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DeNOx process using plasma-assisted catalytic reaction

Research Project

Project/Area Number 23360123
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Power engineering/Power conversion/Electric machinery
Research InstitutionToyohashi University of Technology

Principal Investigator

TAKASHIMA Kazunori  豊橋技術科学大学, 工学(系)研究科(研究院), 准教授 (60303707)

Co-Investigator(Kenkyū-buntansha) MIZUNO Akira  豊橋技術科学大学, 環境・生命工学系, 教授 (20144199)
Project Period (FY) 2011-11-18 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsプラズマ / ガス処理 / NOx / 放電プラズマ / 沿面放電 / スライド放電 / アンモニア / ディーゼルエンジン / 排ガス / 炭化水素 / 粒子化 / 湿度 / NH3-SCR
Research Abstract

Fundamental study on novel plasma-assited ammonia-SCR system and feasibility study on on-board ammonia production using discharge plasma were carried out aiming for compact and effective deNOx system for diesel exhaust from mobile source.
With respect to the plasma-assited SCR system, method to generate discharge plasma inside honeycomb catalyst was newly developed. The combination of discharge plasma and ammonia-SCR catalyst resulted in high deNOx characteristics at low temperatures where the catalyst cannot be activated thermally.
As for plasma assisted production of ammonia, we demonstrated that ammonia was produced from urea powder by means of intense discharge plasma. It was also found that ammonia can be generated from nitrogen and water with the help of discharge plasma.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (22 results)

All 2013 2012 2011 Other

All Journal Article (11 results) (of which Peer Reviewed: 3 results) Presentation (9 results) Remarks (2 results)

  • [Journal Article] Dielectric barrier discharge for ammonia production2013

    • Author(s)
      G . Prieto, K. T akashima, A. Mizuno, O. Prieto, and C. R. Gay
    • Journal Title

      Plasma Chemistry and Plasma Processing

      Volume: vol.33 Pages: 337-353

    • Related Report
      2013 Final Research Report
  • [Journal Article] Honeycomb Discharge Generated with a Single High V oltage Power Supply for Activating Catalyst2013

    • Author(s)
      K. T akashima, T . Suzuki, Y . Nomura, Y . Hinata, H. Hayashi, H. Kurita, and A. Mizuno
    • Journal Title

      International Journal of Plasma Environmental Science and Technology

      Volume: vol.7 Pages: 142-147

    • Related Report
      2013 Final Research Report
  • [Journal Article] Dielectric Barrier Discharge for Ammonia Production2013

    • Author(s)
      Graciela Prieto, Kazunori Takashima, Akira Mizuno, Oscar Prieto, and Carlos R. Gay
    • Journal Title

      Plasma Chemistry and Plasma Processing

      Volume: 33 Issue: 1 Pages: 337-353

    • DOI

      10.1007/s11090-012-9428-2

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of pellet-diameter on discharge characteristics and performance of a packed bed reactor2013

    • Author(s)
      M. Chen, K. Takashima, and , A. Mizuno
    • Journal Title

      nternational Journal of Plasma Environmental Science and Technolog

      Volume: 7 Pages: 89-95

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Honeycomb Discharge Generated with a Single High Voltage Power Supply for Activating Catalyst2013

    • Author(s)
      K. Takashima, T. Suzuki, Y. Nomura, Y. Hinata, H. Hayashi, H. Kurita, and A. Mizuno
    • Journal Title

      nternational Journal of Plasma Environmental Science and Technolog

      Volume: 7 Pages: 142-147

    • Related Report
      2013 Annual Research Report
  • [Journal Article] NOx Removal Using a Non-thermal Surface Plasma Discharge Powered by a Modulated Voltage2012

    • Author(s)
      J. Jolibois, K. T akashima, G . T ouchard, and A. Mizuno
    • Journal Title

      International Journal of Plasma Environmental Science and Technology

      Volume: vol.6 Pages: 74-80

    • Related Report
      2013 Final Research Report
  • [Journal Article] Application of a non-thermal surface plasma discharge in wet condition for gas exhaust treatment : NOx removal2012

    • Author(s)
      J. Jolibois, K. T akashima, and A. Mizuno
    • Journal Title

      Journal of Electrostatics

      Volume: vol.70 Pages: 300-308

    • Related Report
      2013 Final Research Report
  • [Journal Article] NOx Removal Using a Non-thermal Surface Plasma Discharge Powered by a Modulated Voltage2012

    • Author(s)
      J. Jolibois, K. Takashima, G. Touchard, and A. Mizuno
    • Journal Title

      International Journal of Plasma Environmental Science and Technology

      Volume: 6 Pages: 74-80

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of a non-thermal surface plasma discharge in wet condition for gas exhaust treatment: NOx removal2012

    • Author(s)
      J. Jolibois, K. Takashima, and A. Mizuno
    • Journal Title

      Journal of Electrostatics

      Volume: 70 Pages: 300-308

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] NOx removal using a wet type plasma reactor based on a three-electrode device2011

    • Author(s)
      J. Jolibois, K. T akashima, and A. Mizuno
    • Journal Title

      Journal of Physics : Conference Series

      Volume: vol.301 Pages: 12011-12011

    • Related Report
      2013 Final Research Report
  • [Journal Article] Effects of a transmission line on the properties of a surface discharge based on a segmented ground electrode design2011

    • Author(s)
      J. Jolibois, K. T akashima, and A. Mizuno
    • Journal Title

      Journal of Physics : Conference Series

      Volume: vol.301 Pages: 12021-12021

    • Related Report
      2013 Final Research Report
  • [Presentation] 多段式ハニカム内放電反応器を用いたディーゼルエンジン排ガス処理2013

    • Author(s)
      日向雄一, 鈴木智也, 林秀明, 栗田弘史, 高島和則, 水野彰
    • Organizer
      第37回静電気学会全国大会
    • Place of Presentation
      千葉
    • Related Report
      2013 Final Research Report
  • [Presentation] スライディング放電のプラズマパラメータにおける誘電体層の影響2012

    • Author(s)
      ジェローム・ジョリボア、高島和則、水野彰
    • Organizer
      第13回静電気学会春期講演会
    • Place of Presentation
      東京大学
    • Year and Date
      2012-03-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] 単一電源によるハニカム内放電を用いた触媒活性化技術の開発2012

    • Author(s)
      鈴木智也、林秀明、栗田弘史、高島和則、水野彰
    • Organizer
      第13回静電気学会春期講演会
    • Place of Presentation
      東京大学
    • Year and Date
      2012-03-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] Effect of Floating Electrodes on the Properties of a Surface Discharge2012

    • Author(s)
      J. Jolibois, K. Takashima and A. Mizuno
    • Organizer
      8th International Symposium on Non ‐Thermal/Thermal Plasma Pollution Control T echnology & Sustainable Energy
    • Place of Presentation
      France(ISNTP-8, S1-O3)
    • Related Report
      2013 Final Research Report
  • [Presentation] NOx removal using a wet type plasma reactor based on a non-thermal surface plasma discharge2012

    • Author(s)
      J. Jolibois, K. Takashima, and A. Mizuno
    • Organizer
      The 8th Conference of the French Society of Electrostatics (SFE)
    • Place of Presentation
      France(O16)
    • Related Report
      2013 Final Research Report
  • [Presentation] NOx reduction using surface discharge with a material variation of floating electrode2012

    • Author(s)
      J. Jolibois, K. T akashima, and A. Mizuno
    • Organizer
      International Symposium on Electrohydrodynamics, ISEHD 2012
    • Place of Presentation
      Poland
    • Related Report
      2013 Final Research Report
  • [Presentation] 室温における相対湿度がハニカム内放電に与える影響2011

    • Author(s)
      野村侑生、林秀明、高島和則、水野彰
    • Organizer
      第35回静電気学会全国大会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2011-09-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] 単一電源によるハニカム内放電を用いたディーゼルエンジン排ガス処理2011

    • Author(s)
      鈴木智也、林秀明、栗田弘史、高島和則、水野彰
    • Organizer
      第35回静電気学会全国大会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2011-09-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of honeycomb discharge for catalyst activation2011

    • Author(s)
      T . Suzuki, H. Hayashi, H. Kurita, K. Takashima, and A. Mizuno
    • Organizer
      Plasma Conference 2011
    • Place of Presentation
      Japan
    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://ens.tut.ac.jp/electrostatics/

    • Related Report
      2013 Final Research Report
  • [Remarks] 静電気応用研究室

    • URL

      http://ens.tut.ac.jp/electrostatics/

    • Related Report
      2013 Annual Research Report

URL: 

Published: 2013-05-15   Modified: 2019-07-29  

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