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Study on Nickel Sintering in Solid Oxide Fuel Cell Anode

Research Project

Project/Area Number 23360093
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thermal engineering
Research InstitutionThe University of Tokyo

Principal Investigator

SHIKAZONO Naoki  東京大学, 生産技術研究所, 教授 (30345087)

Co-Investigator(Kenkyū-buntansha) UMENO Yoshitaka  東京大学, 生産技術研究所, 准教授 (40314231)
HARA Shotaro  東京大学, 生産技術研究所, 特任講師 (10401134)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2013: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2012: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2011: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Keywords燃料電池 / 燃料極 / 数値シミュレーション / エネルギー効率化 / セラミックス
Research Abstract

In the present study, solid oxide fuel cell (SOFC) which is indispensable for achieving highest efficiency for energy conversion from hydrocarbon fuel is investigated. One of the major issues of SOFC is the sintering of Nickel in the anode which causes degradation problem. In order to overcome sintering degradation issue, fisrst principle analysis, molecular dynamics and continuum approaches as well as experimental studies were carried out in the present study.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (54 results)

All 2014 2013 2012 2011 Other

All Journal Article (16 results) (of which Peer Reviewed: 16 results) Presentation (31 results) Book (6 results) Remarks (1 results)

  • [Journal Article] Simulation of Nickel Morphological and Crystal Structures Evolution in Solid Oxide Fuel Cell Anode Using Phase Field Method2014

    • Author(s)
      Jiao, Z. and Shikazono, N
    • Journal Title

      J. Electrochem. Soc

      Volume: 161(5)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Simulation of Nickel Morphological and Crystal Structures Evolution in Solid Oxide Fuel Cell Anode Using Phase Field Method2014

    • Author(s)
      Jiao, Z. and Shikazono, N.
    • Journal Title

      J. Electrochem. Soc.

      Volume: 161 Issue: 5 Pages: F577-F582

    • DOI

      10.1149/2.009405jes

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Study on the Influence of Current Collector on the Sudden Deterioration of Solid Oxide Fuel Cell Anode Performance2013

    • Author(s)
      Jiao, Z. and Shikazono, N
    • Journal Title

      J. Fuel Cell Sci. Technol

      Volume: 11(2) Pages: 21010-21010

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Simulation of Solid Oxide Fuel Cell Anode Microstructure Evolution Using Phase Field Method2013

    • Author(s)
      Jiao, Z. and Shikazono, N
    • Journal Title

      J. Electrochem. Soc

      Volume: 160(6)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Simulation of Solid Oxide Fuel Cell Anode Microstructure Evolution Using Phase Field Method2013

    • Author(s)
      Jiao, Z. and Shikazono, N.
    • Journal Title

      J. Electrochem. Soc.

      Volume: 160 Issue: 6 Pages: F709-F715

    • DOI

      10.1149/2.139306jes

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Study on the Influence of Current Collector on the Sudden Deterioration of Solid Oxide Fuel Cell Anode Performance2013

    • Author(s)
      Jiao, Z. and Shikazono, N.
    • Journal Title

      J. Fuel Cell Sci. Technol.

      Volume: 11 Issue: 2 Pages: 21010-21010

    • DOI

      10.1115/1.4026087

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative Study on the Correlation Between Solid Oxide Fuel Cell Ni-YSZ Composite Anode Performance and Sintering T emperature Based on Three Dimensional Reconstruction2012

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N
    • Journal Title

      J. Electrochem. Soc

      Volume: 159(7)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative Characterization of SOFC Nickel-YSZ Anode Microstructure Degradation Based on Focused-Ion-Beam 3D-Reconstruction T echnique2012

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N
    • Journal Title

      J. Electrochem. Soc

      Volume: 159(3)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative Characterization of SOFC Nickel-YSZ Anode Microstructure Degradation Based on Focused-Ion-Beam 3D-Reconstruction Technique2012

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N.
    • Journal Title

      J. Electrochem. Soc.

      Volume: 159 Issue: 3 Pages: B285-B291

    • DOI

      10.1149/2.045203jes

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative Study on the Correlation Between Solid Oxide Fuel Cell Ni-YSZ Composite Anode Performance and Sintering Temperature Based on Three Dimensional Reconstruction2012

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N.
    • Journal Title

      J. Electrochem. Soc.

      Volume: 159 Issue: 7 Pages: F278-F286

    • DOI

      10.1149/2.056207jes

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Study on Local Morphological Changes of Nickel in Solid Oxide Fuel Cell Anode using Porous Ni pellet Electrode2011

    • Author(s)
      Jiao, Z., T akagi, N., Shikazono, N. and Kasagi, N
    • Journal Title

      J. Power Sources

      Volume: 196(3) Pages: 1019-1029

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] An Ultra-fast Fabrication T echnique for Anode Support Solid Oxide Fuel Cells by Microwave2011

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N
    • Journal Title

      J. Power Sources

      Volume: 196(13) Pages: 5490-5493

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Study on Degradation of Solid Oxide Fuel Cell Anode by using pure Nickel Electrode2011

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N
    • Journal Title

      J. Power Sources

      Volume: 196(20) Pages: 8366-8376

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of SOFC Anode Polarization Simulation using Three-Dimensional Microstructures Reconstructed by FIB Tomography2011

    • Author(s)
      Kanno, D., Shikazono, N., Takagi, N., Matsuzaki, K., Kasagi, N.
    • Journal Title

      Electrochimica Acta

      Volume: 56 Issue: 11 Pages: 4015-4021

    • DOI

      10.1016/j.electacta.2011.02.010

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Ultra-fast Fabrication Technique for Anode Support Solid Oxide Fuel Cells by Microwave2011

    • Author(s)
      Jiao, Z., Shikazono, N., Kasagi, N.
    • Journal Title

      Journal of Power Sources

      Volume: 196 Issue: 13 Pages: 5490-5493

    • DOI

      10.1016/j.jpowsour.2011.02.040

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Study on Degradation of Solid Oxide Fuel Cell Anode by using pure Nickel Electrode2011

    • Author(s)
      Jiao, Z., Shikazono, N., Kasagi, N.
    • Journal Title

      Journal of Power Sources

      Volume: 196 Issue: 20 Pages: 8366-8376

    • DOI

      10.1016/j.jpowsour.2011.06.069

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] NiO-YSZ 燃料極の製造プロセスにおける焼結挙動の研究2013

    • Author(s)
      大井彰洋, 原祥太郎, 焦震鈞, 志村敬彬,西橋健, 鹿園直毅
    • Organizer
      第22回SOFC 研究発表会講演要旨集
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] Simulation of Solid Oxide Fuel Cell Anode Microstructure Evolution Using Phase Field Method2013

    • Author(s)
      Jiao, Z. and Shikazono, N
    • Organizer
      第22回SOFC 研究発表会講演要旨集
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] Monte Carlo Study on The Constraint Effect of YSZ Phase on Ni Sintering in Ni-YSZ Composite System2013

    • Author(s)
      Hara, S. Shikata, K., Shikazono, N., Izumi, S. and Sakai, S
    • Organizer
      Proc. 13th International Symposium on Solid Oxide Fuel Cells(SOFC-XIII)
    • Place of Presentation
      Okinawa
    • Related Report
      2013 Final Research Report
  • [Presentation] Quantitative Analysis of SOFC Anode Microstructure Change During Redox Cycles2013

    • Author(s)
      Shimura, T . and Shikazono, N
    • Organizer
      Proc. : 13th International Symposium on Solid Oxide Fuel Cells (SOFC-XIII)
    • Place of Presentation
      Okinawa
    • Related Report
      2013 Final Research Report
  • [Presentation] Simulation of Solid Oxide Fuel Cell Anode Microstructure Evolution Using Phase Field Method2013

    • Author(s)
      Jiao, Z. and Shikazono, N
    • Organizer
      Proc. 13th International Symposium on Solid Oxide Fuel Cells (SOFC-XIII)
    • Place of Presentation
      Okinawa
    • Related Report
      2013 Final Research Report
  • [Presentation] Monte Carlo Study on the Constraint Effect of YSZ Phase on Ni Sintering in Ni-YSZ Composite System2013

    • Author(s)
      Hara, S. Shikata, K., Shikazono, N., Izumi, S. and Sakai, S.
    • Organizer
      13th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      Okinawa, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Quantitative Analysis of SOFC Anode Microstructure Change During Redox Cycles2013

    • Author(s)
      Shimura, T. and Shikazono, N.
    • Organizer
      13th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      Okinawa, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Simulation of Solid Oxide Fuel Cell Anode Microstructure Evolution Using Phase Field Method2013

    • Author(s)
      Jiao, Z. and Shikazono, N.
    • Organizer
      13th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      Okinawa, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Simulation of Solid Oxide Fuel Cell Anode Microstructure Evolution Using Phase Field Method2013

    • Author(s)
      焦 震鈞,鹿園直毅
    • Organizer
      第22回SOFC研究発表会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] NiO-YSZ 燃料極の製造プロセスにおける焼結挙動の研究2013

    • Author(s)
      大井彰洋,原祥太郎,焦震鈞,志村敬彬,西橋健,鹿園直毅
    • Organizer
      第22回SOFC研究発表会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Simulation of Solid Oxide Fuel Cell Anode Microstructure Evolution by Using the Phase Field Method2012

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N
    • Organizer
      第21回SOFC 研究発表会講演要旨集
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] 3 次元モンテカルロ法に基づく SOFC 燃料極の Ni 粗大化現象解析2012

    • Author(s)
      原祥太郎, 四方健太郎, 孫瑜, 鹿園直毅,泉聡志,酒井信介
    • Organizer
      第21回SOFC研究発表会講演要旨集
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] 固体酸化物形燃料電池燃料極の構造変化に関するナノ・メゾスケール解析2012

    • Author(s)
      原 祥太郎, 四方 健太郎,鹿園 直毅,泉 聡志,酒井 信介
    • Organizer
      日本機械学会第4回マイクロ・ナノ工学シンポジウム講演論文集
    • Place of Presentation
      北九州
    • Related Report
      2013 Final Research Report
  • [Presentation] Multiscale Modeling for Material Design of Solid Oxide Fuel Cell Electrodes2012

    • Author(s)
      Umeno, Y ., Tada, T., Hara, S. and Shikazono, N
    • Organizer
      Proc. ECI Harnessing the Materials Genome
    • Place of Presentation
      Colorado
    • Related Report
      2013 Final Research Report
  • [Presentation] Redox サイクルにおける SOFC 燃料極の微細構造変化に関する定量的評価2012

    • Author(s)
      志村 敬彬, 尺田 将喜, 西橋 健, 鹿園 直毅
    • Organizer
      日本機械学会2012年度年次大会講演論文集
    • Place of Presentation
      金沢
    • Related Report
      2013 Final Research Report
  • [Presentation] SOFC 燃料極の微視構造発展予測に向けた 3 次元モンテカルロシミュレーション2012

    • Author(s)
      四方 健太郎, 原 祥太郎, 鹿園 直毅, 泉聡志, 酒井 信介
    • Organizer
      日本機械学会2012年度年次大会講演論文集
    • Place of Presentation
      金沢
    • Related Report
      2013 Final Research Report
  • [Presentation] K., Okita, K., Shikazono, N. and Kasagi, N. 3D Quantitative Characterization of Nickel-Yttria-stabilized Zirconia Solid Oxide Fuel Cell Anode Microstructure in Operation2012

    • Author(s)
      Sun, X., Jiao, Z., Lee, G ., Hayakawa, K., Okita, K., Shikazono, N. and Kasagi, N
    • Organizer
      10th European Solid Oxide Fuel Cell Forum
    • Place of Presentation
      Lucerne, Switzerland
    • Related Report
      2013 Final Research Report
  • [Presentation] Evolution of Microstructural Parameters of Solid Oxide Fuel Cell Anode during Initial Discharge Process2012

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N
    • Organizer
      10th European Solid Oxide Fuel Cell Forum
    • Place of Presentation
      Lucerne, Switzerland
    • Related Report
      2013 Final Research Report
  • [Presentation] Evolution of Microstructural Parameters of Solid Oxide Fuel Cell Anode during Initial Discharge Process2012

    • Author(s)
      ④ Sun, X., Jiao, Z., Lee, G., Hayakawa, K., Okita, K., Shikazono, N. and Kasagi, N.
    • Organizer
      10th European Solid Oxide Fuel Cell Forum
    • Place of Presentation
      Luzern, Switzerland
    • Related Report
      2012 Annual Research Report
  • [Presentation] Redox サイクルにおけるSOFC 燃料極の微細構造変化に関する定量的評価2012

    • Author(s)
      志村 敬彬,尺田 将喜,西橋 健,鹿園 直毅
    • Organizer
      日本機械学会2012年度年次大会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] SOFC 燃料極の微視構造発展予測に向けた3次元モンテカルロシミュレーション2012

    • Author(s)
      四方 健太郎, 原 祥太郎,鹿園 直毅, 泉 聡志, 酒井 信介
    • Organizer
      日本機械学会2012年度年次大会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] Kinetic Monte Carlo Simulations of Microstructural Evolution in Solid Oxide Fuel Cell Cermet Anode2012

    • Author(s)
      Shikata, K., Hara, S., Shikazono, N., Izumi, S. and Sakai, S.
    • Organizer
      IUMRS-International Conference on Electronic Materials
    • Place of Presentation
      Yokohama
    • Related Report
      2012 Annual Research Report
  • [Presentation] Multiscale Modeling for Material Design of Solid Oxide Fuel Cell Electrodes2012

    • Author(s)
      Umeno, Y., Tada, T., Hara, S. and Shikazono, N.
    • Organizer
      ECI Harnessing the Materials Genome
    • Place of Presentation
      Colorado
    • Related Report
      2012 Annual Research Report
  • [Presentation] 固体酸化物形燃料電池燃料極の構造変化に関するナノ・メゾスケール解析2012

    • Author(s)
      原 祥太郎, 四方 健太郎,鹿園 直毅,泉 聡志,酒井 信介
    • Organizer
      日本機械学会第4回マイクロ・ナノ工学シンポジウム
    • Place of Presentation
      北九州
    • Related Report
      2012 Annual Research Report
  • [Presentation] Simulation of Solid Oxide Fuel Cell Anode Microstructure Evolution by Phase Field Method2012

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N.
    • Organizer
      第21回SOFC研究発表会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 3次元モンテカルロ法に基づくSOFC燃料極のNi粗大化現象解析2012

    • Author(s)
      原祥太郎,四方健太郎,孫瑜,鹿園直毅,泉聡志,酒井信介
    • Organizer
      第21回SOFC研究発表会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] Three Dimensional Numerical Simulation of SOFC Electrodes2011

    • Author(s)
      Shikazono, N.
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2011-12-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] Numerical Simulation of SOFC Electrode Polarization Using Three-Dimensional Microstructure Reconstructed by FIB-SEM2011

    • Author(s)
      Shikazono, N.
    • Organizer
      2011 MRS Fall Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2011-12-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] Study on Degradation of Solid Oxide Fuel Cell with Pure Ni Anode2011

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N
    • Organizer
      12 th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2011-05-03
    • Related Report
      2013 Final Research Report
  • [Presentation] 3D Quantitative characterization of Nickel-Yittria-stabilized Zirconia solid oxide fuel cell anode microstructure in discharge2011

    • Author(s)
      Jiao, Z., Shikazono, N. and Kasagi, N
    • Organizer
      第20回SOFC 研究発表会講演要旨集
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] Numerical Simulation of SOFC Electrode Polarization Using Three-Dimensional Microstructure Reconstructed by FIB-SEM2011

    • Author(s)
      Shikazono, N. and Kasagi, N
    • Organizer
      Proc. 2011 MRS Fall Meeting
    • Place of Presentation
      Boston, USA, C8.3, Boston
    • Related Report
      2013 Final Research Report
  • [Book] 「第1.3 節 Ni-YSZ 燃料極の形態変化」, ナノ・マイクロスケール機械工学2014

    • Author(s)
      鹿園直毅
    • Publisher
      東京大学出版会
    • Related Report
      2013 Final Research Report
  • [Book] 「第 6.2.1 項 固体酸化物形燃料電池」, ナノ・マイクロスケール機械工学2014

    • Author(s)
      鹿園直毅
    • Publisher
      東京大学出版会
    • Related Report
      2013 Final Research Report
  • [Book] CHAPTER 8 : Three Dimensional Numerical Modelling of Ni-YSZ Anode, Solid Oxide Fuel Cells : From Materials to System Modeling, Meng Ni and Tim S. Zhao (ed.)2013

    • Author(s)
      Shikazono, N. and Kasagi, N
    • Related Report
      2013 Final Research Report
  • [Book] Solid Oxide Fuel Cells: From Materials to System Modeling Chapter 82013

    • Author(s)
      Shikazono, N. and Kasagi, N.
    • Total Pages
      19
    • Publisher
      RSC Publishing
    • Related Report
      2013 Annual Research Report
  • [Book] ナノ・マイクロスケール機械工学 第1.3節 Ni-YSZ燃料極の形態変化2013

    • Author(s)
      鹿園直毅
    • Total Pages
      4
    • Publisher
      東京大学出版会
    • Related Report
      2013 Annual Research Report
  • [Book] ナノ・マイクロスケール機械工学 第6.2.1項 固体酸化物形燃料電池2013

    • Author(s)
      鹿園直毅
    • Total Pages
      5
    • Publisher
      東京大学出版会
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.feslab.iis.u-tokyo.ac.jp/

    • Related Report
      2011 Annual Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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