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Control of cation distribution in spinel type iron oxide particles

Research Project

Project/Area Number 23360276
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionTohoku University

Principal Investigator

WASEDA Yoshio  東北大学, 多元物質科学研究所, 名誉教授 (00006058)

Co-Investigator(Kenkyū-buntansha) SUZUKI Shigeru  東北大学, 多元物質科学研究所, 教授 (40143028)
SHINODA Kozo  東北大学, 多元物質科学研究所, 准教授 (10311549)
FUJIEDA Shun  東北大学, 多元物質科学研究所, 助教 (60551893)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2011: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Keywords金属物性 / 解析・評価 / 放射線、X線、粒子線 / 酸化鉄 / 超常磁性 / X線吸収分光 / 放射線・X線・粒子線
Research Abstract

The porous particles of maghemite were prepared from iron phosphate particles by a novel method using alkaline solution, and then these were immersed in a solution containing Co. The Co adsorbed porous particles of maghemite showed superparamagnetic behavior. The superparamagnetic blocking temperature of these particles was increased by the annealing. In addition, the results of X-ray absorption spectroscopy measurements showed that the local structure around Co in the Co adsorbed porous particles after annealing is very similar to that of CoFe2O4. Consequently, Co in the Co adsorbed porous particles after annealing probably locates at the cation vacancy site of maghemite.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (34 results)

All 2014 2013 2012 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (25 results) Remarks (4 results)

  • [Journal Article] Arsenic adsorption properties of porous iron oxide particles synthesized from iron phosphate particles using alkaline solution2014

    • Author(s)
      S. Fujieda, K. Shinoda, S. Suzuki
    • Journal Title

      Ceramic Transactions

      Volume: (印刷中)

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Influence of tungstate ions on transformation of green rust to ferric oxyhydroxide via aqueous solution investigated by in situ X-ray absorption spectroscopy2014

    • Author(s)
      S. Fujieda, A. Yoshino, K. Shinoda, S. Tsuri, S. Suzuki
    • Journal Title

      Corrosion Science

      Volume: 82 Pages: 85-92

    • DOI

      10.1016/j.corsci.2014.01.003

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] <i>In situ</i> Measurements of X-ray Absorption Spectra during Transformation of Green Rust to Ferric Oxyhydroxide Via Aqueous Solution2014

    • Author(s)
      S. Fujieda, A. Yoshino, K. Shinoda, S. Suzuki
    • Journal Title

      ISIJ International

      Volume: 54 Issue: 1 Pages: 125-130

    • DOI

      10.2355/isijinternational.54.125

    • NAID

      130003392828

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Magnetite Particles by Oxidation of Hydroxyl-chloride Green Rust Suspension under Controlled Conditions2013

    • Author(s)
      A. Yoshino, S. Fujieda, K. Shinoda, S. Suzuki
    • Journal Title

      ISIJ International

      Volume: 53 Issue: 5 Pages: 894-899

    • DOI

      10.2355/isijinternational.53.894

    • NAID

      10031195639

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dissolution Characteristics and Morphology of Large-sized Scorodite Particles Synthesized from Fe(II) and As(V) in Aqueous Solution2012

    • Author(s)
      S. Fujieda, K. Shinoda, T. Inanaga, M. Abumiya, S. Suzuki
    • Journal Title

      High Temperature Materials and Processes

      Volume: 31 Issue: 4-5 Pages: 451-458

    • DOI

      10.1515/htmp-2012-0080

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Synthesis of Novel Spinel Ferrites from Porous Iron Oxides Adsorbed by Different Cations2013

    • Author(s)
      T. Akiyama, M. Fukuoka, S. Fujieda, K. Shinoda, S. Suzuki
    • Organizer
      Euro Intelligent Materials
    • Place of Presentation
      Kiel, Germany
    • Related Report
      2013 Final Research Report
  • [Presentation] Retardation of the transformation rate of green rust to ferric oxyhydroxide by oxoaions in aqueous solution2013

    • Author(s)
      S. Fujieda, Y. Takahashi, K. Shinoda, S. Suzuki
    • Organizer
      Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis and Structural Characterization of Spinel-Ferrites/Maghemite Porous Particles2013

    • Author(s)
      K. Shinoda, M. Fukuoka, S. Fujieda, S. Suzuki
    • Organizer
      International Conference on Ferrites
    • Place of Presentation
      Okinawa, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis and Structural Characterization of Spinel-Ferrites/Maghemite Porous Particles2013

    • Author(s)
      Kozo Shinoda, Masayuki Fukuoka, Shun Fujieda, Shigeru Suzuki
    • Organizer
      International Conference on Ferrites (ICF 11)
    • Place of Presentation
      沖縄
    • Related Report
      2013 Annual Research Report
  • [Presentation] Retardation of the transformation rate of green rust to ferric oxyhydroxide by oxoaions in aqueous solution2013

    • Author(s)
      S. Fujieda, Y. Takahashi, K. Shinoda, S. Suzuki
    • Organizer
      Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      仙台
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis of Novel Spinel Ferrites from Porous Iron Oxides Adsorbed by Different Cations2013

    • Author(s)
      Takuya Akiyama, Masayuki Fukuoka, Shun Fujieda, Kozo Shinoda, Shigeru Suzuki
    • Organizer
      Euro Intelligent Materials
    • Place of Presentation
      Germany, Kiel
    • Related Report
      2013 Annual Research Report
  • [Presentation] Coを吸着させた多孔質鉄酸化物の熱処理による局所構造変化2013

    • Author(s)
      藤枝俊, 福岡誠之, 篠田弘造, 鈴木茂, 早稲田嘉夫
    • Organizer
      日本金属学会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 液相合成多孔質酸化鉄粒子の構造および特性評価2013

    • Author(s)
      篠田弘造, 福岡誠之, 藤枝俊, 鈴木茂, 早稲田嘉夫
    • Organizer
      資源・素材学会
    • Place of Presentation
      習志野
    • Related Report
      2012 Annual Research Report
  • [Presentation] 多孔質酸化鉄粒子の加熱による構造変化に及ぼす珪酸イオン吸着の影響2013

    • Author(s)
      神谷忠弘, 藤枝俊, 篠田弘造, 鈴木茂
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 液相法により作製した多孔質酸化鉄粒子へのCo 吸着およびその磁気特性2012

    • Author(s)
      福岡誠之, 藤枝 俊, 篠田弘造, 鈴木 茂, 早稲田嘉夫
    • Organizer
      日本金属学会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] 液相法により作製した多孔質酸化鉄粒子へのCo吸着およびその磁気特性2012

    • Author(s)
      福岡誠之、藤枝俊、篠田弘造、鈴木茂、早稲田嘉夫
    • Organizer
      日本金属学会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2012-03-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 多孔質酸化鉄粒子の加熱による構造変化に及ぼす珪酸イオン吸着の影響2012

    • Author(s)
      神谷忠弘, 藤枝 俊, 篠田弘造, 鈴木 茂
    • Organizer
      日本金属学会
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] 液相合成多孔質酸化鉄粒子の構造および特性評価2012

    • Author(s)
      篠田弘造, 福岡誠之, 藤枝 俊, 鈴木 茂, 早稲田嘉夫
    • Organizer
      資源・素材学会
    • Place of Presentation
      習志野
    • Related Report
      2013 Final Research Report
  • [Presentation] Co を吸着させた多孔質鉄酸化物の熱処理による局所構造変化2012

    • Author(s)
      藤枝 俊, 福岡誠之, 篠田弘造, 鈴木 茂, 早稲田嘉夫
    • Organizer
      日本金属学会
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] Novel Solution Phase Synthesis of Porous Iron Oxide Particles2012

    • Author(s)
      K. Shinoda, S. Fujieda, T. Fujita, S. Suzuki
    • Organizer
      French Research Organizations - Tohoku University Joint Workshop on Frontier Materials
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Influence of Zn and Sn on oxidation of Green Rust (Cl-) in aqueous solution2012

    • Author(s)
      S. Fujieda, K. Shinoda, S. Suzuki
    • Organizer
      International symposium on Recent Advance in Analytical Techniques for Steelmaking Industry
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] 水溶液中におけるグリーンラストの構造変化のその場X 線吸収分光測定2012

    • Author(s)
      吉野 絢, 藤枝 俊, 篠田弘造, 鈴木 茂
    • Organizer
      表面科学学術講演会
    • Place of Presentation
      松山
    • Related Report
      2013 Final Research Report
  • [Presentation] 水溶液中におけるFe(II)-Fe(III)酸化物の構造変化の放射光によるその場測定2012

    • Author(s)
      吉野 絢, 藤枝 俊, 篠田弘造, 鈴木 茂
    • Organizer
      日本金属学会
    • Place of Presentation
      松山
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] 準安定水酸化鉄の水溶液中酸化過程のその場X 線吸収分光2012

    • Author(s)
      藤枝 俊, 吉野 絢, 篠田弘造, 鈴木 茂
    • Organizer
      日本金属学会
    • Place of Presentation
      松山
    • Related Report
      2013 Final Research Report
  • [Presentation] 多孔質酸化鉄粒子の新規液相合成とその構造2012

    • Author(s)
      篠田弘造, 藤枝 俊, 鈴木 茂, 藤田哲雄
    • Organizer
      資源・素材学会
    • Place of Presentation
      秋田
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] 液相処理による多孔質酸化鉄粒子の合成およびその特性2012

    • Author(s)
      福岡誠之, 藤枝 俊, 篠田弘造, 鈴木 茂, 早稲田嘉夫
    • Organizer
      資源・素材学会
    • Place of Presentation
      秋田
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] 準安定水酸化鉄の水溶液中酸化過程のその場X線吸収分光2012

    • Author(s)
      藤枝 俊, 吉野 絢, 篠田弘造, 鈴木 茂
    • Organizer
      日本金属学会
    • Place of Presentation
      松山
    • Related Report
      2012 Annual Research Report
  • [Presentation] 水溶液中におけるグリーンラストの構造変化のその場X 線吸収分光測定2012

    • Author(s)
      吉野絢, 藤枝俊, 篠田弘造, 鈴木茂
    • Organizer
      表面科学学術講演会
    • Place of Presentation
      仙台
    • Related Report
      2012 Annual Research Report
  • [Presentation] Influence of Zn and Sn on oxidation of Green Rust (Cl-) in aqueous solution2012

    • Author(s)
      Shun Fujieda, Kozo Shinoda, Shigeru Suzuki
    • Organizer
      International symposium on Recent advance in analytical techniques for steelmaking industry
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] Novel Solution Phase Synthesis of Porous Iron Oxide Particles2012

    • Author(s)
      K. Shinoda, S. Fujieda, T. Fujita, S. Suzuki
    • Organizer
      5th French Research Organizations - Tohoku University Joint Workshop on Frontier Materials (FRONTIER 2012)
    • Place of Presentation
      仙台
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://db.tagen.tohoku.ac.jp/php/db/

    • Related Report
      2013 Final Research Report
  • [Remarks] 多元物質科学研究所 業績データベース

    • URL

      http://db.tagen.tohoku.ac.jp/php/db/

    • Related Report
      2013 Annual Research Report
  • [Remarks] 多元物質科学研究所 業績データベース

    • URL

      http://db.tagen.tohoku.ac.jp/php/db/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/

    • Related Report
      2011 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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