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Preparation and characterization of intermetallic compound nanoparticles to create novel catalysts having high performance.

Research Project

Project/Area Number 23360353
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional solid state chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

KOMATSU Takayuki  東京工業大学, 理工学研究科, 教授 (40186797)

Co-Investigator(Renkei-kenkyūsha) FURUKAWA Shinya  東京工業大学, 理工学研究科, 助教 (10634983)
OZAWA Ken-ichi  東京工業大学, 理工学研究科, 助教 (00282822)
MURAMATSU Atsushi  東北大学, 多元物質科学研究所, 教授 (40210059)
Project Period (FY) 2011-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2012: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywords金属間化合物 / 触媒 / 合金 / 水素化 / 脱水素 / 白金 / パラジウム / ロジウム / ナノ粒子 / 選択水素化 / PROX反応 / 酸化脱水素 / ブタジエン / アミン / アルミナ / 触媒・化学プロセス / 水素分子 / アンモニア合成 / 水素移動反応 / 選択的水素化 / d軌道中心
Outline of Final Research Achievements

The purpose of this study is to reveal the ability of special alloy, intermetallic compound, to be an excellent catalyst. Impregnation procedure with appropriate metal precursors and reductants provided single-phase particles of intermetallic compounds with diameter smaller than 10 nm on various supports. Some compounds between noble metal and typical element showed higher selectivity than pure metal catalysts in selective hydrogenation, oxidative dehydrogenation, etc. The strong correlation was found between catalytic property and the nature of intermetallic compound, such as, surface atomic arrangement and electronic state of surface atoms. It is concluded that intermetallic compounds are promising materials to obtain high-performance catalysts.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (36 results)

All 2015 2014 2013 2012 2011 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 3 results) Presentation (25 results) (of which Invited: 1 results) Remarks (2 results)

  • [Journal Article] Mechanistic Study on Aerobic Oxidation of Amine over Intermetallic Pd3Pb: Concerted Promotion Effects by Pb and Support Basicity2015

    • Author(s)
      S. Furukawa, A. Suga and T. Komatsu
    • Journal Title

      ACS Catal.

      Volume: 5 Issue: 2 Pages: 1214-1222

    • DOI

      10.1021/cs501695m

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intermetallic Compound Nanoparticles Dispersed on the Surface of Oxide Support as Active and Selective Catalysts2015

    • Author(s)
      T. Komatsu and S. Furukawa
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 56 Issue: 4 Pages: 460-467

    • DOI

      10.2320/matertrans.MF201408

    • NAID

      130005129269

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Efficient Catalytic System for Synthesis of Trans-Stilbene from Diphenylacetylene Using Rh-Based Intermetallic Compounds2014

    • Author(s)
      S. Furukawa, A. Yokoyama and T. Komatsu
    • Journal Title

      ACS Catal.

      Volume: 4 Issue: 10 Pages: 3581-3585

    • DOI

      10.1021/cs500947d

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Bifunctional Catalytic System Effective for Oxidative Dehydrogenation of 1-Butene and n-Butane Using Pd-Based Intermetallic Compounds2014

    • Author(s)
      S. Furukawa, M. Endo and T. Komatsu
    • Journal Title

      ACS Catal.

      Volume: 4 Issue: 10 Pages: 3533-3542

    • DOI

      10.1021/cs500920p

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Study on the Hydrogen Activation Properties of Ni-Based Intermetallics: Relationship between Reactivity and Electronic State2014

    • Author(s)
      S. Furukawa, K. Ehara, K. Ozawa and T. Komatsu
    • Journal Title

      Phys. Chem. Chem. Phys.,

      Volume: 16 Issue: 37 Pages: 19828-19831

    • DOI

      10.1039/c4cp01514b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic properties of Pt-based intermetallic compounds in dehydrogenation ofcyclohexane and n-butane2014

    • Author(s)
      Shinya Furukawa, Asako Tamura, Kenichi Ozawa, Takayuki Komatsu
    • Journal Title

      Applied Catalysis A: General

      Volume: 469 Pages: 300-305

    • DOI

      10.1016/j.apcata.2013.10.012

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly efficient aerobic oxidation of various amines using Pd3Pb intermetallic compounds as catalysts2014

    • Author(s)
      Shinya Furukawa, Akifusa Suga, Takayuki Komatsu
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 25 Pages: 3277-3280

    • DOI

      10.1039/c4cc00024b

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemoselective hydrogenation of nitrostyrene to aminostyrene over Pd- and Rh-based intermetallic compounds2014

    • Author(s)
      Shinya Furukawa, Yurika Yoshida, Takayuki Komatsu
    • Journal Title

      ACS Catalysis

      Volume: 4 Issue: 5 Pages: 1441-1450

    • DOI

      10.1021/cs500082g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of alumina-supported intermetallic compounds2013

    • Author(s)
      Shinya Furukawa, Kenichi Ozawa, Takayuki Komatsu
    • Journal Title

      RSC Advances

      Volume: 3 Issue: 45 Pages: 23269-23277

    • DOI

      10.1039/c3ra43163k

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Pd系金属間化合物触媒を用いたアルコールによるアミンのN-アルキル化反応2015

    • Author(s)
      鈴木遼平、古川森也、小松隆之
    • Organizer
      第115回触媒討論会
    • Place of Presentation
      成蹊大学(東京都、武蔵野市)
    • Year and Date
      2015-03-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] CO吸着IRによるRh系金属間化合物の表面原子配列に関するキャラクタリゼーション2015

    • Author(s)
      古川森也、羅輝、小松隆之
    • Organizer
      第115回触媒討論会
    • Place of Presentation
      成蹊大学(東京都、武蔵野市)
    • Year and Date
      2015-03-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pt-based intermetallic compounds: Active catalysts for preferential oxidation of CO in hydrogen2014

    • Author(s)
      Takayuki Komatsu
    • Organizer
      2014 Japan-China Advanced Materials and Nanotechnology Sympojium
    • Place of Presentation
      IPC生産性国際交流センター(神奈川県葉山市)
    • Year and Date
      2014-11-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pt3Co触媒上でのPROX反応における担体効果2014

    • Author(s)
      江原健悟、古川森也、小澤健一、小松隆之
    • Organizer
      第44回石油・石油化学討論会
    • Place of Presentation
      旭川グランドホテル(北海道旭川市)
    • Year and Date
      2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pd系およびRh系金属間化合物を用いたニトロスチレンの官能基選択的水素化2014

    • Author(s)
      古川森也、吉田由利佳、小松隆之
    • Organizer
      第44回石油・石油化学討論会
    • Place of Presentation
      旭川グランドホテル(北海道旭川市)
    • Year and Date
      2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Catalytic Performance of Pt-based Intermetallic Compound Catalysts in Hydrogenation of chloronitrobenzene2014

    • Author(s)
      S. Iihama, S. Furukawa, K. Ozawa and T. Komatsu
    • Organizer
      第44回石油・石油化学討論会
    • Place of Presentation
      旭川グランドホテル(北海道旭川市)
    • Year and Date
      2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ru触媒を用いた尿素の加水分解による水素生成2014

    • Author(s)
      鈴木遼平、越智一喜、古川森也、小松隆之
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島大学東広島キャンパス(広島県東広島市)
    • Year and Date
      2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pd系およびRh系金属間化合物を用いたニトロスチレンの選択的水素化2014

    • Author(s)
      古川森也、吉田由利佳、小松隆之
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島大学東広島キャンパス(広島県東広島市)
    • Year and Date
      2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] アルミナ担持金属間化合物の調製2013

    • Author(s)
      古川森也
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学(大阪府)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Pd系金属間化合物を用いたアミンの酸化脱水素2013

    • Author(s)
      須賀昭房
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学(大阪府)
    • Related Report
      2012 Annual Research Report
  • [Presentation] PROX reaction on PtCu intermetallic compound catalysts supported on alumina2012

    • Author(s)
      Takayuki Komatsu
    • Organizer
      15th International Congress on Catalysis
    • Place of Presentation
      Munich, Germany
    • Related Report
      2012 Annual Research Report
  • [Presentation] アルケン異性化に対するRh系金属間化合物の触媒作用の解明2012

    • Author(s)
      越智一喜
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田キャッスルホテル(秋田県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Co系金属間化合物触媒を用いた有機化合物のCTH反応2012

    • Author(s)
      飯濱 翔
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田キャッスルホテル(秋田県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] アンモニア合成に対する金属間化合物の触媒特性2011

    • Author(s)
      石黒恵太、小澤健一、小松隆之
    • Organizer
      第41回石油・石油化学討論会
    • Place of Presentation
      山口県山口市
    • Year and Date
      2011-11-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属間化合物の構造・電子状態が水素分子の活性化に及ぼす影響2011

    • Author(s)
      菅野直樹、小澤健一、小松隆之
    • Organizer
      第41回石油・石油化学討論会
    • Place of Presentation
      山口県山口市
    • Year and Date
      2011-11-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属間化合物を触媒としたニトロベンゼンのCTH反応2011

    • Author(s)
      吉田由利佳、小澤健一、小松隆之
    • Organizer
      第41回石油・石油化学討論会
    • Place of Presentation
      山口県山口市
    • Year and Date
      2011-11-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属間化合物の特異な触媒作用と吸着能の関係2011

    • Author(s)
      小松隆之
    • Organizer
      日本金属学会2011秋期大会
    • Place of Presentation
      沖縄県那覇市
    • Year and Date
      2011-11-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] Preferential Oxidation of CO in Hydrogen on PtCu Nano Particles Supported on Alumina

    • Author(s)
      Takayuki Komatsu, Michiko Takasaki, Shinya Furukawa, Kenichi Ozawa
    • Organizer
      International Conference on Processing and Manufacturing of Advanced Materials
    • Place of Presentation
      Lio Hotel, (Las Vegas, USA)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Preparation of alumina-supported intermetallic compounds

    • Author(s)
      Shinya Furukawa, Kenichi Ozawa, Takayuki Komatsu
    • Organizer
      The 6th Asia-Pacific Congress on Catalysis
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pd系金属間化合物触媒を用いたアミンの酸化脱水素

    • Author(s)
      須賀昭房、古川森也、小澤健一、小松隆之
    • Organizer
      第43回石油・石油化学討論会
    • Place of Presentation
      北九州国際会議場(福岡県北九州市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 金属間化合物触媒を用いたn-ブタンの酸化脱水素による1,3-ブタジエンの生成

    • Author(s)
      遠藤雅大、古川森也、小松隆之
    • Organizer
      第43回石油・石油化学討論会
    • Place of Presentation
      北九州国際会議場(福岡県北九州市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pd3Pb金属間化合物触媒を用いた高効率アミン酸化

    • Author(s)
      古川森也、須賀昭房、小松隆之
    • Organizer
      第113回触媒討論会
    • Place of Presentation
      ロワジールホテル豊橋(愛知県豊橋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] アルミナ担持金属間化合物の調製とその触媒特性

    • Author(s)
      古川森也、須賀昭房、江原健悟、小澤健一、小松隆之
    • Organizer
      第43回石油・石油化学討論会
    • Place of Presentation
      北九州国際会議場(福岡県北九州市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] アルミナ担持金属間化合物の調製―化合物形成に対する金属前駆体および還元剤の影響―

    • Author(s)
      古川森也、小澤健一、小松隆之
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学(秋田県、秋田市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ru系金属間化合物触媒を用いたアンモニアの分解による水素製造

    • Author(s)
      遠藤雅大
    • Organizer
      石油学会第17回JPIJS若手研究者のためのポスターセッション
    • Place of Presentation
      タワーホール船堀(東京都)
    • Related Report
      2012 Annual Research Report
  • [Remarks] 小松研究室ホームページ-Research-金属間化合物

    • URL

      http://www.cms.titech.ac.jp/~komatsu/pages/intermetallic.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 小松研究室 -Komatsu Laboratory-

    • URL

      http://www.cms.titech.ac.jp/~komatsu/index.htm

    • Related Report
      2013 Annual Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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