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Synthesis of percolative ZnO quantum-dot superlattices

Research Project

Project/Area Number 23510130
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionOsaka University

Principal Investigator

TOYAMA Toshihiko  大阪大学, 工学(系)研究科(研究院), 特任准教授 (10294159)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsナノ材料創製 / パーコレーティブ伝導 / 液相合成 / 量子ドット超格子 / コア/シェル構造 / 酸化亜鉛 / 酸化マグネシウム / パーコレーション転移
Research Abstract

We have studied percolative (P-) quantum-dot superlattices (QDSLs) based on the percolation threshold for the formation of QDSLs that are suitable for solution-based fabrication processes. Cross-sectional transmission-electron-microscope measurements revealed the presence of ZnO cores with a mean radius of 2.5 nm that were densely and nearly mono-dispersed in the printed emission layer (EML). Elemental analysis indicated the presence of Mg elements locally around the ZnO cores, suggesting the formation of MgO shells. The blue shifts observed in the transmittance and photoluminescence spectra indicated band gap widening induced by quantum confinement effects. From analysis of the current versus voltage and current versus light intensity characteristics, the formation of the percolative current paths was indicated. Consequently, the structural and optical studies of the EML and the device performance of the light-emitting device demonstrate that the formation of P-QDSLs is possible.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (10 results)

All 2014 2012 2011

All Journal Article (5 results) (of which Peer Reviewed: 1 results) Presentation (4 results) Book (1 results)

  • [Journal Article] Optical Absorption Spectra of P-type Tin Monoxide Thin Films around Their Indirect Fundamental Gaps Determined Using Photothermal Deflection Spectroscopy2014

    • Author(s)
      Toshihiko Toyama, Yuichi Seo, Takafumi Konishi, Hiroaki Okamoto, Ryohei Morimoto, Yuichi Nishikawa, and Yasuo Tsutsumi
    • Journal Title

      Thin Solid Films

      Volume: 555 Pages: 148-152

    • Related Report
      2013 Final Research Report
  • [Journal Article] Optical Absorption Spectra of P-type Tin Monoxide Thin Films around Their Indirect Fundamental Gaps Determined Using Photothermal Deflection Spectroscopy2014

    • Author(s)
      Toshihiko Toyama, Yuichi Seo, Takafumi Konishi, Hiroaki Okamoto, Ryohei Morimoto, Yuichi Nishikawa, and Yasuo Tsutsumi
    • Journal Title

      Thin Film Solids

      Volume: 555 Pages: 148-152

    • DOI

      10.1016/j.tsf.2013.05.141

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of percolative quantum dot superlattice for printed light emitting device2012

    • Author(s)
      Toshihiko Toyama, Kazuki Itatani, and Hiroaki Okamoto
    • Journal Title

      physica status solidi (c)

      Volume: 9 Pages: 2541-2544

    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Journal Article] Top-Emission Ultraviolet-Light-Emitting Diodes Containing Solution-Processed ZnO Nanocrystals2011

    • Author(s)
      Toshihiko Toyama, Hayato Kawasaki, Kazuki Itatani, and Hiroaki Okamoto
    • Journal Title

      Applied Physics Express

      Volume: 4

    • NAID

      10029000658

    • Related Report
      2013 Final Research Report 2011 Research-status Report
  • [Journal Article] Physical Properties of p-Type Tin Monoxide Films Deposited at Low Temperature by Radio Frequency Magnetron Sputtering2011

    • Author(s)
      Toshihiko Toyama, Yuichi Seo, Takafumi Konishi, Hiroaki Okamoto, and Yasuo Tsutsumi
    • Journal Title

      Applied Physics Express

      Volume: 4

    • NAID

      10029239264

    • Related Report
      2013 Final Research Report 2011 Research-status Report
  • [Presentation] Preparation of percolative quantum dot superlattice for printed light emitting device2012

    • Author(s)
      Toshihiko Toyama, Kazuki Itatani, and Hiroaki Okamoto
    • Organizer
      The 5th International Conference on Optical, Optoelectronic and Photonic Materials and Applications (ICOOPMA12)
    • Place of Presentation
      Nara, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Optical Absorption Spectra of P-type Tin Monoxide Thin Films around Their Indirect Fundamental Gaps Determined Using Photothermal Deflection Spectroscopy2012

    • Author(s)
      Toshihiko Toyama, Yuichi Seo, Takafumi Konishi, Hiroaki Okamoto, Ryohei Morimoto, Yuichi Nishikawa, and Yasuo Tsutsumi
    • Organizer
      The 4th International Symposium on Transparent Conductive Materials (TCM2012)
    • Place of Presentation
      Hersonissos, Crete, Greece
    • Related Report
      2013 Final Research Report
  • [Presentation] Printed Electroluminescent Devices Containing Solution-Processed Zinc-Based Inorganic-Semiconductor Nanocrystals2011

    • Author(s)
      Toshihiko Toyama
    • Organizer
      BIT's 1st Annual World Congress of Nano-S & T-2011
    • Place of Presentation
      Dalian, China
    • Related Report
      2013 Final Research Report
  • [Presentation] Printed Electroluminescent Devices Containing Solution-Processed Zinc-Based Inorganic-Semiconductor Nanocrystals2011

    • Author(s)
      Toshihiko Toyama
    • Organizer
      BIT’s 1st Annual World Congress of Nano-S&T-2011(招待講演)
    • Place of Presentation
      Dalian, China
    • Related Report
      2011 Research-status Report
  • [Book] 「ナノ蛍光体のELデバイスへの応用」、ナノ蛍光体の開発と応用(普及版)、磯辺徹彦監修, 第4章1節2012

    • Author(s)
      安立 大輔, 外山 利彦
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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