Development of ceramic-based membranes having chemical affinity

• Project/Area Number: 23360285
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic materials/Physical properties
• Research Institution: Nagoya Institute of Technology
• Principal Investigator: IWAMOTO YUJI 名古屋工業大学, 工学(系)研究科(研究院), 教授 (40399598)
• Co-Investigator(Kenkyū-buntansha): HASHIMOTO Shinobu 名古屋工業大学, 大学院・工学研究科, 准教授 (10242900) ; HONDA Sawao 名古屋工業大学, 大学院・工学研究科, 助教 (50301221)
• Project Period (FY): 2011-04-01 – 2014-03-31
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000); Fiscal Year 2013: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000); Fiscal Year 2012: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000); Fiscal Year 2011: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
• Keywords: 機能性セラミックス / ガス分離膜 / 化学親和性 / 水素 / 二酸化炭素 / 分離膜 / 無機・有機ハイブリッド

Research Abstract

Metal-organic precursor-derived novel ceramic based membranes have successfully synthesized. Microporous amorphous silica-based membranes having hydrogen affinity as well as conventional molecular sieve-like properties showed enhanced hydrogen permeance at and above 373 K. Organic/inorganic hybrid membranes composed of organoamino group-functionalized amorphous silica have been synthesized from silicon-based polymers. The facilitated transport of carbon dioxide was achieved by the organoamino groups as designed. For developing an efficient porous support for the ceramic membrane, macroporous alumina-based materials have been also designed and synthesized using alominosilicate polymers or alumina platelets.

Research Products

• [Journal Article] Fabrication and characterization of hardened bodies from Japanese volcanic ash using geopolymerization (2014)
  • Author(s): H. Takeda, S. Hashimoto, H. Kanie, S. Honda and Y. Iwamoto
  • Journal Title: Ceram. Int Volume: 40 Issue: 3 Pages: 4071-4076
  • DOI: 10.1016/j.ceramint.2013.08.061
  • Peer Reviewed
• [Journal Article] Rapid fabrication of highly dense geopolymers using a warm press method and their ability to absorb neutron irradiation (2014)
  • Author(s): H. Takeda, S. Hashimoto, H. Matsui, S. Honda and Y. Iwamoto
  • Journal Title: Construction and Building Materials Volume: 50 Pages: 82-86
  • DOI: 10.1016/j.conbuildmat.2013.09.014
  • Peer Reviewed
• [Journal Article] Hydrothermal stability of hydrogen permselective amorphous silica membrane synthesized by counter diffusion chemical vapor deposition method (2013)
  • Author(s): K. Miyajima, T. Eda, B. N. Nair, S. Honda and Y. Iwamoto
  • Journal Title: Journal of the Ceramic Society of Japan Volume: 121 Issue: 1420 Pages: 992-998
  • DOI: 10.2109/jcersj2.121.992
  • NAID: 130004950883
  • ISSN: 1348-6535, 1882-0743
  • Peer Reviewed
• [Journal Article] Fabrication and porous spinel (MgAl_2O_4) from porous alumina using a template method (2013)
  • Author(s): S. Hashimoto, S. Honda, T. Hiramatsu and Y. Iwamoto
  • Journal Title: Ceram. Int Volume: 39 Issue: 2 Pages: 2077-2081
  • DOI: 10.1016/j.ceramint.2012.08.062
  • Peer Reviewed
• [Journal Article] Characterization of Zeolite in Zeolite-geopolymer Hybrid Bulk Materials Derived from Kaolinitic Clays (2013)
  • Author(s): H. Takeda, S. Hashimoto, A. Yokoyama, S. Honda and Y. Iwamoto
  • Journal Title: Materials Volume: 6 Issue: 5 Pages: 1767-1778
  • DOI: 10.3390/ma6051767
  • Peer Reviewed
• [Journal Article] Improvement on characteristics of porous alumina from platelets using a TEOS treatment (2013)
  • Author(s): S. Honda, S. Hashimoto, Y. Ito, R. Hanai, H. Hirano and Y. Iwamoto
  • Journal Title: Ceram. Int. Volume: 39（2） Issue: 2 Pages: 1265-1270
  • DOI: 10.1016/j.ceramint.2012.07.057
  • Peer Reviewed
• [Journal Article] Organic-inorganic layered membrane for selective hydrogen permeation together with dehydration (2012)
  • Author(s): K. Miyajima, T. Eda, B. N. Nair, and Y. Iwamoto
  • Journal Title: J. Membr. Sci Volume: 421-422 Pages: 124-130
  • DOI: 10.1016/j.memsci.2012.07.002
  • Peer Reviewed
• [Presentation] 様々な微構造形態をもつアルミナ多孔体の特性 (2014)
  • Author(s): 本多沢雄、江田智一、渡邊裕和、宮嶋圭太、大幸裕介、橋本忍、岩本雄二
  • Organizer: 日本セラミックス協会2014年年会
  • Place of Presentation: 慶應義塾大学 神奈川
• [Presentation] Polymer-derived microporous amorphous silica (2014)
  • Author(s): Mohd Nazri MOHD SOKRI, S. HONDA, Y. IWAMOTO
  • Organizer: 3rd International Symposium on Ceramics nanotune Technology (ISCeNT-3)
  • Place of Presentation: 名古屋工業大学 名古屋
• [Presentation] Heat transfer in porous ceramic materials (2014)
  • Author(s): D. S. SMITH, B. NAIT-ALI, J. BOURRET, N. TESSIER-DOYEN, C. S. PEYRATOUT, S. HONDA, K. OTSU, H. MATSUBARA, S. HASHIMOTO, Y. IWAMOTO
  • Organizer: 3rd International Symposium on Ceramics nanotune Technology (ISCeNT-3)
  • Place of Presentation: 名古屋工業大学 名古屋
• [Presentation] The stress analysis of porous ceramic support tube in module of ceramic separation membranes (2014)
  • Author(s): S. Honda, S. Hashimoto, Y. Daiko, T. Eda, H. Watanabe, K. Miyajima and Y. Iwamoto
  • Organizer: 38th International Conference & Exposition on Advanced Ceramics & Composites (ICACC’14)
  • Place of Presentation: Daytona Beach, USA
• [Presentation] セラミック分離膜支持基材用多孔体の物性と微構造評価 (2014)
  • Author(s): 本多沢雄、江田智一、渡辺裕和、宮嶋圭太、大幸裕介、橋本忍、岩本雄二
  • Organizer: 第52回セラミックス基礎科学討論会
  • Place of Presentation: ウインクあいち 愛知
• [Presentation] Gas permeation properties of amorphous silica-based membranes having chemical affinity (2013)
  • Author(s): Y. Iwamoto
  • Organizer: The International Conference on High-Performance Ceramics (CICC-8)
  • Place of Presentation: Chongqing, China
• [Presentation] Gas permeation behaviors of amorphous silica-based composite membranes (2013)
  • Author(s): Y. Iwamoto, A. Mori, H. Mizuno, K. Hataya, S. Sakaida and S. Honda
  • Organizer: 13th Conference of the European Ceramic Society (ECerS13)
  • Place of Presentation: Limoge France
• [Presentation] 粒子配向アルミナの作製とその熱および機械的特性評価 (2013)
  • Author(s): 橋本 忍、本多沢雄、岩田周也、岩本雄二
  • Organizer: 平成25年度日本セラミックス協会東海支部学術研究発表会
  • Place of Presentation: 名城大学 名古屋
• [Presentation] 非晶質シリカ系材料の水素との反応挙動 (2013)
  • Author(s): 多田翔太朗、水野秀紀、大幸祐介、本多沢雄、岩本雄二
  • Organizer: 平成25年度日本セラミックス協会東海支部学術研究発表会
  • Place of Presentation: 名城大学 名古屋
• [Presentation] Effect of Pore Microstructure on Properties of Porous Alumina for Support Substrates of Permselective Ceramic Membranes (2013)
  • Author(s): S. Honda, Y. Daiko, S. Hashimoto, T. Eda, H. Watanabe, K. Miyajima, B. Nait Ari, D. S. Smith and Y. Iwamoto
  • Organizer: The 30th Japan-Korea International Seminar on Ceramics
  • Place of Presentation: 北九州
• [Presentation] セラミック分離膜支持基材用アルミナ多孔体物性におよぼす微構造の影響 (2013)
  • Author(s): 本多沢雄、大幸裕介、橋本忍、江田智一、渡邊裕和、宮嶋圭太、Benoit Nait-Ali、David Smith、岩本雄二
  • Organizer: 第26回秋季シンポジウム
  • Place of Presentation: 信州大学
• [Presentation] Improvement of Properties on Porous Alumina from Platelets with Solution Immersion and Reheating Treatment (2013)
  • Author(s): S. Hashimoto, S. Honda and Y. Iwamoto
  • Organizer: 13th Conference of the European Ceramic Society (ECerS13)
  • Place of Presentation: Limoge France
• [Presentation] Chemical formation of silicon nitride-based ceramics from polymer precursors (2013)
  • Author(s): Y. Iwamoto
  • Organizer: 13th Conference of the European Ceramic Society (ECerS13)
  • Place of Presentation: Limoge France
  • Invited
• [Presentation] Effect of microstructure on properties of porous alumina for support substrates of permselective ceramic membranes (2013)
  • Author(s): S. Honda, N. Nishihara, T. Eda, H. Watanabe, K. Miyajima, S. Hashimoto,N. A. Benoit and D. S. Smith
  • Organizer: 13th Conference of the European Ceramic Society (ECerS13)
  • Place of Presentation: Limoge France
• [Presentation] Synthesis and characterization of polymer-derived micro-/meso-porous amorphous silica-based materials for gas separation membranes (2013)
  • Author(s): T. Onishi, A. Kawai, Y. Yamada, T. Hiramatsu, S. Honda and Y. Iwamoto
  • Organizer: 13th Conference of the European Ceramic Society (ECerS13)
  • Place of Presentation: Limoge France
• [Presentation] Gas permeation and fatigue properties of macroporous porous alumina for porous tubelar support for microporous ceramic membranes (2013)
  • Author(s): S. Honda, S. Hashimoto, T. Eda, H. Watanabe, K. Miyajima and Y. Iwamoto
  • Organizer: 6th International Zeolite membrane Meeting(IZMM2013)
  • Place of Presentation: Jeju Island, Korea
• [Presentation] Fabrication of the Hardened Bodies from Japanese Volcanic Ash using an Alkali-activated Cement (Geopolymer) Technique (2013)
  • Author(s): S. Hashimoto, H. Takeda, H. Kanie, S. Honda and Y. Iwamoto
  • Organizer: 10th Pacific Rim Conference on Ceramic and Glass Technology(PACRIM10)
  • Place of Presentation: San Diego, CA, USA
• [Presentation] Synthesis and characterization of organoamino group-functionalized amorphous silica (2013)
  • Author(s): Y. Iwamoto, T. Hiramatsu, T. Onishi, A. Kawai and S. Honda
  • Organizer: 10th Pacific Rim Conference on Ceramic and Glass Technology(PACRIM10)
  • Place of Presentation: San Diego, CA, USA
• [Presentation] Organic-inorganic layered membrane for selective hydrogen permeation together with dehydration (2013)
  • Author(s): K. Miyajima, T. Eda, B. N. Nair and Y. Iwamoto
  • Organizer: 10th Pacific Rim Conference on Ceramic and Glass Technology(PACRIM10)
  • Place of Presentation: San Diego, CA, USA
• [Presentation] Influence of microstructure on Properties of Porous Alumina for Support Substrates of Ceramic Membranes (2013)
  • Author(s): S. Honda, N. Nishihara, T. Eda, H. Watanabe, K. Miyajima, S. Hashimoto, B. Nait Ari, D. S. Smith and Y. Iwamoto
  • Organizer: 10th Pacific Rim Conference on Ceramic and Glass Technology(PACRIM10)
  • Place of Presentation: San Diego, CA, USA
• [Presentation] Microporous Amorphous Ceramic-Based Membranes for Gas Separation (2013)
  • Author(s): Yuji Iwamoto
  • Organizer: International Conference on Nanoscience and Nanotechnology 2013 (NANO-SCITECH 2013)
  • Place of Presentation: Selangor, Malaysia
  • Invited
• [Presentation] Gas permeation properties of microporous amorphous silica-based membranes (2013)
  • Author(s): Y. Iwamoto, A. Mori, H. Mizuno, A. Kimura, K. Hataya and S. Honda
  • Organizer: 37th International Conference & Exposition on Advanced Ceramics & Composites (ICACC’13)
  • Place of Presentation: Daytona Beach, USA
• [Presentation] Gas permeation properties of amorphous silica-based composite membranes having chemical affinity toward hydrogen (2012)
  • Author(s): Y. Iwamoto
  • Organizer: 2012 MRS Fall Meeting & Exhibit
  • Place of Presentation: Boston, USA
• [Presentation] Gas permeation properties of microporous amorphous silica-based ceramic membranes (2012)
  • Author(s): Y. Iwamoto
  • Organizer: Cellular Materials 2012
  • Place of Presentation: Dresden, Germany
• [Presentation] Gas permeation properties of amorphous silica-based composite membranes having chemical affinity toward hydrogen (2012)
  • Author(s): Yuji Iwamoto
  • Organizer: 2012 MRS Fall Meeting & Exhibit
  • Place of Presentation: Boston, MA
  • Invited
• [Presentation] 板状アルミナ粒子を用いたスピネル多孔体の作製 (2012)
  • Author(s): 橋本忍、平松知樹、本多沢雄、岩本雄二
  • Organizer: 第25回秋季シンポジウム
  • Place of Presentation: 名古屋
• [Presentation] Microporous ceramic-based membranes for gas separation (2012)
  • Author(s): Yuji Iwamoto
  • Organizer: International Workshop on Advanced Ceramics (IWAC05)
  • Place of Presentation: London
  • Invited
• [Presentation] High-temperature reaction behaviors between metal cation-doped amorphous silica and hydrogen (2012)
  • Author(s): K. Higashiguchi , K. Hataya, S. Honda and Y. Iwamoto
  • Organizer: International Workshop on Advanced Ceramics (IWAC05)
  • Place of Presentation: London
• [Presentation] Hydrogen affinity of amorphous silica-based materials (2012)
  • Author(s): A. Kimura, K. Higashiguchi, S. Honda and Y. Iwamoto
  • Organizer: International Workshop on Advanced Ceramics (IWAC05)
  • Place of Presentation: London
• [Presentation] Precursors-derived porous ceramic-based membranes for gas separation (2012)
  • Author(s): Yuji Iwamoto
  • Organizer: 4th International Congress on Ceramics(ICC4)
  • Place of Presentation: Chicago, USA
  • Invited
• [Presentation] Precursors-derived ceramic membranes for gas separation (2012)
  • Author(s): Yuji Iwamoto
  • Organizer: International Symposium on Ceramic Materials and Components for Energy and Environmental Applications(10th CMCEE）
  • Place of Presentation: Dresden,Germany
  • Invited
• [Presentation] Synthesis and characterization of amorphous silica-based inorganic-organic hybrid membranes for carbon dioxide separation (2012)
  • Author(s): A. Kawai, S. Honda, Y. Iwamoto, K. Miyajima and K. Sakimoto
  • Organizer: International Symposium on Ceramic Materials and Components for Energy and Environmental Applications(10th CMCEE）
  • Place of Presentation: Dresden,Germany
• [Presentation] アモルファスシリカ系材料の高温水素反応挙動 (2012)
  • Author(s): 岩本雄二
  • Organizer: 日本セラミックス協会2012年年会サテライトプログラム第5回ケミカルプロセス研究討論会
  • Place of Presentation: 京都
• [Presentation] 分離膜支持基材用アルミナ多孔体の微構造と特性評価 (2012)
  • Author(s): 本多沢雄、西原教真、江田智一、渡辺裕和、宮嶋圭太、橋本忍、岩本雄一
  • Organizer: 日本セラミックス協会2012年年会
  • Place of Presentation: 京都
• [Presentation] Ceramic membranes for gas separation (2012)
  • Author(s): Y.Iwamoto
  • Organizer: Nanomaterials Technology Specialized Conference (NTSC2012)
  • Place of Presentation: Johor Bahru, Malaysia(招待講演)
• [Presentation] Synthesis and characterization of carbon dioxide-permselective organoamino group-functionalized amorphous silica membranes (2012)
  • Author(s): A.Kawai, K.Miyajima, K.Sekimoto, S.Honda, Y.Iwamoto
  • Organizer: 36th International Conference & Exposition on Advanced Ceramics & Composites
  • Place of Presentation: Daytona Beach, USA
• [Presentation] Gas Permiability and Fracture Properties of Porous Alumina with Vario us Pore Structures for Support Substrates of Ceramic Membranes (2012)
  • Author(s): S.Honda, N.Nishihara, S.Hashimoto, T.Eda, H.Watanabe, K.Miyajima, Y.Iwamoto
  • Organizer: 36th International Conference & Exposition on Advanced Ceramics & Composites
  • Place of Presentation: Daytona Beach, USA
• [Presentation] Strengthening technique of porous alumina using a TEOS solution treatment (2012)
  • Author(s): S.Hashimoto, R.Hanai, Y.Ito, S.Honda, Y.Iwamoto
  • Organizer: 36th International Conference & Exposition on Advanced Ceramics & Composites
  • Place of Presentation: Daytona Beach, USA
• [Presentation] Local structural characterizations of transition metal cation-doped amorphous silica-based membranes for high-temperature gas separation (2012)
  • Author(s): A.Mori, K.Higashiguchi, K.Hataya, S.Honda, Y.Iwamoto
  • Organizer: 36th International Conference & Exposition on Advanced Ceramics & Composites
  • Place of Presentation: Daytona Beach, USA
• [Presentation] アモルファスシリカ系無機有機ハイブリッド膜の合成とガス透過特性 (2011)
  • Author(s): 川合瑛、関本光一郎、宮嶋圭太、本多沢雄、岩本雄二
  • Organizer: 平成23年度日本セラミックス協会東海支部学術研究発表会
  • Place of Presentation: 名古屋
  • Year and Date: 2011-12-03
• [Presentation] Polymer-derived ceramic membranes for gas separation (2011)
  • Author(s): Y. Iwamoto
  • Organizer: ECerS VII 12th Conference of the European Ceramic Society
  • Place of Presentation: Stockholm, Sweden
• [Presentation] 遷移金属添加アモルファスシリカと高温水素の反応挙動 (2011)
  • Author(s): 森昭人、東口鉱平、幡谷耕二、本多沢雄、岩本雄二
  • Organizer: 日本セラミックス協会第24回秋季シンポジウム
  • Place of Presentation: 北海道
• [Presentation] Polymer-derived ceramic membranes for gas separation (2011)
  • Author(s): Y.Iwamoto
  • Organizer: ECerS XII 12th Conference of the European Ceramic Society
  • Place of Presentation: Stockholm, Sweden(招待講演)
• [Book] アルミナ系多孔質耐火物骨材の作製と評価 (2013)
  • Author(s): セラミックデータブック 2013/14
  • Total Pages: 4
  • Publisher: 工業製品技術協会（株式会社テクノプラザ）
• [Book] ガス分離膜用多孔質基材のガス透過特性と熱・機械的特性 (2011)
  • Author(s): 本多沢雄, 宮嶋圭太, 岩本雄二
  • Publisher: セラミックデータブック, 工業製品技術協会
• [Book] セラミックス製高温水素分離膜, セラミックス機能化ハンドブック (2011)
  • Author(s): 岩本 雄二
  • Publisher: (株)エス・ティ・エヌ
• [Remarks]
  • URL: http://chempro.web.nitech.ac.jp/index.html
• [Remarks] 岩本研究室 ホームページ
  • URL: http://chempro.web.nitech.ac.jp/index.html
• [Remarks] 名古屋工業大学 岩本研HP
  • URL: http://chempro.web.nitech.ac.jp/index.html
• [Remarks]
  • URL: http://nitzy.mse.nitech.ac.jp/~iwamotolab/index.html