Analysis of micro-catakytic reactor by means of micro-spectroscopy

• Project/Area Number: 23360346
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Reaction engineering/Process system
• Research Institution: Nagoya University
• Principal Investigator: TAGAWA Tomohiko 名古屋大学, 工学(系)研究科(研究院), 教授 (10171571)
• Co-Investigator(Kenkyū-buntansha): YAMADA Hiroshi 名古屋大学, 大学院工学研究科, 助教 (70293644)
• Project Period (FY): 2011-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000); Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000); Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2011: ¥13,260,000 (Direct Cost: ¥10,200,000、Indirect Cost: ¥3,060,000)
• Keywords: 化学工学 / 触媒・化学プロセス / マイクロ反応器 / 反応・分離工学 / 表面界面物性 / 顕微赤外分光 / 顕微紫外分光 / 流動シミュレーション / 顕微赤外分光分析 / 顕微紫外分光分析 / 触媒反応工学 / 反応分離工学 / 顕微赤外分光法 / 顕微紫外分光法 / in situ分析

Outline of Final Research Achievements

For the progress of reaction engineering of micro-catalytic process, in situ analysis of reaction was conducted by means of micro-spectroscopic method. Micro-infrared spectroscopy and micro-ultraviolet spectroscopy were used to analyze the catalytic reaction in micro reactors.
International collaboration study with Thailand was conducted to simulate organic-aqueous two phase parallel flow in microreactor with guideline structure. Experimental study was also conducted to discuss the reaction path and active site on the catalyst during dehydrogenation of propane and cyclohexane by means of micro-infrared spectroscopy and micro-ultraviolet spectroscopy.

Research Products

• [Journal Article] Effect of surface modification on parallelflow in microchannel with guideline structure (2013)
  • Author(s): C. Kositanont
  • Journal Title: Chemiccal Engineering Journal Volume: 215 Pages: 404-410
  • DOI: 10.1016/j.cej.2012.10.047
  • Peer Reviewed
• [Journal Article] Evaluation of catalyst prepared in microchannel with in situ FT-IR microscopy (2011)
  • Author(s): Tagawa, Isobe, Tanaka, Yamada
  • Journal Title: Chemical Engineering Journal Volume: 167 Pages: 427-430
  • Peer Reviewed
• [Journal Article] Flow pattern of liquid multiphase flow in microreactors with different guideline sturucftures (2011)
  • Author(s): Kositanont, Putivisutisar, Piyasan, Suttichai, Yamada
  • Journal Title: Journal of Chemical Engineering of Japan Volume: 44 Pages: 649-652
  • Peer Reviewed
• [Journal Article] Process intensification of dehydrogenation reactions by pressure swing reactor (2011)
  • Author(s): T.Tagawa
  • Journal Title: Journal of Japan Petroleum Institute Volume: 54 Pages: 310-319
  • NAID: 10030180346
  • Peer Reviewed
• [Presentation] シリコンマイクロ触媒反応器の反応特性に対する担持触媒調整法の影響 (2015)
  • Author(s): 山崎拓也 山田博史 田川智彦
  • Organizer: 化学工学会80年会
  • Place of Presentation: 東京
  • Year and Date: 2015-03-19 – 2015-03-21
• [Presentation] Liquid-Liquid-Liquid Three Phase Parallel Flow Microchannel Reactor Using Phase Transfer Catalyst (2014)
  • Author(s): T. Tagawa, T. Sengoku, H. Yamada
  • Organizer: CAMURE-ISMR 2014
  • Place of Presentation: リヨン
  • Year and Date: 2014-12-07 – 2014-12-10
• [Presentation] 顕微赤外分光法を用いたマイクロ触媒反応器での環状炭化水素の脱水素反応の評価 (2014)
  • Author(s): 林 凌土、山田博史 田川智彦
  • Organizer: 化学工学会46秋季大会
  • Place of Presentation: 福岡
  • Year and Date: 2014-09-17 – 2014-09-19
• [Presentation] Infuluence of Flow Pattern on Monolithic Reactor for Methanol Steam Reforming Reaction Coupled with Methane Combustion (2014)
  • Author(s): T. Jiwanuruk, P. Ponpesh, S. Putivisutisak, T. Tagawa, C. Fukuhara, S. Assabumrungrat
  • Organizer: ISCRE23
  • Place of Presentation: バンコク
  • Year and Date: 2014-09-07 – 2014-09-10
• [Presentation] Reaction Engineering of Microchannel Catalytic Reactors for Green Process (2014)
  • Author(s): Tomohiko Tagawa
  • Organizer: ICPEAM2014
  • Place of Presentation: クアラルンプール
  • Year and Date: 2014-06-03 – 2014-06-05
  • Invited
• [Presentation] マイクロチャンネルに坦持した白金触媒のinsitu紫外分光法による評価 (2014)
  • Author(s): L.Y.Fuan, 山田博史、田川智彦
  • Organizer: 化学工学会79回年会
  • Place of Presentation: 岐阜
• [Presentation] 液多相平行流を形成するマイクロ触媒反応器の特性解析 (2014)
  • Author(s): 千石雄大, 山田博史、田川智彦
  • Organizer: 化学工学会79回年会
  • Place of Presentation: 岐阜
• [Presentation] Use of micro-spectroscopy for in situ characterization of catalyst on silicon microchannel wall (2013)
  • Author(s): T.Tagawa, L.Y.Fuan, K.Ohta and H. Yamada
  • Organizer: 14th Japan-Korea Symposium on Catalysis
  • Place of Presentation: Nagoya
• [Presentation] マイクロリアクタを用いた相間移動触媒による安息香酸フェニル生成反応 (2013)
  • Author(s): 千石雄大, 山田博史、田川智彦
  • Organizer: 化学工学会45回秋季大会
  • Place of Presentation: 岡山
• [Presentation] マイクロリアクター器壁に担持した白金触媒の顕微赤外分光法による評価 (2013)
  • Author(s): 太田 一輝(田川智彦）
  • Organizer: 化学工学会第７８年会
  • Place of Presentation: 大阪大学
• [Presentation] Use of Microchannel Reactor for Multiphase Reactions (2013)
  • Author(s): T.Tagawa
  • Organizer: COE in Catalysis and Catalytic Reaction Engineering
  • Place of Presentation: THailand
  • Invited
• [Presentation] Evaluation of microcatalytic reactor with in situ UV microscopy (2012)
  • Author(s): T.Tagawa
  • Organizer: 19th Regional Symposium on Chemical Engineering
  • Place of Presentation: Indonesia
• [Presentation] Effect of surface modification on parallel flow in microchannel with guideline structure (2012)
  • Author(s): C.Kositanont, (T.Tagawa, S. Assabumrungrat)
  • Organizer: 22nd International Symposium on Chemical Reaction Engineering
  • Place of Presentation: Netherlands
• [Presentation] 顕微紫外分光装置を用いたマイクロチャネル触媒表面における吸着種の検討 (2012)
  • Author(s): Lee Yi Fuan (田川智彦）
  • Organizer: 化学工学会第４４回秋季大会
  • Place of Presentation: 東北大学
• [Presentation] Organic-aqueous two phase flow reaction using microreactors with guideli (2011)
  • Author(s): Tagawa, Yamada, Kositanont, Putivisutisar, Suttichai
  • Organizer: 3rd Frontiers in organic synthesis technology conference
  • Place of Presentation: ブダペスト(ハンガリー)
• [Remarks] 反応プロセス工学グループ
  • URL: http://www.nuce.nagoya-u.ac.jp/e1/e1.html