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Development of High Rate Capacitor by Optimizing Electrode Structure

Research Project

Project/Area Number 23360347
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionKyoto University

Principal Investigator

KAWASE Motoaki  京都大学, 工学(系)研究科(研究院), 教授 (60231271)

Co-Investigator(Kenkyū-buntansha) INOUE Gen  京都大学, 工学研究科, 助教 (40336003)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2013: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2011: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Keywords電気二重層キャパシター / 速度性能 / 構造化電極 / イオン輸送 / イオンパス / モデル / 物質移動抵抗 / 粒子間空隙 / 混合電極 / 静電容量 / キャパシター / レート特性 / モデリング / 粒子間空隙内イオン輸送 / 複合電極 / 電極構造 / 炭素材料 / イオンチャネル / 高放電電流密度
Research Abstract

At the high discharge rate, the diffusion resistance of ion in the through-plane direction of electrode greatly deteriorates the discharge rate of electrochemical double-layer capacitor (EDLC). We produced structured thick electrodes with through-plane microchannel, and investigated the effects of the structured electrodes on the discharge rate. Two types of structured electrodes with through-plane microchannel, multi-cylindrical-channel electrode (MCE) and multi-layered electrode (MLE) were prepared and the specific capacitance per weight of MCE and MLE were measured. Multi-cylindrical-channel and porous layer of MLE function as ion path. The specific capacitance of MCE and MLE was improved from that of a normal electrode in the high discharge rate region.
We also built the model taking into acount mass transfer resistance of ion passing through the pore in the particle and between the particles in order to give the design guideline of EDLC.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (10 results)

All 2014 2013 2012

All Presentation (10 results)

  • [Presentation] マクロ空隙を設けた電極構造による電気二重層キャパシターの速度性能改善2014

    • Author(s)
      河瀬 元明・平田 彩香・井上 元
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Year and Date
      2014-03-20
    • Related Report
      2013 Final Research Report
  • [Presentation] 電極構造が電気二重層キャパシターの速度性能に与える影響2014

    • Author(s)
      宮崎崇・平田彩香・河瀬元明
    • Organizer
      大阪府立大学
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2014-03-01
    • Related Report
      2013 Final Research Report
  • [Presentation] 電極構造が電気二重層キャパシターの速度性能に与える影響2014

    • Author(s)
      宮崎 崇・平田 彩香・河瀬 元明
    • Organizer
      第16回化学工学会学生発表会(堺大会)
    • Place of Presentation
      大阪府立大学 中百舌鳥キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] マクロ空隙を設けた電極構造による電気二重層キャパシターの速度性能改善2014

    • Author(s)
      河瀬 元明・平田 彩香・井上 元
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学 柳戸キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] A New Structured Electrode with Through-Plane Microchannel for Improving Rate Performance of Electrical Double Layer Capacitor2013

    • Author(s)
      Ayaka Hirata, Toshinori Okura, Akira Morimoto, Gen Inoue, Motoaki Kawase
    • Organizer
      the 9th World Congress of Chemical Engineering (WCCE9), the 15th Asian Pacific Confederation of Chemical Engineering Congress (APCChE2013)
    • Place of Presentation
      Coex, Seoul, Korea
    • Year and Date
      2013-08-22
    • Related Report
      2013 Final Research Report
  • [Presentation] A New Structured Electrode with Through-Plane Microchannel for Improving Rate Performance of Electrical Double Layer Capacitor2013

    • Author(s)
      Ayaka Hirata, Toshinori Okura, Akira Morimoto, Gen Inoue, Motoaki Kawase
    • Organizer
      the 9th World Congress of Chemical Engineering (WCCE9), the 15th Asian Pacific Confederation of Chemical Engineering Congress (APCChE2013)
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structured EDLC Electrode with Through-Plane Microchannel2012

    • Author(s)
      Toshinori Okura, Akira Morimoto, Gen Inoue, Motoaki Kawase
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME) 2012, 222nd Meeting of ECS
    • Place of Presentation
      Hawaii Convention Center and the Hilton Hawaiian Village
    • Year and Date
      2012-10-10
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] マイクロチャネルを形成した構造化電極による電気二重層キャパシタの速度性能向上2012

    • Author(s)
      大倉 才昇・守本 玲・井上 元・河瀬 元明
    • Organizer
      化学工学会 第44回秋季大会
    • Place of Presentation
      東北大学
    • Year and Date
      2012-09-21
    • Related Report
      2013 Final Research Report
  • [Presentation] 電極構造と電気二重層キャパシターの充放電特性の関係2012

    • Author(s)
      守本 玲・大倉 才昇・井上 元・河瀬 元明
    • Organizer
      第14回化学工学会学生発表会
    • Place of Presentation
      山口県・宇部工業高等専門学校
    • Year and Date
      2012-03-03
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] マイクロチャネルを形成した構造化電極による電気二重層キャパシタの速度性能向上2012

    • Author(s)
      大倉才昇
    • Organizer
      化学工学会 第44回秋季大会
    • Place of Presentation
      東北大学
    • Related Report
      2012 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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