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High-concentration nitrogen removal in industrial wastewater by nitrous biological reaction and subcritical hydrothermal reaction

Research Project

Project/Area Number 23510108
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionUbe National College of Technology

Principal Investigator

YAMASAKI HIROHITO  宇部工業高等専門学校, 宇部工業高等専門学校, 教授 (20300618)

Co-Investigator(Kenkyū-buntansha) NEGORO Munetaka  独立行政法人国立高等専門学校機構 宇部工業高等専門学校, 物質工学科, 准教授 (80258152)
MIYAKOSHI Akihiko  独立行政法人国立高等専門学校機構 旭川工業高等専門学校, 物質化学工学科, 教授 (10249724)
竹内 正美  宇部工業高等専門学校, その他部局等, 教授 (30043889)
Co-Investigator(Renkei-kenkyūsha) TAKEUCHI Masami  独立行政法人国立高等専門学校機構 宇部工業高等専門学校, 物質工学科, 教授 (30043889)
MURAKAMI Sadaaki  独立行政法人国立高等専門学校機構 広島商船高等専門学校, 校長 (00035065)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords環境保全技術 / 省エネルギー技術 / 環境負荷低減技術 / 固定化亜硝酸菌 / 窒素除去 / 生物亜硝化反応 / アンモニア態窒素 / 亜臨界水熱反応 / 無触媒 / 工業排水処理システム / 高濃度アンモニア態窒素 / 固定化細菌 / バイオリアクタ / 亜硝酸態窒素 / 工業排水処理 / 亜硝酸化細菌
Research Abstract

Acclimated nitrifying bacteria from Effective Micro-organism groups for a highly concentrated ammonium sulfate as high as 5,300 mg/L or above were physically immobilized on polymeric spherical hydrogel. The immobilized nitrifying bacteria which produced only NO2- from NH4+ could reach an equilibrium condition after about 30 days. Especially, at pH 7.7, it could reach equilibrium in only 22 days, the velocity of the removal of NH4-N (Vr) = 160 mg/(L*d), showed an excellent value, and then the molar ratio of NH4+ and NO2 was almost the same (NH4+ : NO2- = 1.3 : 1).
60mL of model raw wastewater containing fixed amounts of NH4-N and NO2-N in a molar ratio of 1:1 was poured into a pressure bottle. The subcritical hydrothermal reaction was carried out for 1h. In the case of 3,000 mg/L, full decomposition and over 90% decomposition was shown at reaction temp. of over 180 and 160 centigrade temp. At 5,000 mg/L, a lower reaction temp. at 140 centigrade temp. showed 95% decomposition.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (21 results)

All 2014 2013 2012 2011 Other

All Journal Article (4 results) (of which Peer Reviewed: 3 results) Presentation (15 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] 固定化亜硝酸菌群による高濃度窒素含有排水処理と生態学的考察2013

    • Author(s)
      山﨑博人,吉屋愛恵,根來宗孝,福永公寿
    • Journal Title

      環境技術

      Volume: Vol. 42, No. 6 Pages: 362-369

    • NAID

      10031174474

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 固定化亜硝酸菌群による高濃度窒素含有排水処理と生態学的考察2013

    • Author(s)
      山﨑博人、吉屋愛恵、根來宗孝、福永公寿
    • Journal Title

      環境技術

      Volume: 6 Pages: 362-369

    • NAID

      10031174474

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] シクロデキストリンの包接機能に着目した環境共生材料の開発研究2012

    • Author(s)
      山﨑博人,福永公寿
    • Journal Title

      環境技術

      Volume: Vol. 41, No. 11 Pages: 679-682

    • Related Report
      2013 Final Research Report
  • [Journal Article] シクロデキストリンの包接機能に着目した環境共生材料の開発研究2012

    • Author(s)
      山﨑博人,福永公寿
    • Journal Title

      環境技術

      Volume: 41 Pages: 679-682

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Removal of high-concentration ammonium and hydrogen peroxide with hydrogen reduction followed by subcritical hydrothermal reaction2014

    • Author(s)
      H. Yamasaki, M. Negoro, A. Miyakoshi, K. Fukunaga
    • Organizer
      5^<th> EuCheMS Chemistry Congress
    • Place of Presentation
      Istanbul(Turkey)
    • Related Report
      2013 Final Research Report
  • [Presentation] Influence of biological nitritati on reaction on various immobilization supports2013

    • Author(s)
      H. Yamasaki, M. Negoro, A. Miyakoshi, K. Fukunaga
    • Organizer
      The 15th Asian Chemical Congress
    • Place of Presentation
      Resorts World Sentosa(Singapore)
    • Related Report
      2013 Final Research Report
  • [Presentation] Influence of biological nitritati on reaction on various immobilization supports2013

    • Author(s)
      H. YAMASAKI, M. NEGORO, A. MIYAKOSHI, K. FUKUNAGA
    • Organizer
      15th Asian Chemical Congress
    • Place of Presentation
      Resorts World Sentosa(Singapore)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Influence of Biological Nitritation Reaction on Various Immobilization Supports2013

    • Author(s)
      Hirohito YAMASAKI, Munetaka NEGORO, Akihiko MIYAKOSHI, Kimitoshi FUKUNAGA
    • Organizer
      The 15th Asian Chemical Congress, Chemistry at the Centre of Molecular Science & Nanotechnology
    • Place of Presentation
      Resorts World Sentosa, Singapore
    • Related Report
      2012 Research-status Report
  • [Presentation] 生物反応由来の高濃度亜硝酸を用いた水熱反応による高濃度排アンモニア除去2012

    • Author(s)
      原田 諭,山﨑博人,根來宗孝,宮越昭彦
    • Organizer
      第12回環境技術学会研究発表大会
    • Place of Presentation
      立命館大学
    • Year and Date
      2012-09-03
    • Related Report
      2013 Final Research Report
  • [Presentation] 生物反応と水熱反応を組み合わせた高濃度排アンモニアの消滅型除去2012

    • Author(s)
      原田 諭,吉屋愛恵,竹内正美,山﨑博人
    • Organizer
      第14回化学工学会学生発表会宇部大会(西日本地区)
    • Place of Presentation
      宇部高専
    • Year and Date
      2012-03-03
    • Related Report
      2013 Final Research Report
  • [Presentation] High-concentration nitrogen removal in industrial wastewater by subcritical hydrothermal reaction without catalyst2012

    • Author(s)
      H. Yamasaki, I. Yoshiya, M. Negoro, A. Miyakoshi
    • Organizer
      The 4^<th> International IUPAC Confer. on Green Chemistry
    • Place of Presentation
      Foz do Igua u(Brazil)
    • Related Report
      2013 Final Research Report
  • [Presentation] High-concentration nitrogen removal in industrial wastewater by subcritical hydrothermal reaction without catalyst2012

    • Author(s)
      Hirohito YAMASAKI, Itoe YOSHIYA, Munetaka NEGORO, Akihiko MIYAKOSHI
    • Organizer
      The 4th International IUPAC Conference on Green Chemistry
    • Place of Presentation
      Foz do Igua&#231;u, Brazil
    • Related Report
      2012 Research-status Report
  • [Presentation] 生物反応と水熱反応を組み合わせた高濃度排アンモニアの消滅型除去2012

    • Author(s)
      原田 諭
    • Organizer
      第14回化学工学会学生発表会宇部大会(西日本地区)
    • Place of Presentation
      宇部工業高等専門学校
    • Related Report
      2011 Research-status Report
  • [Presentation] 亜硝酸化生物処理と亜臨界水熱処理を組み合わせた高濃度排アンモニアの消滅型除去2011

    • Author(s)
      吉屋愛恵,山﨑博人,竹内正美
    • Organizer
      第11回環境技術学会研究発表会
    • Place of Presentation
      大阪工業大学
    • Year and Date
      2011-09-05
    • Related Report
      2013 Final Research Report
  • [Presentation] 生物反応と水熱反応による高濃度アンモニア成分の除去2011

    • Author(s)
      原田 諭,吉屋愛恵,竹内正美,山﨑博人
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Final Research Report 2011 Research-status Report
  • [Presentation] Treatment of super-high-concentration ammonium wastewater with immobilized nitrifying bacteria2011

    • Author(s)
      H. Yamasaki, M. Takeuchi, K. Fukunaga
    • Organizer
      4^<th> European Conference on Chemistry for Life Sciences
    • Place of Presentation
      Budapest(Hungary)
    • Related Report
      2013 Final Research Report
  • [Presentation] Treatment of super-high-concentration ammonium wastewater with immobilized nitrifying bacteria: Microbial ecology of immobilized nitrifying bacteria2011

    • Author(s)
      Hirohito YAMASAKI
    • Organizer
      4th European Conference on Chemistry for Life Sciences
    • Place of Presentation
      Budapest(Hungary)
    • Related Report
      2011 Research-status Report
  • [Presentation] 亜硝酸化生物処理と亜臨界水熱処理を組み合わせた高濃度排アンモニアの消滅型除去2011

    • Author(s)
      吉屋愛恵
    • Organizer
      第11回環境技術学会研究発表大会
    • Place of Presentation
      大阪工業大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 生物反応由来の高濃度亜硝酸を用いた水熱反応による高濃度排アンモニア除去

    • Author(s)
      原田 諭,山﨑博人,根來宗孝,宮越昭彦
    • Organizer
      第12回環境技術学会研究発表大会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] 窒素含有排水の亜硝酸型硝化処理方法及び処理装置2012

    • Inventor(s)
      鬼頭佑典,榊原隆司,山崎博人,根來宗孝
    • Industrial Property Rights Holder
      パナソニック株式会社,独立行政法人国立高等専門学校機構
    • Industrial Property Rights Type
      特許
    • Patent Publication Number
      2013-226491
    • Filing Date
      2012-04-24
    • Related Report
      2013 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 窒素含有排水の亜硝酸型硝化処理方法及び処理装置2012

    • Inventor(s)
      鬼頭佑典、榊原隆司、山崎博人、根來宗孝
    • Industrial Property Rights Holder
      パナソニック株式会社、独立行政法人国立高等専門学校機構
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-099211
    • Filing Date
      2012-04-24
    • Related Report
      2012 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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