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Fabrication of a new nanocomposite by the electrospinning/electrospray method

Research Project

Project/Area Number 23360294
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Materials/Mechanics of materials
Research InstitutionKeio University

Principal Investigator

HOTTA Atsushi  慶應義塾大学, 理工学部, 教授 (30407142)

Project Period (FY) 2011-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2013: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2011: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Keywordsナノファイバ / ポリマ / 複合材料 / エレクトロスピニング / 生分解 / 高機能性 / ポリマー / ファイバー / 力学物性 / 均一分散 / コンポジット / ナノビーズ・ファイバー
Outline of Final Research Achievements

The purpose of this study was to establish a new method for new polymer composites, in which polymer nanofibers were well-dispersed. The method was also utilized to make a new functional composite. In particular, by ejecting polymer nanofibers into liquid polymer or polymer solution using the electrospinning method, well-dispersed polymeric nanofiber composites have been produced. An organic solvent, in which polymer nanofibers could be well dispersed, was carefully selected from twelve organic solvents. New functional composites were then made by this new method. A biodegradable poly(ε-caprolactone) (PCL) was used as a matrix material, and poly(vinyl alcohol) (PVA) with high mechanical properties and high heat resistance was selected as a nanofiber-reinforcement material. The resulting polymer-fiber composites possessed biodegradability, high Young’s modulus, and high heat resistance.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (43 results)

All 2015 2014 2013 2012 2011

All Journal Article (12 results) (of which Peer Reviewed: 12 results,  Acknowledgement Compliant: 2 results) Presentation (25 results) Book (4 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Structural and mechanical properties of cellulose composites made of isolated cellulose nanofiber and poly(vinyl alcohol)2015

    • Author(s)
      Y. Oishi, M. Nakaya, E. Matsui, A. Hotta
    • Journal Title

      Composites Part A

      Volume: 73 Pages: 72-79

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Biodegradability, reprocessability, and mechanical properties of polybutylene succinate (PBS) photografted by hydrophilic or hydrophobic membranes2015

    • Author(s)
      S. Mizuno, T. Maeda, C. Kanemura, A. Hotta
    • Journal Title

      Polymer Degradation and Stability

      Volume: 未定 Pages: 58-65

    • DOI

      10.1016/j.polymdegradstab.2015.03.015

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Micropatterning of silica nanoparticles by electrospray deposition through a stencil mask2014

    • Author(s)
      Higashi, K., Uchida, K., Hotta, A., Hishida, K. & Miki, N.
    • Journal Title

      Journal of Laboratory Automation

      Volume: 19 Issue: 1 Pages: 75-81

    • DOI

      10.1177/2211068213495205

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Basic Fibroblast Growth Factor as a Potential Stent Coating Material Inducing Endothelial Cell Proliferation2014

    • Author(s)
      Kitamura, N., Hasebe, T., Matsumoto, T, Hotta, A., Suzuki, T., Yamagami, T. & Terada, H.
    • Journal Title

      Journal of Atherosclerosis and Thrombosis

      Volume: 21 Issue: 5 Pages: 477-485

    • DOI

      10.5551/jat.20404

    • NAID

      130004444732

    • ISSN
      1340-3478, 1880-3873
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and characterization of 2-methacryloyloxyethyl phosphorylcholine polymer nanofibers prepared via electrospinning for biomedical materials2014

    • Author(s)
      Maeda, T., Hagiwara, K., Yoshida, S., Hasebe, T. & Hotta, A.
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 131 Issue: 14 Pages: 40606-40606

    • DOI

      10.1002/app.40606

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of salt concentrations on the structural transitions of peptide-amphiphile solution2014

    • Author(s)
      Otsuka, T. & Hotta, A.
    • Journal Title

      Materials Research Society Symposia Proceedings

      Volume: 1622 Pages: 147-152

    • DOI

      10.1557/opl.2014.40

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The structure and the mechanical properties of a newly fabricated cellulose-nanofiber/polyvinyl-alcohol composite2014

    • Author(s)
      Oishi, Y. & Hotta, A.
    • Journal Title

      Materials Research Society Symposia Proceedings

      Volume: 1621 Pages: 149-154

    • DOI

      10.1557/opl.2014.141

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrophobicity and non-thrombogenicity of nanoscale dual rough surface coated with fluorine-incorporated diamond-like carbon films: Biomimetic surface for blood-contacting medical devices2013

    • Author(s)
      Hasebe, T., Nagashima, S., Kamijo, A., Moon, M.W., Kashiwagi, Y., Hotta, A., Lee, K.R., Takahashi, K., Yamagami, T. & Suzuki, T.
    • Journal Title

      Diamond and Related Materials

      Volume: 38 Pages: 14-18

    • DOI

      10.1016/j.diamond.2013.06.001

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Manufacture of glass nanoparticles by electrospraying2013

    • Author(s)
      Uchida, K., Hotta, A., Hishida, K. & Miki, N
    • Journal Title

      Journal of Micromechanics and Micorengineering

      Volume: Vol.23, No.2 Issue: 2 Pages: 25023-25023

    • DOI

      10.1088/0960-1317/23/2/025023

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of plasma treatments on the controlled drug release from poly(ethylene-co-vinyl acetate)2013

    • Author(s)
      Hagiwara, K., Hasebe, T. & Hotta, A.
    • Journal Title

      Surface and Coatings Technology

      Volume: Vol.216 Pages: 318-323

    • DOI

      10.1016/j.surfcoat.2012.11.064

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical properties and chemical structures of biodegradable poly(butylene-succinate) for material reprocessing2012

    • Author(s)
      Kanemura, C., Nakashima, S. & Hotta, A.
    • Journal Title

      Polymer Degradation and Stability

      Volume: Vol.97,Issue6 Issue: 6 Pages: 972-980

    • DOI

      10.1016/j.polymdegradstab.2012.03.015

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Studies on the solution parameters for the fabrication of thinner silicone fibers by electrospinning2012

    • Author(s)
      Nakano, A., Miki, N., Hishida, K. & Hotta, A.
    • Journal Title

      Physical Review E

      Volume: Vol.86 Issue: 1 Pages: 11801-11801

    • DOI

      10.1103/physreve.86.011801

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Structure and mechanical properties of isotactic polypropylene (iPP) gels formed at different cooling temperatures2015

    • Author(s)
      R. Okoshi, A. Hotta
    • Organizer
      APS March Meeting 2015
    • Place of Presentation
      San Antonio, USA
    • Year and Date
      2015-03-02 – 2015-03-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Mechanical properties and biodegradability of polylactide (PLA) with poly(vinyl alcohol) (PVA) nanofibers2014

    • Author(s)
      N. Kurokawa, A. Hotta
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス, 長崎
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Structure and mechanical properties of dried syndiotactic polypropylene gels formed at different cooling temperatures2014

    • Author(s)
      S. Mizuno,A. Hotta
    • Organizer
      APS March Meeting
    • Place of Presentation
      Colorado,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Biodegradability and mechanical properties of poly(butylene succinate) composites with finely dispersed hydrophilic poly(acrylic acid)2014

    • Author(s)
      S. Mizuno,A. Hotta
    • Organizer
      APS March Meeting
    • Place of Presentation
      Colorado,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] A new method for the alignment of electrospun nanofibers by oxygen plasma treatment2014

    • Author(s)
      N. Kobayashi,N. Miki,K. Hishida,A. Hotta
    • Organizer
      APS March Meeting
    • Place of Presentation
      Colorado,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effects of O2 plasma treatment of PDMS on the deposition of electrospun PVA nanofibers2014

    • Author(s)
      N. Kobayashi,N. Miki,K. Hishida,A. Hotta
    • Organizer
      APS March Meeting
    • Place of Presentation
      Colorado,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Controlling the biodegradability of poly(butylene succinate) by photoinduced graft polymerization2013

    • Author(s)
      T. Maeda,C. Kanemura,A. Hotta
    • Organizer
      ACS March Meeting
    • Place of Presentation
      New Orleans,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Syndiotactic polypropylene nanofibers fabricated by a solution electrospinning method with single solvent at ambient temperature2013

    • Author(s)
      T. Maeda,K. Takaesu,A. Hotta
    • Organizer
      ACS March Meeting
    • Place of Presentation
      New Orleans,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] The sol-gel behavior of triblock-copolymer solution in controlling the solvent selectivity2013

    • Author(s)
      T. Maeda,A. Hotta
    • Organizer
      The 13th Pacific Polymer Conference
    • Place of Presentation
      Kaohsiung, Taiwan
    • Related Report
      2013 Annual Research Report
  • [Presentation] The role of sol-gel behavior of copolymer solution in the formation of elastomeric block-copolymer nanofibers2013

    • Author(s)
      T. Maeda,A. Hotta
    • Organizer
      The 13th Pacific Polymer Conference
    • Place of Presentation
      Kaohsiung, Taiwan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Preparation and characterization of phospholipid polymer nanofibers via electrospinning for tissue-engineered vascular grafts2013

    • Author(s)
      K. Hagiwara,A. Hotta
    • Organizer
      The 13th Pacific Polymer Conference
    • Place of Presentation
      Kaohsiung, Taiwan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Human umbilical vein endothelial cell interaction with phospholipid polymer nanofibers2013

    • Author(s)
      K. Hagiwara,A. Hotta
    • Organizer
      The 13th Pacific Polymer Conference
    • Place of Presentation
      Kaohsiung, Taiwan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effects of salt concentrations on the structural transitions of peptide-amphiphile solution2013

    • Author(s)
      T. Otsuka,A. Hotta
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] The gelation behavior observed in aqueous solutions of peptide amphiphile at different NaCl concentrations2013

    • Author(s)
      T. Otsuka,A. Hotta
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effects of alcohol on the rheology and the dispersion state of aqueous silica suspension2013

    • Author(s)
      A. Murano,A. Hotta
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Solvent and temperature dependence of the one-dimensional assembly and the 3D network formation observed in silica-nanoparticle solutions2013

    • Author(s)
      A. Murano,A. Hotta
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] The Structure and the Mechanical Properties of a Newly Fabricated Cellulose-Nanofiber/Polyvinyl-Alcohol Composite2013

    • Author(s)
      Y. Oishi,A. Hotta
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Elastomeric Block-Copolymer Nanofibers Fabricated by Electrospinning2013

    • Author(s)
      Y. Oishi,A. Hotta
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Gelation Behavior of SIS Triblock-Copolymer Solution Controlled by Mixed Solvents2013

    • Author(s)
      T. Maeda,A. Hotta
    • Organizer
      2013 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Newly developed drug-eluting stent (DES) system for cardiovascular diseases2013

    • Author(s)
      )T. Hasebe,T. Kigtagawa,S. Nagashima,T. Matsumoto,N. Kitamura,A. Hotta,T. Suzuki
    • Organizer
      International Symposium on Atomic Level
    • Place of Presentation
      Hawaii,USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Mechanical properties of homogeneous nanofiber composites fabricated by electrospinning2013

    • Author(s)
      Watanabe, K., Hotta, A.
    • Organizer
      APS March Meeting 2013
    • Place of Presentation
      Baltimore, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] A new method for homogeneous and uniformly dispersed nanofiber composites using electrospininng2013

    • Author(s)
      Watanabe, K., Hotta, A.
    • Organizer
      APS March Meeting 2013
    • Place of Presentation
      Baltimore, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Mechanical similarities observed between polypropylene gels and molten polypropylenes2013

    • Author(s)
      Ouchi, T., Yamazaki, M., Hotta, A.
    • Organizer
      APS March Meeting 2013
    • Place of Presentation
      Baltimore, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Improvement of the adhesion force between DLC and polymers by CVD method with photografting polymerization2012

    • Author(s)
      Takahashi, J., Hotta, A.
    • Organizer
      39th ICMCTF, International Conference on Metallurgical Coating and Thin Films
    • Place of Presentation
      San Diego, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] エレクトロスピニング法を用いた新規手法により作製したナノファイバーコンポジット2011

    • Author(s)
      渡辺憲太郎, 堀田篤
    • Organizer
      繊維学会年次大会
    • Place of Presentation
      船堀タワーホール
    • Year and Date
      2011-06-08
    • Related Report
      2011 Annual Research Report
  • [Book] 次世代ポリオレフィン総合研究 Vol. 82014

    • Author(s)
      大越 隆介、堀田 篤
    • Total Pages
      136
    • Publisher
      三恵社
    • Related Report
      2014 Annual Research Report
  • [Book] Thin Films and Coatings in Biology2013

    • Author(s)
      A. Hotta,T. Hasebe
    • Total Pages
      365
    • Publisher
      Springer
    • Related Report
      2013 Annual Research Report
  • [Book] 次世代ポリオレフィン総合研究,Vol. 72013

    • Author(s)
      前田知貴,堀田篤
    • Total Pages
      174
    • Publisher
      三恵社
    • Related Report
      2013 Annual Research Report
  • [Book] 次世代ポリオレフィン総合研究62012

    • Author(s)
      中村浩二,白石嵩人,堀田篤
    • Total Pages
      6
    • Publisher
      三恵社
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] コンポジットの製造方法及びそのコンポジット2012

    • Inventor(s)
      堀田篤, 渡辺憲太郎
    • Industrial Property Rights Holder
      慶應義塾大学
    • Industrial Property Number
      2011-021043
    • Filing Date
      2012-02-01
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] コンポジットの製造方法及びそのコンポジット2012

    • Inventor(s)
      堀田篤, 渡辺憲太郎
    • Industrial Property Rights Holder
      慶應義塾大学
    • Filing Date
      2012-02-02
    • Related Report
      2011 Annual Research Report
    • Overseas

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Published: 2011-04-06   Modified: 2019-07-29  

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