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Electrode property of the composite of metal oxides and carbon materials prepared with aqueous solution methods for metal-oxygen batteries

Research Project

Project/Area Number 23360435
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionThe University of Tokyo

Principal Investigator

HIBINO Mitsuhiro  東京大学, 工学(系)研究科(研究院), 研究員 (20270910)

Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2011: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000)
Keywords二次電池 / 金属-酸素電池 / 電極材料 / ペロブスカイト関連構造化合物 / 金属酸化物 / 金属-空気電池 / 空気極 / 電極触媒 / 複合体電極 / 金属-空気電池 / 金属-酸素電池
Research Abstract

The search of the oxides that function as electrodes in metal-oxygen batteries was performed. Since oxygen atoms in a metal oxide instead of gaseous oxygen molecules in air can be used as active materials if the metal oxide allows insertion or extraction of oxygen atoms, various oxides were investigated in terms of oxygen insertion and extraction. As a result, it was found that a few iron-based and a nickel-based oxides with perovskite-related structures allow reversible oxygen extraction or insertion. By using these materials, a new type battery in which oxygen atoms were shuttled between a cathode and an anode electrode via an aqueous alkaline electrolyte was constructed. Further another new type battery that was composed of the oxide allowing oxygen extraction for a cathode, a metal, such as Li and Na, for an anode, and an organic electrolyte was demonstrated.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (42 results)

All 2014 2013 2012 2011 Other

All Journal Article (9 results) (of which Peer Reviewed: 4 results) Presentation (25 results) (of which Invited: 1 results) Book (3 results) Remarks (3 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Electrochemical Oxidation of BaFeO_2.5 to BaFeO_32014

    • Author(s)
      Y. Suga, M. Hibino, T. Kudo, N. Mizuno
    • Journal Title

      Electrochimica Acta

      Volume: (in print) Pages: 359-362

    • DOI

      10.1016/j.electacta.2014.05.162

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Reactions of Perovskite-Type SrCoO_<3-δ> via Topotactic Oxygen Extraction/Insertion in Aprotic Li+ Electrolyte Solutions2014

    • Author(s)
      Y. Ogasawara, M. Hibino, T. Kudo, N. Mizuno
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 161 Issue: 5 Pages: A792-A797

    • DOI

      10.1149/2.063405jes

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] A New Rechargeable Sodium Battery Utilizing Reversible Topotactic Oxygen Extraction/Insertion of CaFeOz (2.5 <= z <= 3) in An Organic Electrolyte2014

    • Author(s)
      M. Hibino, R. Harimoto, Y. Ogasawara, R. Kido, A. Sugahara, T. Kudo, E. Tochigi, N. Shibata, Y. Ikuhara, N. Mizuno
    • Journal Title

      Journal of the American Chemical Society

      Volume: 136 Issue: 1 Pages: 488-494

    • DOI

      10.1021/ja411365z

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 酸素ロッキング電池 -電極間で酸化物イオンの受け渡しをする新しいアニオン型電池-2013

    • Author(s)
      日比野光宏, 水野哲孝
    • Journal Title

      マテリアルステージ

      Volume: 13 Pages: 67-69

    • NAID

      40019784095

    • URL

      http://www.gijutu.co.jp/doc/magazine/m_2013_08.htm

    • Related Report
      2013 Final Research Report
  • [Journal Article] 酸素ロッキング電池2013

    • Author(s)
      日比野光宏, 水野哲孝
    • Journal Title

      未来材料2013

      Pages: 42-47

    • URL

      http://www.nts-book.co.jp/mirai/bn.html

    • Related Report
      2013 Final Research Report
  • [Journal Article] 酸素ロッキング電池 -電極間で酸化物イオンの受け渡しをする新しいアニオン型電池-2013

    • Author(s)
      日比野光宏,水野哲孝
    • Journal Title

      マテリアルステージ

      Volume: 13 Pages: 67-69

    • NAID

      40019784095

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Oxygen rocking aqueous batteries utilizing reversible topotactic oxygen insertion/extraction in iron-based perovskite oxides Ca_<1-x>LaxFeO_<3-δ>2012

    • Author(s)
      M. Hibino, T. Kimura, Y. Suga, T. Kudo, N. Mizuno
    • Journal Title

      Scientific Reports

      Volume: 2 Issue: 1 Pages: 601-601

    • DOI

      10.1038/srep00601

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] リチウム-空気二次電池-原理から最近の動向まで-2012

    • Author(s)
      日比野光宏
    • Journal Title

      触媒

      Volume: 54 Pages: 203-208

    • NAID

      10030518664

    • URL

      http://www.shokubai.org/jnl/cgi-bin/ccotw.cgi

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Journal Article] 酸素ロッキング電池2012

    • Author(s)
      日比野 光宏, 水野 哲孝
    • Journal Title

      未来材料

      Volume: 13 Pages: 42-47

    • Related Report
      2012 Annual Research Report
  • [Presentation] 酸化物イオン脱挿入を利用したAFeO_3 (A = Ca, Sr, Ba)のナトリウム電池正極特性2013

    • Author(s)
      日比野光宏, 張本龍司, 工藤徹一, 水野哲孝
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪(大阪国際会議場)
    • Year and Date
      2013-10-09
    • Related Report
      2013 Final Research Report
  • [Presentation] SrCoO_2.92 の電気化学的酸化物イオン脱挿入とリチウム電池正極特性2013

    • Author(s)
      小笠原義之, 日比野光宏, 工藤徹一, 水野哲孝
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪(大阪国際会議場)
    • Year and Date
      2013-10-08
    • Related Report
      2013 Final Research Report
  • [Presentation] Oxygen rocking aqueous batteries utilizing reversible topotactic oxygen insertion/extraction in iron-based perovskite oxides Ca_<1-x>La_xFeO_<3-δ>2013

    • Author(s)
      M.Hibino, Y.Suga, T.Kimura, T.Kudo, Y.Sumida, N.Mizuno
    • Organizer
      International Symposium on Innovation of Energy Storage Device by Interdisciplinary Synergy
    • Place of Presentation
      東京(東京大学武田先端知ビル)
    • Year and Date
      2013-01-18
    • Related Report
      2013 Final Research Report
  • [Presentation] SrCoO2.92の電気化学的酸化物イオン脱挿入とリチウム電池正極特性2013

    • Author(s)
      小笠原義之、日比野光宏、工藤徹一、水野哲孝
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪国際会議場,大阪府
    • Related Report
      2013 Annual Research Report
  • [Presentation] 酸化物イオン脱挿入を利用したAFeO3(A = Ca, Sr, Ba)のナトリウム電池正極特性2013

    • Author(s)
      日比野光宏,張本龍司,工藤徹一,水野哲孝
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪国際会議場,大阪府
    • Related Report
      2013 Annual Research Report
  • [Presentation] リチウム系有機電解液を用いたSrCoO_<3-δ>の電気化学的還元・酸化挙動2012

    • Author(s)
      小笠原義之, 日比野光宏, 工藤徹一, 水野哲孝
    • Organizer
      第38回固体イオニクス討論会
    • Place of Presentation
      京都(京都テルサ)
    • Year and Date
      2012-12-04
    • Related Report
      2013 Final Research Report
  • [Presentation] Sr_3Fe2O_<7-δ>の電気化学的酸素脱挿入を利用したリチウム電池正極としての検討2012

    • Author(s)
      須賀陽介, 日比野光宏, 工藤徹一, 水野哲孝
    • Organizer
      第38回固体イオニクス討論会
    • Place of Presentation
      京都(京都テルサ)
    • Year and Date
      2012-12-04
    • Related Report
      2013 Final Research Report
  • [Presentation] 鉄系複酸化物AFeO_3(A = Ca, Sr, Ba)と様々な負極を組み合わせた新しい電池2012

    • Author(s)
      日比野光宏, 城戸良太, 工藤徹一, 水野哲孝
    • Organizer
      第53回電池討論会
    • Place of Presentation
      福岡(ヒルトン福岡シーホーク)
    • Year and Date
      2012-11-15
    • Related Report
      2013 Final Research Report
  • [Presentation] 酸素欠損ペロブスカイト型AFeO_2.5 (A = Ca, Sr, Ba)の有機電解液中での電気化学的酸化2012

    • Author(s)
      木村豪志, 日比野光宏, 工藤徹一, 水野哲孝
    • Organizer
      第53回電池討論会
    • Place of Presentation
      福岡(ヒルトン福岡シーホーク)
    • Year and Date
      2012-11-15
    • Related Report
      2013 Final Research Report
  • [Presentation] ペロブスカイト型鉄系複酸化物AFeO_3 (A = Ca, Sr, Ba)のナトリウム電池正極特性2012

    • Author(s)
      張本龍司, 日比野光宏, 工藤徹一, 水野哲孝
    • Organizer
      第53回電池討論会
    • Place of Presentation
      福岡(ヒルトン福岡シーホーク)
    • Year and Date
      2012-11-15
    • Related Report
      2013 Final Research Report
  • [Presentation] Electrode property of A_0.5La_0.5FeO_z (A = Ca, Sr) for rocking chair type oxide ion batteries2012

    • Author(s)
      M.Hibino, Y.Suga, T.Kimura, R.Kido, T.Kudo, N.Mizuno
    • Organizer
      The 13th Asian Conference on Solid State Ionics
    • Place of Presentation
      仙台(東北大学さくらホール)
    • Year and Date
      2012-07-20
    • Related Report
      2013 Final Research Report
  • [Presentation] ペロブスカイト型Ca_0.5La_0.5FeO_z の電気化学的酸素脱挿入特性2012

    • Author(s)
      木村豪志, 日比野光宏, 須賀陽介, 工藤徹一, 水野哲孝
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      静岡(アクトシティ浜松)
    • Year and Date
      2012-03-31
    • Related Report
      2013 Final Research Report
  • [Presentation] BaFeO_2.5 への電気化学的酸素ドープ2012

    • Author(s)
      須賀陽介, 日比野光宏, 木村豪志, 工藤徹一, 水野哲孝
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      静岡(アクトシティ浜松)
    • Year and Date
      2012-03-31
    • Related Report
      2013 Final Research Report
  • [Presentation] BaFeO_<2.5>への電気化学的酸素ドープ2012

    • Author(s)
      須賀陽介, 日比野光宏, 木村豪志, 工藤徹一, 水野哲孝
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      静岡
    • Year and Date
      2012-03-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] ペロブスカイト型Ca_<0.5>La_<0.5>FeO_2の電気化学的酸素脱挿入特性2012

    • Author(s)
      木村豪志, 日比野光宏, 須賀陽介, 工藤徹一, 水野哲孝
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      静岡
    • Year and Date
      2012-03-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] 欠陥ペロブスカイト型鉄系酸化物の電気化学的酸素脱挿入と電池電極特性2012

    • Author(s)
      日比野光宏, 須賀陽介, 木村豪志, 城戸良太, 工藤徹一, 水野哲孝
    • Organizer
      第13回メスバウアー分光研究会シンポジウム
    • Place of Presentation
      東京(東京大学本郷キャンパス)
    • Year and Date
      2012-03-23
    • Related Report
      2013 Final Research Report
  • [Presentation] 欠陥ペロブスカイト型鉄系酸化物の電気化学的酸素脱挿入と電池電極特性2012

    • Author(s)
      日比野光宏, 須賀陽介, 木村豪志, 城戸良太, 工藤徹一, 水野哲孝
    • Organizer
      第13回メスバウアー分光研究会シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2012-03-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Electrode property of A0.5La0.5FeOz (A = Ca, Sr) for rocking chair type oxide ion batteries2012

    • Author(s)
      Mitsuhiro Hibino, Yosuke Suga, Takeshi Kimura, Ryota Kido, Tetsuichi Kudo, Noritaka Mizuno
    • Organizer
      The 13th Asian Conference on Solid State Ionics
    • Place of Presentation
      東北大学さくらホール,宮城
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 鉄系複酸化物AFeO3(A = Ca, Sr, Ba)と様々な負極を組み合わせた新しい電池2012

    • Author(s)
      日比野光宏,城戸良太,工藤徹一,水野哲孝
    • Organizer
      第53回電池討論会
    • Place of Presentation
      ヒルトン福岡シーホーク,福岡
    • Related Report
      2012 Annual Research Report
  • [Presentation] 酸素欠損ペロブスカイト型AFeO2.5 (A = Ca, Sr, Ba)の有機電解液中での電気化学的酸化2012

    • Author(s)
      木村豪志,日比野光宏,工藤徹一,水野哲孝
    • Organizer
      第53回電池討論会
    • Place of Presentation
      ヒルトン福岡シーホーク,福岡
    • Related Report
      2012 Annual Research Report
  • [Presentation] ペロブスカイト型鉄系複酸化物AFeO3 (A = Ca, Sr, Ba)のナトリウム電池正極特性2012

    • Author(s)
      張本龍司,日比野光宏,工藤徹一,水野哲孝
    • Organizer
      第53回電池討論会
    • Place of Presentation
      ヒルトン福岡シーホーク,福岡
    • Related Report
      2012 Annual Research Report
  • [Presentation] Sr3Fe2O7-dの電気化学的酸素脱挿入を利用したリチウム電池正極としての検討2012

    • Author(s)
      須賀陽介,日比野光宏,工藤徹一,水野哲孝
    • Organizer
      第38回固体イオニクス討論会
    • Place of Presentation
      京都テルサ,京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] リチウム系有機電解液を用いたSrCoO3-&#61540;の電気化学的還元・酸化挙動2012

    • Author(s)
      小笠原義之,日比野光宏,工藤徹一,水野哲孝
    • Organizer
      第38回固体イオニクス討論会
    • Place of Presentation
      京都テルサ,京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] ブラウンミラーライト型AFeO_2.5 (A = Ca, Sr)の電気化学的酸素脱挿入特性2011

    • Author(s)
      日比野光宏, 須賀陽介, 木村豪志, 城戸良太, 工藤徹一, 水野哲孝
    • Organizer
      第52回電池討論会
    • Place of Presentation
      東京(タワーホール船堀)
    • Year and Date
      2011-10-21
    • Related Report
      2013 Final Research Report
  • [Presentation] ブラウンミラーライト型AFeO_<2.5>(A=Ca, Sr)の電気化学的酸素脱挿入特性2011

    • Author(s)
      日比野光宏, 須賀陽介, 木村豪志, 城戸良太, 工藤徹一, 水野哲孝
    • Organizer
      第52回電池討論会
    • Place of Presentation
      東京
    • Year and Date
      2011-10-21
    • Related Report
      2011 Annual Research Report
  • [Book] 酸素シャトル電池の提案と動作実証2013

    • Author(s)
      宇宙資源(宮本英昭, 津田馨編), 日比野光宏, 水野哲孝
    • Publisher
      東京大学総合研究博物館
    • Related Report
      2013 Final Research Report
  • [Book] 第6章5節酸素シャトル電池の提案と実証(リチウム空気電池の最前線(周豪慎監修))2013

    • Author(s)
      日比野光宏, 水野哲孝
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Final Research Report
  • [Book] リチウム空気電池の最前線(周 豪慎監修) 担当部分pp.153-1622013

    • Author(s)
      日比野光宏,水野哲孝
    • Total Pages
      177
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://park.itc.u-tokyo.ac.jp/mizuno/japanese/research.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 水野研究室の研究コンセプト

    • URL

      http://park.itc.u-tokyo.ac.jp/mizuno/japanese/research.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 水野研究室

    • URL

      http://park.itc.u-tokyo.ac.jp/mizuno

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] Oxygen shuttle battery2012

    • Inventor(s)
      日比野光宏, 水野哲孝, 工藤徹一, 須賀陽介, 木村豪志
    • Industrial Property Rights Holder
      東京大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2012-10-03
    • Related Report
      2013 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 酸素シャトル電池2012

    • Inventor(s)
      日比野光宏, 水野哲孝, 工藤徹一, 須賀陽介, 木村豪志
    • Industrial Property Rights Holder
      東京大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2012-04-03
    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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