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Investigation of catalytic characteristics of metal nano-particles using in situ observation techniques.

Research Project

Project/Area Number 23510149
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Microdevices/Nanodevices
Research InstitutionHiroshima University

Principal Investigator

Galif Kutlk  広島大学, 放射光科学研究センター, 特任准教授 (00444711)

Project Period (FY) 2011-04-28 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2015: ¥130,000 (Direct Cost: ¥100,000、Indirect Cost: ¥30,000)
Fiscal Year 2014: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2013: ¥130,000 (Direct Cost: ¥100,000、Indirect Cost: ¥30,000)
Fiscal Year 2012: ¥260,000 (Direct Cost: ¥200,000、Indirect Cost: ¥60,000)
Fiscal Year 2011: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Keywordsナノ粒子 / 電子分光 / 走査トンネル顕微鏡 / 局在電子 / 薄膜 / 光電子分光 / ナノ触媒 / 金属クラスター / 希土類金属 / 電子構造 / 逆光電子分光 / STM / 金属ナノ粒子 / 表面・界面 / STM STS / graphite / 表面・界面物性 / 表面物性
Outline of Final Research Achievements

Structure of Sm nano particle was measured by scanning tunneling microscopy (STM). While Sm nano particle less than 0.2nm shows nonmetallic characteristics, the particle greater than 0.3nm shows metallic characteristics in the STS spectrum. For Sm bulk crystal the its d,f electronic states near the Fermi level have empty states, these empty states on the Fermi level is not observed in the nano particle. We have observed the localized electronic states are sensitive to the change of local atomic structures.

Report

(6 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (12 results)

All 2016 2014 2013 2012

All Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results) Presentation (10 results)

  • [Journal Article] Metal-semiconductor transition concomitant with a structural transformation in tetrahedrite Cu12Sb4S132016

    • Author(s)
      H. I. Tanaka, K. Suekuni, K. Umeo, T. Nagasaki, H. Sato, G. Kutluk, E. Nishibori, H. Kasai, T. Takabatake
    • Journal Title

      Journal of Physical Society of Japan

      Volume: 85 Issue: 1 Pages: 014703-014703

    • DOI

      10.7566/jpsj.85.014703

    • NAID

      210000133804

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] VUV light induced valence degeneration in Sm over-layer on HOPG2013

    • Author(s)
      G. Kutluk, M. Nakatake, M.Arita, Y. Ishitobi, H. Sumida, H. Namatame, M. Taniguchi
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 425 Issue: 13 Pages: 1320071-1320074

    • DOI

      10.1088/1742-6596/425/13/132007

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Electronic properties of Sm nanostructure2014

    • Author(s)
      G. Kutluk1, M. Nakatake1, M. Ye1,3, M. Arita1, H. Sumida2, Y. Kooda2, H. Namatame1, M. Taniguchi1
    • Organizer
      The 7th International Symposium on Surface Science (ISSS-7)
    • Place of Presentation
      Matsue, Japan
    • Year and Date
      2014-11-02 – 2014-11-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Electronic property of Li overlayer on graphite2014

    • Author(s)
      G. Kutluk1, M. Nakatake1, M.Arita1, H. Sumida2, Y. Kooda, H. Namatame1, M. Taniguchi1
    • Organizer
      European conference on surface science (ECOSS30)
    • Place of Presentation
      Antalya, Turky
    • Year and Date
      2014-08-31 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] Electronic property of Li overlayer on graphite2014

    • Author(s)
      G. Kutluk, M. Nakatake, M.Arita, H. Sumida, H. Namatame, M. Taniguchi
    • Organizer
      The 18th Hiroshima international symposium on synchrotron radiation
    • Place of Presentation
      広島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Selective synthesis of CuS and Cu2S thin films and S K-edge XAFS characterization2014

    • Author(s)
      Toma Takiguchi, Tomoe Tahara, Naoki Noguchi, Galif Kutluk, Hirofumi Namatame and Shinjiro Hayakawa
    • Organizer
      The 18th Hiroshima international symposium on synchrotron radiation
    • Place of Presentation
      広島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] In-situ XAFS measurements of lithium secondary batteries with lithium titanium oxide negative active material2014

    • Author(s)
      Shinjiro Hayakawa, Susumu Mineoi, Hirosuke Sumida, Kenjiro Momosaki,Galif Kutluk and Hirofumi Namatame
    • Organizer
      The 18th Hiroshima international symposium on synchrotron radiation
    • Place of Presentation
      広島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] HOPG上に形成したLi 薄膜の電子構造2013

    • Author(s)
      アーリップ クトウルク,仲武昌史,有田将司,生天目博文,谷口雅樹
    • Organizer
      日本放射光学会
    • Place of Presentation
      名古屋大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Electronic properties of Sm nanostructure2013

    • Author(s)
      G. Kutluk, M. Nakatake, M. Ye, M.Arita, H. Sumida, H. Namatame, M. Taniguchi
    • Organizer
      The 17th Hiroshima international symposium on synchrotron radiation
    • Place of Presentation
      Hiroshima university
    • Related Report
      2012 Research-status Report
  • [Presentation] HOPG上に形成したLi 薄膜の電子構造2013

    • Author(s)
      アーリップ クトウルク,仲武昌史,有田将司,生天目博文,谷口雅樹
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Research-status Report
  • [Presentation] VUV light induced valence degeneration in Sm over-layer on HOPG2012

    • Author(s)
      G. Kutluk, M. Nakatake, M.Arita, Y. Ishitobi, H. Sumida, H. Namatame, M. Taniguchi
    • Organizer
      11th International Conference on Synchrotron Radiation Instrumentation (SRI 2012)
    • Place of Presentation
      Lyon, France
    • Related Report
      2012 Research-status Report
  • [Presentation] HOPG上に形成したLi 薄膜の電子構造2012

    • Author(s)
      アーリップ クトウルク,仲武昌史,有田将司,住田 弘、生天目博文,谷口雅樹
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      松山大学 愛媛大学
    • Related Report
      2012 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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