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A Low-Temperature Bonding Process Using Nanoparticles Derived from Reduction Reaction and Its Application to Micro Joining

Research Project

Project/Area Number 23360322
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionOsaka University

Principal Investigator

HIROSE Akio  大阪大学, 工学(系)研究科(研究院), 教授 (70144433)

Co-Investigator(Kenkyū-buntansha) SANO Tomokazu  大阪大学, 大学院・工学研究科, 准教授 (30314371)
OGURA Tomo  大阪大学, 大学院・工学研究科, 助教 (90505984)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2013: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2011: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Keywords接合 / ナノ材料 / 界面制御 / 焼結 / 還元反応 / 有機溶剤 / 実装 / 材料加工・処理 / 高密度実装 / 材料加工処理
Research Abstract

We have developed a low-temperature bonding process utilizing low-temperature sintering ability of nanoparticles derived from reducing metallic oxides, such as the silver oxide, by organic solvents. Gold, copper, nickel and aluminum can be bonded using this bonding process. Gold having no surface oxide layer has been directly bonded by sintered silver particles. In copper and nickel, bonding has been accomplished after reducing their natural oxides layers by the organic solvents during bonding process. Bonding of aluminum has been achieved through its natural oxide layer, which cannot be reduced by the organic solvents. Bondability of copper has been improved by applying a paste made by mixing the copper oxide with the silver oxide to an adequate ratio.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (54 results)

All 2014 2013 2012 2011

All Journal Article (17 results) (of which Peer Reviewed: 15 results) Presentation (36 results) (of which Invited: 7 results) Book (1 results)

  • [Journal Article] 酸化銀ー酸化銅ペーストを用いた接合の継手特性評価2014

    • Author(s)
      藤本智之、小椋智、廣瀬明夫
    • Journal Title

      第20回エレクトロニクスにおけるマイクロ接合・実装技術シンポジウム(Mate2014)論文集

      Volume: 第20巻 Pages: 131-136

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bondability of Copper Joints Formed Using a Mixed Paste of Ag<sub>2</sub>O and CuO for Low-Temperature Sinter Bonding2013

    • Author(s)
      T. Ogura, T. Yagishita, S. Takata, T. Fujimoto and A. Hirose
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 54 Issue: 6 Pages: 860-865

    • DOI

      10.2320/matertrans.MD201202

    • NAID

      10031176398

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Polyethylene Glycols with Different Polymer Chain Lengths on the Bonding Process Involving <i>In Situ</i> Formation of Silver Nanoparticles from Ag<sub>2</sub>O2013

    • Author(s)
      T. Yagishita, T. Ogura and A. Hirose
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 54 Issue: 6 Pages: 866-871

    • DOI

      10.2320/matertrans.MD201201

    • NAID

      10031176399

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of solvents in polyethylene glycol series on the bonding of copper joints using Ag_2O paste2013

    • Author(s)
      S. Takata, T. Ogura and A. Hirose
    • Journal Title

      Journal of Electronic Materials

      Volume: Vol. 42 Issue: 3 Pages: 507-515

    • DOI

      10.1007/s11664-012-2354-5

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selection of Particle Size and Solvent to Lower the Pressure Required for Metal-to-Metal Bonding using Silver Nanoparticle Pastes2013

    • Author(s)
      Tomo Ogura, Yosuke Konaka, Eichi Ide, Toshiaki Morita, Akio Hirose
    • Journal Title

      Quarterly Journal of the Japan Welding Society

      Volume: Vol. 31 Pages: 197-201

    • NAID

      130004445763

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bondability of copper joints formed using a mixed paste of Ag2O and CuO for low-temperature sinter bonding2013

    • Author(s)
      Tomo Ogura, Tomohiro Yagishita, Shinaya Takata, Tomoyuki Fujimoto, Akio Hirose
    • Journal Title

      Materials Transactions

      Volume: Vol. 56 Pages: 860-865

    • NAID

      130004786466

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of polyethylene glycols with different polymer chain lengths on the bonding process involving in situ formation of silver nanoparticles from Ag2O2013

    • Author(s)
      Tomohiro Yagishita, Tomo Ogura, Akio Hirose
    • Journal Title

      Materials Transactions

      Volume: Vol. 56 Pages: 866-871

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 酸化銀ペーストを用いた接合における接合界面組織解析2013

    • Author(s)
      高田 慎也
    • Journal Title

      第19回エレクトロニクスにおけるマイクロ接合・実装技術シンポジウム(Mate2013)論文集

      Volume: 19巻 Pages: 83-88

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 銅に対する銀微粒子を用いた通電焼結接合法2013

    • Author(s)
      鈴木 裕一郎
    • Journal Title

      第19回エレクトロニクスにおけるマイクロ接合・実装技術シンポジウム(Mate2013)論文集

      Volume: 19巻 Pages: 189-194

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interfacial Bonding Behavior between Silver Nanoparticles and Gold Substrate Using Molecular Dynamics Simulation2012

    • Author(s)
      T. Ogura, M. Nishimura, H. Tatsumi, W. Takahara and A. Hirose
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 53 Issue: 12 Pages: 2085-2090

    • DOI

      10.2320/matertrans.MB201201

    • NAID

      130004454913

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Au and Pd Additions on Joint Strength, "Electrical Resistivity and Ion-migration Tolerance in Low-temperature Sintering Bonding using Ag_2O Paste2012

    • Author(s)
      T. Ito, T. Ogura and A. Hirose
    • Journal Title

      Journal of Electronic Materials

      Volume: Vol. 41 Issue: 9 Pages: 2573-2579

    • DOI

      10.1007/s11664-012-2167-6

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高温使用環境に適合した鉛フリー接合技術2012

    • Author(s)
      廣瀬明夫
    • Journal Title

      電子情報通信学会論文誌 C

      Volume: Vol. J95-C Pages: 271-278

    • NAID

      110009543923

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 高温使用環境に適合した鉛フリー接合技術2012

    • Author(s)
      廣瀬 明夫
    • Journal Title

      電子情報通信学会論文誌C

      Volume: 95-C巻 Pages: 245-253

    • NAID

      110009543923

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高温鉛基はんだ代替技術の動向(2)ナノテクノロジーを利用した低温焼結接合2012

    • Author(s)
      廣瀬 明夫
    • Journal Title

      金属

      Volume: 82巻 Pages: 1084-1090

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Evaluation of interfacial bonding utilizing Ag2O-derived silver nanoparticles using TEM observation and molecular dynamics simulation2011

    • Author(s)
      T.Ogura
    • Journal Title

      The Open Surface Science Journal

      Volume: Vol.3 Pages: 55-59

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low Temperature Sintering Bonding Process Using Ag Nanoparticles Derived from Ag2O for Packaging of High-temperature Electronics2011

    • Author(s)
      A.Hirose
    • Journal Title

      Materials Science Forum

      Volume: Vol.706-709 Pages: 2962-2967

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] マイクロ接合実装品「技術トピックス編」-銀ナノ粒子および酸化銀を用いた低温接合-2011

    • Author(s)
      廣瀬明夫
    • Journal Title

      溶接学会誌

      Volume: Vol.80 Pages: 702-708

    • Related Report
      2011 Annual Research Report
  • [Presentation] Metal-to-metal bonding process using Ag nanoparticles derived from reduction of Ag_2O by polyethylene glycols2013

    • Author(s)
      A. Hirose, T. Ogura and S. Takata
    • Organizer
      International Conference on Processing & Manufacturing of Advanced Materials (THERMEC' 2013)
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Metal-to-metal bonding process using Ag nanoparticles derived from reduction of Ag2O by polyethylene glycols2013

    • Author(s)
      Akio Hirose, Tomo Ogura, Shinya Takata
    • Organizer
      International Conference on Processing & Manufacturing of Advanced Materials (THERMEC’2013)
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Effect of Silver Fineparticles on the Resistance Spot Welding of Pure Copper2013

    • Author(s)
      Yuichiro Suzuki, Tomo Ogura, Akio Hirose
    • Organizer
      Materials Science & Technology 2013 (MS&T13)
    • Place of Presentation
      Montreal, Quebec, Canada
    • Related Report
      2013 Annual Research Report
  • [Presentation] Metal-to-metal bonding using silver nanoparticle paste derived from silver oxide2013

    • Author(s)
      Tomo Ogura,Shinya Takata, Akio Hirose
    • Organizer
      66th Annual Assembly of International Institute of Welding (IIW2013)
    • Place of Presentation
      Essen, Germany
    • Related Report
      2013 Annual Research Report
  • [Presentation] Low Temperature Sintering Bonding of Metals Using Ag Nanoparticles Derived from Ag2O2013

    • Author(s)
      Akio Hirose, Shinya Takata, Tomo Ogura
    • Organizer
      8th Pacific Rim International Congress on Advanced Materials and Processing (PRICM-8)
    • Place of Presentation
      Waikoloa, Hawaii, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銀ナノ粒子および酸化銀微粒子を用いた純銅の抵抗スポット溶接2013

    • Author(s)
      鈴木裕一郎、小椋智、廣瀬 明夫
    • Organizer
      平成25年度溶接学会秋季全国大会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅に対する銀微粒子を用いた通電焼結接合法2013

    • Author(s)
      鈴木 裕一郎
    • Organizer
      第19回エレクトロニクスにおけるマイクロ接合・実装技術シンポジウム(Mate2013)
    • Place of Presentation
      パシフィコ横浜、横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 酸化銀ペーストを用いた接合における接合界面組織解析2013

    • Author(s)
      高田 慎也
    • Organizer
      第19回エレクトロニクスにおけるマイクロ接合・実装技術シンポジウム(Mate2013)
    • Place of Presentation
      パシフィコ横浜、横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 酸化銀ペーストを用いた接合において還元溶剤が銅ニッケルおよびアルミニウムの接合性に及ぼす影響2012

    • Author(s)
      高田慎也
    • Organizer
      第18回エレクトロニクスにおけるマイクロ接合・実装技術シンポジウム(Mate2012)
    • Place of Presentation
      横浜,日本
    • Year and Date
      2012-02-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Joining Technology through Sintering of Nano Scale Particles2012

    • Author(s)
      A. Hirose
    • Organizer
      International Conference on Nanojoining and Microjoining (NMJ 2012)
    • Place of Presentation
      Tsinghua University, Beijing, China
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Low-temperature joining technique for electronics packaging by sintering of nano-scale Ag particles2012

    • Author(s)
      A. Hirose
    • Organizer
      International welding/Joining Conference (IWJC2012)
    • Place of Presentation
      Jeju, KOREA
    • Related Report
      2013 Final Research Report
  • [Presentation] Interfacial Microstructure in Aluminum and Nickel Bonding Using Silver Nanoparticles Derived from Silver Oxide2012

    • Author(s)
      S. Takata
    • Organizer
      International Conference on Nanojoining and Microjoining (NMJ 2012)
    • Place of Presentation
      Beijing, China
    • Related Report
      2012 Annual Research Report
  • [Presentation] Low Energy Resistance Spot Welding Using Silver Nanoparticle2012

    • Author(s)
      Y. Suzuki
    • Organizer
      International Conference on Nanojoining and Microjoining (NMJ 2012)
    • Place of Presentation
      Beijing, China
    • Related Report
      2012 Annual Research Report
  • [Presentation] Bondability of Joints Using Ag2O and CuO Combined Paste for Electronics Packaging2012

    • Author(s)
      T. Ogura
    • Organizer
      International Conference on Nanojoining and Microjoining (NMJ 2012)
    • Place of Presentation
      Beijing, China
    • Related Report
      2012 Annual Research Report
  • [Presentation] Joining Technology through Sintering of Nano Scale Particles2012

    • Author(s)
      A. Hirose
    • Organizer
      International Conference on Nanojoining and Microjoining (NMJ 2012)
    • Place of Presentation
      Beijing, China
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Femtosecond Laser Direct Joining of Cu with Polyethylene Terephthalate2012

    • Author(s)
      T. Sano
    • Organizer
      International Conference on Nanojoining and Microjoining (NMJ 2012)
    • Place of Presentation
      Beijing, China
    • Related Report
      2012 Annual Research Report
  • [Presentation] Selection of Particle Size and Solvent for Lower Applied Pressure in Metal-to-Metal Bonding using Silver Nanoparticle Paste2012

    • Author(s)
      T. Ogura
    • Organizer
      The International Symposium on Visualization in Joining & Welding Science through Advanced Measurements and Simulation (Visual-JW)
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Application of Silver Nanoparticle for Low-energy Resistance Spot Welding2012

    • Author(s)
      Y. Suzuki
    • Organizer
      The International Symposium on Visualization in Joining & Welding Science through Advanced Measurements and Simulation (Visual-JW)
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Interfacial Microstructure in Aluminum and Copper Bonding using Silver Nanoparticles Derived from Silver Oxide2012

    • Author(s)
      S. Takata
    • Organizer
      The International Symposium on Visualization in Joining & Welding Science through Advanced Measurements and Simulation (Visual-JW)
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Interfacial Microstructure in Aluminum Bonding Using Silver Nanoparticles Derived from Silver Oxide2012

    • Author(s)
      S. Takata
    • Organizer
      Materials Science & Technology 2012 Conference & Exhibition (MS&T)
    • Place of Presentation
      Pittsburgh, Pennsylvania, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Low-Temperature Bonding using Ag2O Paste Containing Polyethylene Glycols2012

    • Author(s)
      T. Ogura
    • Organizer
      65th Annual Assembly & International Conference on the International Institute of Welding
    • Place of Presentation
      Denver, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Low-temperature joining technique for electronics packaging by sintering of nano-scale Ag particles2012

    • Author(s)
      A. Hirose
    • Organizer
      International Welding/Joining Conference-Korea 2012 (IWJC-Korea 2012)
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 酸化銀ペーストを用いた焼結銀接合部の組織と特性評価2012

    • Author(s)
      高田 慎也
    • Organizer
      平成24年度秋季大会,(社)溶接学会
    • Place of Presentation
      奈良県文化会館、奈良
    • Related Report
      2012 Annual Research Report
  • [Presentation] 銀ナノ粒子による抵抗スポット溶接の低エネルギー化2012

    • Author(s)
      鈴木 裕一郎
    • Organizer
      平成24年度秋季大会,(社)溶接学会
    • Place of Presentation
      奈良県文化会館、奈良
    • Related Report
      2012 Annual Research Report
  • [Presentation] 酸化銀ペーストを用いた焼結銀接合部の組織と特性評価2012

    • Author(s)
      高田 慎也
    • Organizer
      平成24年度春季大会,(社)溶接学会
    • Place of Presentation
      アジア太平洋トレードセンター、大阪
    • Related Report
      2012 Annual Research Report
  • [Presentation] Improvement of bondability in Cu/Cu joint using Ag_2O paste by controlling reducing solvent2011

    • Author(s)
      S.Takata
    • Organizer
      International Symposium on Material Science-Eco-materials and Eco-innovation for Global Sustain ability (Eco-Mate 2011)
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2011-11-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Evaluation of Bondability and Reliability in Metal-to-Metal Bonding Using Ag_2O Pastes with Polyethylene Glycols2011

    • Author(s)
      T.Yagishita
    • Organizer
      Materials Science & Technology 2011 Conference (MS&T11)
    • Place of Presentation
      Colombus, USA
    • Year and Date
      2011-10-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] 酸化銀ペーストを用いた接合法におけるエチレングリコール系溶剤の影響2011

    • Author(s)
      柳下朋大
    • Organizer
      平成23年度溶接学会秋季大会
    • Place of Presentation
      伊勢,日本
    • Year and Date
      2011-09-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] 酸化銀ペーストを用いたCu/Cu継手の接合性に及ぼす還元溶剤の影響2011

    • Author(s)
      高田慎也
    • Organizer
      平成23年度溶接学会秋季大会
    • Place of Presentation
      伊勢,日本
    • Year and Date
      2011-09-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] Low Temperature Sintering Bonding Process Using Ag Nanoparticles Derived from Ag_2O for Packaging of High-temperature Electronics2011

    • Author(s)
      A.Hirose
    • Organizer
      International Conference on Processing & Manufacturing of Advanced Materials (Thermec '2011)
    • Place of Presentation
      Quebec, Canada(招待講演)
    • Year and Date
      2011-08-03
    • Related Report
      2011 Annual Research Report
  • [Presentation] Metal-to-Metal Bonding Using Ag Nanoparticles Derived from Ag_2O Particles for Electronics Assembly2011

    • Author(s)
      A.Hirose
    • Organizer
      64th Annual Assembly of International Institute of Welding (IIW)
    • Place of Presentation
      Chennai, India
    • Year and Date
      2011-07-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Selection of particle size and solvent for reducing applied pressure in metal-to-metal bonding using silver nanoparticle paste2011

    • Author(s)
      T.Ogura
    • Organizer
      64th Annual Assembly of International Institute of Welding (IIW)
    • Place of Presentation
      Chennai, India
    • Year and Date
      2011-07-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Effects of Au and Pd Addition on Mechanical Property and Ion-migration Tolerance in Low Temperature Sintering Bonding Using Ag_2O Paste2011

    • Author(s)
      A.Hirose
    • Organizer
      Nanotech Conference & Expo 2011
    • Place of Presentation
      Boston, USA
    • Year and Date
      2011-06-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] Bondability of Low Tenperature Sinter Bonding Process Using Ag_2O Pastes with Polyethlene Glycols2011

    • Author(s)
      T.Yagishita
    • Organizer
      International Conference on Electronics Packaging 2011 (ICEP2011)
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2011-04-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] Low Temperature Sintering Bonding Process Using Ag Nanoparticles Derived from Ag_2O for Packaging of High-temperature Electronics2011

    • Author(s)
      A. Hirose, N. Takeda, H. Tatsumi, Y. Akada, T. Ogura, E. Ide and T. Morida
    • Organizer
      International Conference on Processing & Manufacturing of Advanced Materials (THERMEC'2011)
    • Place of Presentation
      Quebec, Canada
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Effects of Particle Size and Solvent on Bondability of Metal-to-Metal Bonding Using Silver Nanoparticle Paste2011

    • Author(s)
      A. Hirose, T. Ogura, Y. Konaka, E. Ide and T. Morita
    • Organizer
      Materials Science & Technology 2011 (MS&T11)
    • Place of Presentation
      Columbus, Ohio, USA
    • Related Report
      2013 Final Research Report
    • Invited
  • [Book] 精密加工と微細構造の形成技術2013

    • Author(s)
      廣瀬明夫, 他
    • Publisher
      技術情報協会
    • Related Report
      2013 Final Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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