| Project/Area Number |
23360357
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Osaka University |
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Principal Investigator |
KANEDA kiyotomi 大阪大学, 太陽エネルギー化学研究センター, 特任教授 (90029554)
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| Co-Investigator(Kenkyū-buntansha) |
JITSUKAWA Koichiro 大阪大学, 基礎工学研究科, 教授 (50235793)
MIZUGAKI Tomoo 大阪大学, 基礎工学研究科, 准教授 (50314406)
MITSUDOME Takato 大阪大学, 基礎工学研究科, 助教 (00437360)
|
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2012: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
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| Keywords | 触媒・化学プロセス / バイオマス / 固体触媒 / グリセロール / 金属ナノ粒子 / 機能集積触媒 / ハイドロタルサイト / ナノ粒子 |
|---|
| Research Abstract |
In order to develop the environmentally benign chemical processes utilizing biomass derived feedstocks, especially glycerol, high performance heterogeneous catalysts were designed using metal nanoparticles and inorganic crystallites. Various organic transformations from glycerol such as hydrogenolysis to 1,3-propanediol or 1,2-propanediol, one-pot transformation to 1,3-diacetylglyceol, and condensation to cyclic acetals could be achieved using the heterogeneous catalysts. These catalysts are easily recycled without appreciable loss of their activity or selectivity.
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