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Development of Simultaneous Recovery Process of Lithium and Boron from Geothermal Water

Research Project

Project/Area Number 23360344
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionThe University of Kitakyushu

Principal Investigator

YOSHIZUKA Kazuharu  北九州市立大学, 国際環境工学部, 教授 (70191567)

Co-Investigator(Kenkyū-buntansha) NISHIHAMA Syouhei  北九州市立大学, 国際環境工学部, 准教授 (00347668)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2013: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Fiscal Year 2011: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Keywords反応・分離工学 / 資源開発工学 / 吸着・イオン交換 / レアメタル / 地熱水
Research Abstract

For developing highly-selective adsorbents for lithium and boron together with simultaneous recovery process of the rare metals from geothermal water, we have investigated (1) the development of inorganic adsorbents having ion-size recognition and their granulation method, (2) the elucidation of mechanisms of adsorption equilibria and kinetics of lithium and boron, (3) fundamental experiments of recovery of lithium and boron from artificial geothermal water using adsorption columns, (4) fundamental experiments of simultaneous recovery of lithium and boron from geothermal water, and (5) practical experiments of simultaneous recovery process of lithium and boron from geothermal water.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (51 results)

All 2014 2013 2012 2011 Other

All Journal Article (15 results) (of which Peer Reviewed: 11 results) Presentation (25 results) (of which Invited: 6 results) Book (2 results) Remarks (9 results)

  • [Journal Article] Thermal-Swing Adsorption of Europium(III) with Poly(N-isopropylacrylamide) Combined with Acidic Extractant2014

    • Author(s)
      Nishihama, S., Matsunaga, S., Takayama, S., Ookubo, T., Yoshizuka, K., Fujigaya, T., Nakashima, N.
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 21(1) Pages: 37-45

    • NAID

      130005056979

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Recovery of Valuable Metals from Spent Li-ion Batteries Using Solvent-Impregnated Resins2013

    • Author(s)
      Guo, F., Nishihama, S., Yoshizuka, K.
    • Journal Title

      Environmental Technology

      Volume: 34(10) Issue: 10 Pages: 1307-1317

    • DOI

      10.1080/09593330.2012.746734

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Separation of Lanthanum and Cerium Using a Coated Solvent-Impregnated Resin2013

    • Author(s)
      Nishihama, S., Kohata, K., Yoshizuka, K.
    • Journal Title

      Separation and Purification Technology

      Volume: 118 Pages: 511-518

    • DOI

      10.1016/j.seppur.2013.07.047

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Separation and Recovery of Nickel from Waste Electroless Nickel-Phosphorous Plating Solution2013

    • Author(s)
      Ookubo, T., Nishihama, S., Yoshizuka, K.
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 20 Pages: 149-157

    • NAID

      130005056974

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Separation of Tetramethyl Ammonium Hydroxide Using an MFI-Type Zeolite-Coated membrane2013

    • Author(s)
      Nishihama, S., Tsutsumi, Y., Yoshizuka, K.
    • Journal Title

      Separation and Purification Technology

      Volume: 120 Pages: 129-133

    • DOI

      10.1016/j.seppur.2013.09.040

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Practical Recovery of Lithium from Seawater2012

    • Author(s)
      吉塚和治
    • Journal Title

      Journal of Ion Exchange

      Volume: 23 Issue: 3 Pages: 59-65

    • DOI

      10.5182/jaie.23.59

    • NAID

      130002138545

    • ISSN
      0915-860X, 1884-3360
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Journal Article] 海水からのリチウム回収の実際2012

    • Author(s)
      吉塚和治
    • Journal Title

      ペトロテック

      Volume: 35(9) Pages: 653-659

    • NAID

      10031141455

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Journal Article] Adsorption of Boron Using Glucamine-Based Chelate Adsorbents2012

    • Author(s)
      Nishihama, S., Sumiyoshi, Y., Ookubo, T., Yoshizuka, K.
    • Journal Title

      Desalination

      Volume: 310 Pages: 81-86

    • DOI

      10.1016/j.desal.2012.06.021

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Separation and Recovery of Lithium from Geothermal Water by Sequential Adsorption Process with λ-MnO_2 and TiO_22012

    • Author(s)
      Park, J. E., Sato, H., Nishihama, S., Yoshizuka, K.
    • Journal Title

      Ion Exchange Letters

      Volume: 5 Pages: 1-5

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lithium Recovery from Geothermal Water by Combined Adsorption Methods2012

    • Author(s)
      Park, J. E., Sato, H., Nishihama, S., Yoshizuka, K.
    • Journal Title

      Solvent Extraction and Ion Exchange

      Volume: 30(4) Issue: 4 Pages: 398-404

    • DOI

      10.1080/07366299.2012.687165

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 海水からのリチウム回収2011

    • Author(s)
      吉塚和治, 近藤正聡
    • Journal Title

      プラズマ・核融合学会誌

      Volume: 87(12) Pages: 795-800

    • NAID

      110008898422

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Journal Article] 海水やかん水からのリチウム回収技術-アンデスの塩湖からのリチウム回収への挑戦2011

    • Author(s)
      吉塚和治
    • Journal Title

      化学と工業

      Volume: 64(10) Pages: 771-773

    • NAID

      10029684132

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Journal Article] Removal of Boron and Arsenic from Geothermal Water in Kyushu Island, Japan by Using Selective Ion Exchange Resins2011

    • Author(s)
      Koseoglu, P., Yoshizuka, K., Nishihama, S., Yuksel, U., Kabay, N.
    • Journal Title

      Solvent Extraction and Ion Exchange

      Volume: 29 Issue: 3 Pages: 440-457

    • DOI

      10.1080/07366299.2011.573448

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Recovery Process of Lithium from Seawater Using Integrated Ion Exchange Methods2011

    • Author(s)
      Nishihama, S., Onishi, K., Yoshizuka, K.
    • Journal Title

      Solvent Extraction and Ion Exchange

      Volume: 29 Issue: 3 Pages: 421-431

    • DOI

      10.1080/07366299.2011.573435

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption of Europium (III) with Solvent Impregnated Kapok Fiber Containing2-Ethylhexyl Phosphonic Acid Mono-2-Ethylhexyl Ester2011

    • Author(s)
      Higa, N.; Nishihama, S.; Yoshizuka, K.
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 18 Pages: 187-192

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] ボリビアのアルティプラーノ高原にあるウユニ塩湖からのリチウム回収2013

    • Author(s)
      吉塚和治
    • Organizer
      2013 化学工学会九州セミナー
    • Place of Presentation
      市民会館崇城大学ホール
    • Year and Date
      2013-11-10
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Separation and Recovery of Boron from Water Using Ion Exchange Methods2013

    • Author(s)
      Shao, S., Nishihama, S., Yoshizuka, K.
    • Organizer
      The 12th International Symposium on East Asian Resources Recycling Technology "EARTH 2013"
    • Place of Presentation
      張家界, 中国
    • Year and Date
      2013-11-04
    • Related Report
      2013 Final Research Report
  • [Presentation] 高分子モノリスを担体とする吸着剤の調製とイオン交換特性2013

    • Author(s)
      吉塚和治, 柴田加奈子, 高山誠太郎,西浜章平
    • Organizer
      第29回日本イオン交換研究発表会
    • Place of Presentation
      東北大学
    • Year and Date
      2013-10-18
    • Related Report
      2013 Final Research Report
  • [Presentation] λ -MnO_2 担持モノリス吸着剤によるリチウムの吸着2013

    • Author(s)
      高山誠太郎, 西浜章平, 吉塚和治
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2013-07-06
    • Related Report
      2013 Final Research Report
  • [Presentation] Separation and Recovery of Lithium with λ-MnO_2 -Supported Polymeric Monolith Adsorbent2013

    • Author(s)
      Takayama, S., Nishihama, S., Yoshizuka, K.
    • Organizer
      2nd International Conference of Methods and Materials for Separation Processes "Separation Science - Theory and Practice 2013"
    • Place of Presentation
      SWIERADOW ZDRÓJ, ポーランド
    • Year and Date
      2013-06-10
    • Related Report
      2013 Final Research Report
  • [Presentation] ボリビア・ウユニ塩湖のリチウム開発に挑む2012

    • Author(s)
      吉塚和治
    • Organizer
      第26回福岡県高等学校化学クラブ研究発表会
    • Place of Presentation
      北九州市立大学
    • Year and Date
      2012-12-01
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Invited
  • [Presentation] 塩湖かん水からのリチウム回収技術~アンデス・ウユニ塩湖からのリチウム回収プロジェクト~2012

    • Author(s)
      吉塚和治
    • Organizer
      2012年日本化学会西日本大会
    • Place of Presentation
      佐賀大学
    • Year and Date
      2012-11-11
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] Recovery of Lithium from Geothermal Water by Ion Exchange-Membrane Filtration Hybrid Method2012

    • Author(s)
      Kabay, N., Ilarslan, S. G., Arda, M., Yuksel, U., Yoshizuka, K.
    • Organizer
      IEX 2012 : The International Ion Exchange Conference
    • Place of Presentation
      University of Cambridge, イギリス
    • Year and Date
      2012-09-20
    • Related Report
      2013 Final Research Report
  • [Presentation] かん水からのリチウム回収技術~アンデス・ウユニ塩湖からのリチウム回収プロジェクト~2012

    • Author(s)
      吉塚和治
    • Organizer
      第32 期新工業材料ゼミナール(第10回)
    • Place of Presentation
      京都リサーチパーク
    • Year and Date
      2012-07-18
    • Related Report
      2013 Final Research Report
  • [Presentation] かん水からのリチウム回収技術~アンデス・ウユニ塩湖からのリチウム回収プロジェクト~2012

    • Author(s)
      吉塚和治
    • Organizer
      第32期新工業材料ゼミナール(第10回)
    • Place of Presentation
      京都リサーチパーク
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Recovery of lithium from geothermal water by ion exchange-membrane filtration hybrid method2012

    • Author(s)
      Kabay, N., Ilarslan, S. G., Arda, M., Yuksel, U.
    • Organizer
      IEX 2012: The International Ion Exchange Conference
    • Place of Presentation
      University of Cambridge, UK
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synergistic Solvent Impregnated Resin for Selective Recovery of Lithium Ion2011

    • Author(s)
      Yoshizuka, K., Onishi, K. Nakamura, T., Nishihama, S.
    • Organizer
      19th International Solvent Extraction Conference
    • Place of Presentation
      Sheraton Santiago Hotel & Convention Center,チリ
    • Year and Date
      2011-10-06
    • Related Report
      2013 Final Research Report
  • [Presentation] Synergistic Solvent Impregnated Resin for Selective Recovery of Lithium Ion2011

    • Author(s)
      Yoshizuka, K.; Onishi, K.; Nakamura, T.; Nishihama, S.
    • Organizer
      19th International Solvent Extraction Conference
    • Place of Presentation
      Sheraton Santiago Hotel & Convention Center. Chile
    • Year and Date
      2011-10-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] Solvent Impregnated Kapok Fiber for Separation of Rare Earth Metals2011

    • Author(s)
      Nishihama, S.; Higa, N.; Yoshizuka, K.
    • Organizer
      19th International Solvent Extraction Conference
    • Place of Presentation
      Sheraton Santiago Hotel & Convention Center.Chile
    • Year and Date
      2011-10-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] 海水からのリチウム回収の現状と今後の展望2011

    • Author(s)
      吉塚和治
    • Organizer
      レーザー核融合技術振興会/IFE フォーラム
    • Place of Presentation
      千里ライフサイエンスセンター
    • Year and Date
      2011-06-01
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 海水からのリチウム回収の現状と今後の展望2011

    • Author(s)
      吉塚和治
    • Organizer
      レーザー核融合技術振興会/IFEフォーラム
    • Place of Presentation
      千里ライフサイエンスセンター(招待講演)
    • Year and Date
      2011-06-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Analytical Survey of Spatial and Vertical Distribution of Inorganic Components in Deep Ocean Water2011

    • Author(s)
      Mimori, A., Yoshizuka, K., Nishihama, S., Nakaoka, T., Nishida, T., Ichinose, J., Ueda, T.
    • Organizer
      IUPAC International Congress on Analytical, Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center
    • Year and Date
      2011-05-25
    • Related Report
      2013 Final Research Report
  • [Presentation] Analytical Survey of Spatial and Vertical Distribution of Inorganic Components in Deep Ocean Water2011

    • Author(s)
      Mimori, A.; Yoshizuka, K.; Nishihama, S., Nakaoka, T.; Nishida, T., Ichinose, J.; Ueda, T.
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Separation and Recovery of Lithium with λ-MnO2-Supported Polymeric Monolith Adsorbent

    • Author(s)
      Takayama, S., Nishihama, S., Yoshizuka, K.
    • Organizer
      2nd International Conference of Methods and Materials for Separation Processes "Separation Science; Theory and Practice 2013"
    • Place of Presentation
      SWIERADOW ZDROJ、ポーランド
    • Related Report
      2013 Annual Research Report
  • [Presentation] Arsenic Removal from Groundwater by Several Adsorbents

    • Author(s)
      Yoshizuka, K., Park, J., Shibata, K., Nishihama, S.
    • Organizer
      2nd International Conference of Methods and Materials for Separation Processes "Separation Science; Theory and Practice 2013"
    • Place of Presentation
      SWIERADOW ZDROJ、ポーランド
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] λ-MnO2担持モノリス吸着剤によるリチウムの吸着

    • Author(s)
      高山誠太郎、西浜章平、吉塚和治
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] 抽出剤を固定化した感温性高分子を利用した環境調和型吸着システムの開発

    • Author(s)
      西浜章平、松永理美、高山誠太郎、大澤佳代、大久保祝絵、吉塚和治
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高分子モノリスを担体とする吸着剤の調製とイオン交換特性

    • Author(s)
      吉塚和治、柴田加奈子、高山誠太郎、西浜章平
    • Organizer
      第29回日本イオン交換研究発表会
    • Place of Presentation
      東北大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Separation and Recovery of Boron from Water Using Ion Exchange Methods

    • Author(s)
      Shao, S., Nishihama, S., Yoshizuka, K.
    • Organizer
      The 12th International Symposium on East Asian Resources Recycling Technology “EARTH 2013”
    • Place of Presentation
      張家界、中国
    • Related Report
      2013 Annual Research Report
  • [Presentation] ボリビアのアルティプラーノ高原にあるウユニ塩湖からのリチウム回収

    • Author(s)
      吉塚和治
    • Organizer
      2013化学工学会九州セミナー
    • Place of Presentation
      市民会館崇城大学ホール
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] "Boron Separation Processes", Chapter 5: Separation and Recovery of Boron from Various Resources Using Chelate Adsorbents2014

    • Author(s)
      Yoshizuka, K., Nishihama, S.
    • Publisher
      Elsevier
    • Related Report
      2013 Final Research Report
  • [Book] Boron Separation Processes”, Chapter 5: Separation and recovery of boron from various resources using chelate adsorbents2014

    • Author(s)
      Yoshizuka, K., Nishihama, S.
    • Total Pages
      250
    • Publisher
      Elsevier
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.kitakyu-u.ac.jp/env/subject/d-energy/Kazuharu_Yoshizuka/index.html

    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://chemeng.env.kitakyu-u.ac.jp/jp/index_j.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 北九州市立大学国際環境工学部/エネルギー循環化学科/吉塚和治

    • URL

      http://www.kitakyu-u.ac.jp/env/subject/d-energy/Kazuharu_Yoshizuka/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 北九州市立大学国際環境工学部分離工学研究室

    • URL

      http://chemeng.env.kitakyu-u.ac.jp/jp/index_j.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 北九州学術研究都市研究者情報検索システム/吉塚 和治/北九州市立大学国際環境工学部

    • URL

      http://fais.ksrp.or.jp/05kenkyusha/srchresult.asp?ID=k-yoshizuka01

    • Related Report
      2013 Annual Research Report
  • [Remarks] 北九州市立大学国際環境工学部 エネルギー循環化学科 教員紹介 吉塚 和治

    • URL

      http://www.kitakyu-u.ac.jp/env/subject/d-energy/Kazuharu_Yoshizuka/index.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] 北九州市立大学国際環境工学部 分離工学研究室

    • URL

      http://chemeng.env.kitakyu-u.ac.jp/jp/index_j.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://chemeng.env.kitakyu-u.ac.jp/jp/index_j.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://chemeng.env.kitakyu-u.ac.jp/~yoshizuka/

    • Related Report
      2011 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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