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Exploring chlorination by-products from pesticides using high resolution mass spectrometry

Research Project

Project/Area Number 23510102
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionKagoshima University

Principal Investigator

TAKANASHI Hirokazu  鹿児島大学, 理工学研究科, 准教授 (40274740)

Project Period (FY) 2011-04-28 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords農薬 / 変化体 / 塩素処理 / 質量分析 / 副生成物 / 精密質量分析 / 環境変化体 / 高分解能LC/MS / 変異原性物質 / 構造推定 / 変異原 / 構造解析
Outline of Final Research Achievements

Pesticides are sprayed onto plants, weeds or soil for insect or weed control, and some of the pesticides will transfer to the water environment. These pesticides may undergo various reactions such as hydrolysis, photolysis and biodegradation in the water environment. Pesticides and Pesticide Transformation Products in Water environments (PTPWs) have been found in natural water. Natural water containing these pesticides and their PTPWs will often be chlorinated at waterworks. In this study, 3-methyl-4-nitrophenol (3M4NP) was focused as a possible precursor of mutagens in chlorinated fenitrothion. 3M4NP is a typical hydrolysate of fenitrothion and reported that 3M4NP itself has no mutagenicity. Chlorinated 3M4NP sample was analyzed by high resolution/accurate mass LC/MS and 1H-NMR to identify chlorination by-products from 3M4NP, resulting in successful identification of a chlorination by-product.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (12 results)

All 2015 2014 2013 2012 2011

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (10 results) (of which Invited: 1 results)

  • [Journal Article] Production of Chloro-5-hydroxy-2-nitrobenzoic Acid through Chlorination of 3-Methyl-4-nitrophenol, a Typical Hydrolysate of Fenitrothion2012

    • Author(s)
      H. TAKANASHI, K. ABIRU, H. TANAKA, M. KISHIDA, T. NAKAJIMA, A. OHKI, T. KONDO, T. KAMEYA and T. MATSUSHITA
    • Journal Title

      Journal of Water and Environment Technology

      Volume: 10 Issue: 4 Pages: 437-447

    • DOI

      10.2965/jwet.2012.437

    • NAID

      130003363000

    • ISSN
      1348-2165
    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Mutagen Formation Potential (MFP) of Kotsuki River Water and Contribution of Pesticides to MFP2011

    • Author(s)
      Kazuya ABIRU, Hirokazu TAKANASHI, Misako KISHIDA, Tsunenori NAKAJIMA and Akira OHKI
    • Journal Title

      Journal of Water and Environment Technology

      Volume: 9 Issue: 4 Pages: 349-357

    • DOI

      10.2965/jwet.2011.349

    • NAID

      130001907710

    • ISSN
      1348-2165
    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 多変量解析による3-methyl-4-nitrophenol塩素処理物中の変異原の探索2015

    • Author(s)
      浜 知広、高梨啓和、中島常憲、大木 章、上田岳彦
    • Organizer
      第49回日本水環境学会年会
    • Place of Presentation
      金沢大学(石川県・金沢市)
    • Year and Date
      2015-03-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] 多変量解析による3-methyl-4-nitrophenol塩素処理物中の変異原の網羅的探索2015

    • Author(s)
      浜 知広、一宮利恵、高梨啓和、中島常憲、大木 章、上田岳彦
    • Organizer
      平成26年度日本水環境学会九州沖縄支部研究発表会
    • Place of Presentation
      鹿児島工業高等専門学校(鹿児島県・霧島市)
    • Year and Date
      2015-02-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Production of chloro-5-hydroxy-2-nitrobenzoic acid through chlorination of 3-methyl-4- nitrophenol2014

    • Author(s)
      高梨啓和
    • Organizer
      公益社団法人日本水環境学会平成25年度論文賞受賞講演
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Year and Date
      2014-06-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 殺虫剤fenitrothionの環境変化体3-methyl-4-nitrophenol塩素処理副生成物の構造推定2014

    • Author(s)
      田中華子、糸満桃子、高梨啓和、中島常憲、大木 章、上田岳彦、近藤貴志、亀屋隆志、松下 拓
    • Organizer
      第48回日本水環境学会年会
    • Place of Presentation
      仙台市
    • Related Report
      2013 Research-status Report
  • [Presentation] 殺虫剤fenitrothionの環境変化体3-methyl-4-nitrophenol塩素処理副生成物の構造解析2014

    • Author(s)
      田中華子、糸満桃子、高梨啓和、中島常憲、大木 章、上田岳彦、近藤貴志、亀屋隆志、松下 拓
    • Organizer
      日本水環境学会九州支部研究発表会
    • Place of Presentation
      霧島市
    • Related Report
      2013 Research-status Report
  • [Presentation] LC-MSを用いた3-メチル-4-ニトロフェノール塩素処理試料中の変異原性物質の探索2014

    • Author(s)
      糸満桃子、松崎直樹、田中華子、高梨啓和、中島常憲、大木 章、上田岳彦、近藤貴志、亀屋隆志、松下 拓
    • Organizer
      日本水環境学会九州支部研究発表会
    • Place of Presentation
      霧島市
    • Related Report
      2013 Research-status Report
  • [Presentation] LC/MSを用いた農薬変化体(PTPWs)塩素処理物中の変異原の探索2013

    • Author(s)
      高梨啓和、田中華子、糸満桃子、松崎直樹、中島常憲、大木 章、上田岳彦、近藤貴志、亀屋隆志、松下 拓
    • Organizer
      第16回日本水環境学会シンポジウム
    • Place of Presentation
      那覇市
    • Related Report
      2013 Research-status Report
  • [Presentation] Accurate Mass Analysis of Chlorination By-Products of Fenitrothion2012

    • Author(s)
      H. TAKANASHI, K. ABIRU, H. TANAKA, M. KISHIDA, T. NAKAJIMA, A. OHKI, T. KONDO, T. KAMEYA and T. MATSUSHITA
    • Organizer
      10th China-Japan Water Environment Symposium-Water Reclamation, Remediation and Restoration towards a Greener Asia-
    • Place of Presentation
      Shenzhen, China
    • Related Report
      2012 Research-status Report
  • [Presentation] 農薬分解物塩素処理サンプル中の変異原性物質の探索2012

    • Author(s)
      田中華子、阿比留和也、高梨啓和、中島常憲、大木章、松下拓、近藤貴志、亀屋隆志
    • Organizer
      平成23年度日本水環境学会九州支部研究発表会
    • Place of Presentation
      北九州
    • Related Report
      2011 Research-status Report
  • [Presentation] 精密質量分析による農薬塩素処理物中の変異原性物質の探索2012

    • Author(s)
      阿比留和也、田中華子、高梨啓和、中島常憲、大木章、松下拓、近藤貴志、亀屋隆志
    • Organizer
      第46回日本水環境学会年会
    • Place of Presentation
      東京
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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