K.Hayashi
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2011)
    • Place of Presentation
      Den Hague (Netherland)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of RE123 Melt-Solidified Bulks Under Low Pressure Pure Oxygen2011

    • Author(s)
      Y.Kinemura, J.Shimoyama, A.Yamamoto, H.Ogino, K.Kishio
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2011)
    • Place of Presentation
      Den Hague (Netherland)
    • Year and Date
      2011-09-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] Derivable Potentials of HTS by Chemical Methods toward More Versatile Materials

    • Author(s)
      J. Shimoyama, A. Yamamoto, K. Kishio H. Ogino
    • Organizer
      Materials Research Society 2013 Spring Meeting
    • Place of Presentation
      San Francisco(USA)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] "RE123溶融凝固バルクの組織、臨界電流特性におけるRE混合効果

    • Author(s)
      瀬戸山 結衣, 山木 修, 下山淳一, 山本明保, 荻野拓, 岸尾光二
    • Organizer
      第87回低温工学・超電導学会
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 微細なY123粉末を原料とした高臨界電流特性Y123焼結体の開発

    • Author(s)
      山木 修, 下山淳一, 瀬戸山 結衣, 山本 明保, 荻野 拓, 岸尾 光二
    • Organizer
      第87回低温工学・超電導学会
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 微細なY123粉末を原料とした高臨界電流特性Y123焼結体の開発

    • Author(s)
      下山淳一, 廣田哲也, 今康一, 市川直樹, 稲森聡, 内藤恭吾
    • Organizer
      第87回低温工学・超電導学会
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Study of fluorine doped Sm1111 arsenide oxide superconductors

    • Author(s)
      S.J. Singh, J. Shimoyama, A. Yamamoto, H. Ogino, K. Kishio
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Influence of microstructure on the intergranular current transport properties of Ba(Fe,Co)2As2 polycrystalline bulks

    • Author(s)
      Y. Hayashi, A. Yamamoto, H. Ogino, J. Shimoyama, K. Kishio
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2013)
    • Place of Presentation
      Genova(Italy)
    • Related Report
      2013 Annual Research Report
  • [Presentation] "Transport properties of Fe based superconductors: SmFeAs(O,F) and (Fe2As2)(Ca4(Mg,Ti)3O8)

    • Author(s)
      S. J. Singh, H. Ogino, J. Shimoyama, A. Yamamoto, K. Kishio
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2013)
    • Place of Presentation
      Genova(Italy)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Control of Grain Boundary Properties of RE123 Sintered Bulks by Reductive Post-annealing

    • Author(s)
      T. Hirota, J. Shimoyama, A. Yamamoto, H. Ogino, K. Kishio
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2013)
    • Place of Presentation
      Genova(Italy)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Preparation of magnetically c-axis aligned Bi(Pb)2223 and Hg(Re)1212 bulks

    • Author(s)
      T. Shino, J. Shimoyama, A. Yamamoto, H. Ogino, K. Kishio
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2013)
    • Place of Presentation
      Genova(Italy)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effects of RE-mixing on microstructure and critical current properties of RE123 melt-solidified bulks

    • Author(s)
      Y. Setoyama, J. Shimoyama, A. Yamamoto, H. Ogino, K. Kishio
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2013)
    • Place of Presentation
      Genova(Italy)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Potentials of iron-based superconductors for practical materials in future

    • Author(s)
      J. Shimoyama
    • Organizer
      European Conference on Applied Superconductivity (EUCAS2013)
    • Place of Presentation
      Genova(Italy)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] RE123焼結体の粒間臨界電流特性の支配因子

    • Author(s)
      下山淳一, 廣田哲也, 今康一, 市川直樹, 稲森聡, 内藤恭吾
    • Organizer
      第88回低温工学・超電導学会
    • Place of Presentation
      ウィンクあいち(愛知)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 磁場配向法によるc軸配向Hg(Re)1212焼結体の作製

    • Author(s)
      椎野匠、下山淳一, 山本明保, 荻野拓, 岸尾光二
    • Organizer
      第88回低温工学・超電導学会
    • Place of Presentation
      ウィンクあいち(愛知)
    • Related Report
      2013 Annual Research Report
  • [Presentation] RE123溶融凝固バルクにおけるRE混合およびBa2Cu3O4Cl2添加効果

    • Author(s)
      瀬戸山結衣、下山淳一、山木修、山本 明保, 荻野 拓, 岸尾 光二,水戸瀬智久、淡路智
    • Organizer
      第88回低温工学・超電導学会
    • Place of Presentation
      ウィンクあいち(愛知)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ba122多結晶体における相・組織形成と粒界臨界電流特性の評価

    • Author(s)
      林 雄二郎,山本 明保,荻野 拓,下山 淳一,岸尾 光二
    • Organizer
      第88回低温工学・超電導学会
    • Place of Presentation
      ウィンクあいち(愛知)
    • Related Report
      2013 Annual Research Report
  • [Presentation] RE123焼結体、溶融凝固バルクへのCaドープ効果

    • Author(s)
      下山 淳一,栗山陽介,廣田哲也,山本 明保, 荻野 拓, 岸尾 光二
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      青山学院大(神奈川)
    • Related Report
      2013 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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