| Budget Amount *help |
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2014: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2011: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
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| Outline of Final Research Achievements |
Conventionally organometallic chemistry has been used for functionalization of heteroaromatic compounds. From viewpoint of new selectivity and environmental sustainability, I focused my interest on the development of metal-free method for functionalization of heteroaromatic compounds. I successfully developed the catalytic functionalization using onium amide which derived from the combination of onium fluorides and aminosilanes. Another catalytic reaction developed in this project is the direct silylation of heteroaromatic compounds using trifluoromethylsilane and fluoride, which reaction is compatible with various functinal groups including nitro group.
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