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Ultrafast dynamics of valence holes in photo-excited semiconductors studied by femtosecond time-resolved photoelectron spectroscopy

Research Project

Project/Area Number 23540366
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics I
Research InstitutionOsaka University

Principal Investigator

KANASAKI Jun'ichi  大阪大学, 産業科学研究所, 准教授 (80204535)

Co-Investigator(Kenkyū-buntansha) TANAKA Shin-ichiro  大阪大学, 産業科学研究所, 准教授 (00227141)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords半導体 / キャリア動力学 / 時間分解光電子分光 / 正孔 / 励起電子 / フェムト秒レーザー / 超高速現象 / 角度分解フェムト秒2光子光電子分光 / 非平衡キャリア / 多体効果 / フェルミ縮退 / 電子・フォノン散乱 / グラファイト
Research Abstract

Ultrafast dynamics of photo-generated non-equilibrium carriers (excited electrons in the conduction band and holes in the valence band) in typical semiconductors has been studied by femtosecond time-resolved photoelectron spectroscopy. We successfully observed time-evolution of carrier populations, in the energy (E) and momentum (k) space, and determined the fundamental scattering processes that govern the carrier relaxation. We have determined directly the rates of intervalley scatterings and carrier thermalization times of excited electrons. Also, in order to derive direct information on hole-dynamics in valence band, we have developed a new technique, one-photon photoelectron differential spectroscopy, where the difference in the photoelectron images with and without pump excitation is acquired. By using this technique, we have obtained first the direct information on ultrafast relaxation in silicons of photo-generated holes and the transition between bulk and surface states.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (62 results)

All 2014 2013 2012 2011 Other

All Journal Article (15 results) (of which Peer Reviewed: 14 results) Presentation (47 results) (of which Invited: 7 results)

  • [Journal Article] Crucial Roles of Holes in Electronic Bond Rupture on Semiconductor Surfaces2014

    • Author(s)
      J. Tsuruta, E. Inami, J. Kanasaki, K. Tanimura
    • Journal Title

      Surface Science

      Volume: 印刷中 Pages: 49-52

    • DOI

      10.1016/j.susc.2014.04.003

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast electron dynamics in photo-excited semiconductors studied by time- and angle-resolved two-photon photoelectron spectroscopy2014

    • Author(s)
      J. Kanasaki
    • Journal Title

      Proceedings of Conference on Lasers and Electro-Optics (CLEO-2014)

      Volume: 印刷中

    • Related Report
      2013 Annual Research Report
  • [Journal Article] An Investigation of Electron-Phonon Coupling via Phonon Dispersion Measurements in Graphite Using Angle-Resolved Photoelectron Spectroscopy2013

    • Author(s)
      S. Tanaka, M. Matsunami, S. Kimura
    • Journal Title

      Scientific Reports

      Volume: 3 巻

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] An investigation of electron-phonon coupling via phonon dispersion measurements in graphite using angle-resolved photoelectron spectroscopy2013

    • Author(s)
      S. Tanaka, M. Matsunami, S. Kimura
    • Journal Title

      Scientific Reports

      Volume: 3

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Capture of the Hot Electron by the Surface Defects on the Si(001) Surface2012

    • Author(s)
      S. Tanaka
    • Journal Title

      Surface Science

      Volume: 606 巻 Pages: 407-413

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Utility and constraint on the use of pump-probe photoelectron spectroscopy for detecting time-resolved surface photovoltage2012

    • Author(s)
      S. Tanaka
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: 185 Pages: 152-158

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Capture of the Hot Electron by the Surface Defects on the Si(001) Surface2012

    • Author(s)
      Shin-ichiro Tanaka
    • Journal Title

      Surface Science

      Volume: 606 Pages: 407-413

    • Related Report
      2012 Research-status Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] The role of applied bias and tip electronic structure in the Scanning Tunneling Microscopy imaging of highly oriented pyrolytic graphite2012

    • Author(s)
      G. Teobaldi, E. Inami, J. Kanasaki, K. Tanimura, A. L. Shluger
    • Journal Title

      Physical Review B

      Volume: 85

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ultrafast relaxation of highly excited electrons in Si : Roles of the L-X intervalley scattering2011

    • Author(s)
      T. Ichibayashi, S. Tanaka, J. Kanasaki, K. Tanimura, Th. Fauster
    • Journal Title

      Phys. Rev. B

      Volume: 84 Issue: 23 Pages: 235210-11

    • DOI

      10.1103/physrevb.84.235210

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Scanning tunneling microscopic studies of laser-induced modifications of Si(001)-(2x1) surface2011

    • Author(s)
      K. Yasui, J. Kanasaki
    • Journal Title

      Journal ofApplied Physics

      Volume: 110 巻 Issue: 10

    • DOI

      10.1063/1.3662120

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intact-sheet double-layer ablation induced by femtosecond-laser excitation of graphite2011

    • Author(s)
      Ohnishi, E. Inami, J. Kanasaki
    • Journal Title

      Surface Science

      Volume: 605 Pages: 1494-1499

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Scanning tunneling microscopic studies of laser-induced modifications of Si(001)-(2x1) surface2011

    • Author(s)
      K. Yasui, J. Kanasaki
    • Journal Title

      Journal of Applied Physics

      Volume: 110

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ultrafast relaxation of highly excited hot electrons in Si: Roles of the L-X intervalley scattering2011

    • Author(s)
      T. Ichibayashi, S. Tanaka, J. Kanasaki, K. Tanimura, T. Fauster
    • Journal Title

      Physical Review B

      Volume: 84

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Observation of anomalous peaks in the photoelectron spectra of highly oriented pyrolytic graphite: Folding of the band due to the surface charge density wave transition2011

    • Author(s)
      S. Tanaka, M. Matsunami, S. Kimura
    • Journal Title

      Physical Review B

      Volume: 84

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Unoccupied dimer-bond state at Si(001) surfaces2011

    • Author(s)
      T. Fauster, S. Tanaka, K. Tanimura
    • Journal Title

      Physical Review B

      Volume: 84

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 時間分解光電子分光法による非平衡キャリア動力学2014

    • Author(s)
      金崎順一
    • Organizer
      日本物理学会第69回年次大会領域5, 4, 6合同シンポジウム「限界駆動の物質光科学」
    • Place of Presentation
      東海大学(神奈川県平塚市)
    • Year and Date
      2014-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Ultrafast electron dynamics in photo-excited semiconductors studied by time- and angle-resolved two-photon photoelectron spectroscopy2014

    • Author(s)
      J. Kanasaki
    • Organizer
      International Conference on Lasers and Electro-Optics (CLEO-2014)
    • Place of Presentation
      San Jose, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 時間分解光電子分光法による非平衡キャリア動力学2014

    • Author(s)
      金崎 順一
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] GaAsにおける励起電子の超高速intervalley scattering2014

    • Author(s)
      谷村克己、金﨑順一
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 半導体における光生成非平衡キャリアの超高速動力学:エネルギー緩和速度の励起強度依存性2014

    • Author(s)
      金崎順一、谷村克己
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 半導体中の高励起電子状態の超高速緩和過程II2014

    • Author(s)
      谷村洋、金﨑順一、谷村克己
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 角度積分型光電子分光は何を見ているのか?:グラファイトにおける第一原理計算と実験の比較2014

    • Author(s)
      田中慎一郎
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 角度積分型光電子分光は何を見ているのか?:グラファイトにおける第一原理計算と実験の比較2014

    • Author(s)
      田中慎一郎
    • Organizer
      物構研サイエンスフェスタ2013
    • Place of Presentation
      筑波
    • Related Report
      2013 Annual Research Report
  • [Presentation] New aspects of the angle-resolved photoelectron spectroscopy:2014

    • Author(s)
      S. Tanaka
    • Organizer
      The 18th Hiroshima International Symposium on Synchrotron Radiation
    • Place of Presentation
      広島大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] グラファイトの 2 次電子ピークの起源:2次電子・光電子コインシデンス分光の試み2014

    • Author(s)
      田中慎一郎
    • Organizer
      日本放射光学会 学術講演大会
    • Place of Presentation
      広島国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] 角度分解光電子分光による電子・フォノン散乱過程の直接観察:運動量依存性2014

    • Author(s)
      田中慎一、松波雅治、木村真一
    • Organizer
      日本放射光学会 学術講演大会
    • Place of Presentation
      広島国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] グラファイトにおける低エネルギー角度分解光電子分光, UVSORシンポジウム2013

    • Author(s)
      田中慎一郎
    • Organizer
      自然科学研究機構岡崎コンファレンスセンター
    • Place of Presentation
      愛知県岡崎市
    • Year and Date
      2013-12-07
    • Related Report
      2013 Final Research Report
  • [Presentation] グラファイトにおける低エネルギー角度分解光電子分光2013

    • Author(s)
      田中慎一郎
    • Organizer
      UVSORシンポジウム
    • Place of Presentation
      UVSOR, 岡崎
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 直接遷移型半導体における超高速キャリア動力学:フェムト秒時間分解光電子分光IV2013

    • Author(s)
      金﨑順一、谷村克己
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 半導体中の高励起電子状態の超高速緩和過程2013

    • Author(s)
      谷村洋、金﨑順一、谷村克己
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 角度分解光電子分光による単結晶グラファイトフォノン分散の観測2013

    • Author(s)
      田中慎一郎
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ultrafast electron dynamics in photo-excited GaAs studied by time- and angle-resolved two photon photoelectron spexctroscopy2013

    • Author(s)
      J. Kanasaki
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      Doshisha University, Kyoto
    • Related Report
      2013 Annual Research Report
  • [Presentation] Electron-phonon coupling investigation via phonon dispersion measurement in graphite by angle-resolved photoelectron spectroscopy2013

    • Author(s)
      S. Tanaka
    • Organizer
      Advanced Spectroscopy of Correlated Materials (A satellite meeting of SCES2013)
    • Place of Presentation
      Okazaki, Aichi
    • Related Report
      2013 Annual Research Report
  • [Presentation] Direct Observation of the Electron-Phonon Scattering in Graphite by Using the Angle-Resolved Photoelectron Spectroscopy2013

    • Author(s)
      S. Tanaka
    • Organizer
      The 12th Asia Pacific Physics Conference(APPC12)
    • Place of Presentation
      Makuhari, Chiba
    • Related Report
      2013 Annual Research Report
  • [Presentation] Imaging energy- and momentum-resolved distributions of photoinjected hot electrons in GaAs2013

    • Author(s)
      J. Kanasaki, K. Tanimura
    • Organizer
      8th Conference on Ultrafast surface dynamics
    • Place of Presentation
      Colrado, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ultrafast Relaxation of Highly Excited Hot Electrons in Semiconductors2013

    • Author(s)
      H. Tanimura, J. Kanasaki, K. Tanimura
    • Organizer
      8th Conference on Ultrafast surface dynamics
    • Place of Presentation
      Colorado, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] 直接遷移型半導体における超高速キャリア動力学:フェムト秒時間分解光電子分光 III2013

    • Author(s)
      金崎順一、谷村克己
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 半導体における超高速緩和動力学フェムト秒2光子光電子分光による多次元イメージング2012

    • Author(s)
      金崎順一
    • Organizer
      Cat-on-Cat新規表面反応研究センターシンポジウム2012
    • Place of Presentation
      兵庫県立先端科学技術支援センター
    • Year and Date
      2012-12-07
    • Related Report
      2013 Final Research Report
  • [Presentation] Photo-Induced Structural Instability Driven by Inttrinsic Carrier Localization on Covalent Semiconductor Surfaces2012

    • Author(s)
      J. Kanasaki
    • Organizer
      13 th International Workshop on Desorption and Dynamics Induced by Electronic Transitions(DIET XIII)
    • Place of Presentation
      Stradford-upon-Avon, UK
    • Year and Date
      2012-07-04
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 共有結合性半導体表面における光誘起構造変化-キャリア局在による構造不安定性-2012

    • Author(s)
      金崎順一
    • Organizer
      九州表面・真空研究会2012(兼第17回九州薄膜表面研究会)
    • Place of Presentation
      佐賀県立九州シンクロトロン光研究センター, (佐賀県, 鳥栖市)
    • Year and Date
      2012-06-09
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] グラファイトからの2次電子放出機構の再検討2012

    • Author(s)
      田中慎一郎,松波雅治,木村真一
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 半導体における超高速キャリア緩和過程と多次元イメージング2012

    • Author(s)
      金崎順一
    • Organizer
      励起ナノプロセス研究会
    • Place of Presentation
      大阪大学中之島センター
    • Related Report
      2012 Research-status Report
  • [Presentation] 半導体における超高速キャリア動力学 ーフェムト秒2光子光電子分光による多次元イメージングー2012

    • Author(s)
      金崎順一
    • Organizer
      Cat-on-Cat新規表面反応研究センターシンポジウム2012
    • Place of Presentation
      兵庫県立大学
    • Related Report
      2012 Research-status Report
  • [Presentation] フェムト秒時間分解光電子分光法による半導体表面・界面における超高速キャリア動力学の研究2012

    • Author(s)
      金崎順一
    • Organizer
      ナノマクロ物質・デバイス・システム創製アライアンス プロジェクトグループ研究会
    • Place of Presentation
      九州大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 直接遷移型半導体における超高速キャリア動力学: フェムト秒時間分解光電子分光 I2012

    • Author(s)
      金崎順一、谷村克己
    • Organizer
      日本物理学会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 直接遷移型半導体における超高速キャリア動力学: フェムト秒時間分解光電子分光 II2012

    • Author(s)
      金崎順一、谷村克己
    • Organizer
      日本物理学会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 光電子分光によるグラファイトの電子フォノン散乱過程の直接観察2012

    • Author(s)
      田中慎一郎,松波雅治,木村真一
    • Organizer
      日本物理学会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Laser-Induced Bond Rupture and Structural Modifications of Si(001)-(2x1) Surface2012

    • Author(s)
      J. Kanasak, K. Yasui
    • Organizer
      International Union of Material Research Society & International Conference on Elexctronic Materials
    • Place of Presentation
      パシフィコ横浜, 神奈川
    • Related Report
      2012 Research-status Report
  • [Presentation] The Surface Bond Rupture on InP(110)-(1x1) Induced by Hole Injection from the STM Tips2012

    • Author(s)
      J. Kanasaki , E. Inami, J. Tsuruta, and K. Tanimura
    • Organizer
      International Union of Material Research Society & International Conference on Elexctronic Materials
    • Place of Presentation
      パシフィコ横浜、神奈川
    • Related Report
      2012 Research-status Report
  • [Presentation] photo-induced structural instability driven by intrinsic carrier localization on covalent semiconductor surfaces2012

    • Author(s)
      J. Kanasaki
    • Organizer
      13th International Workshop on Desorptionand Dynamics Induced by Electronic Transitions (DIET XIII)
    • Place of Presentation
      Stradford, UK
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Laser-induced structural changes and phase transition on covalently bonded surfaces2012

    • Author(s)
      J. Kanasaki
    • Organizer
      2012 Material Research Society (MRS) Spring Meting
    • Place of Presentation
      San Francisco, USA
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] フェムト秒時間分解光電子分光による半導体価電子正孔系の超高速動力学2012

    • Author(s)
      金崎順一、谷村克己
    • Organizer
      日本物理学会
    • Place of Presentation
      関西学院大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Angle-resolved Constant Initial State 分光によるHOPGの非占有軌道のマッピング2012

    • Author(s)
      田中慎一郎
    • Organizer
      日本物理学会
    • Place of Presentation
      関西学院大学
    • Related Report
      2011 Research-status Report
  • [Presentation] フェムト秒時間分解光電子分光によるSi価電子正孔系の超高速動力学 II2011

    • Author(s)
      金崎順一、谷村克己
    • Organizer
      日本物理学会
    • Place of Presentation
      富山大学
    • Related Report
      2011 Research-status Report
  • [Presentation] HOPGの低エネルギー角度分解光電子分光2011

    • Author(s)
      田中慎一郎、松波雅治、木村真一
    • Organizer
      日本物理学会
    • Place of Presentation
      富山大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 励起パルス時間幅に依存するグラファイト光構造相転移の核形成過程2011

    • Author(s)
      稲見栄一、金崎順一、谷村克己
    • Organizer
      日本物理学会
    • Place of Presentation
      富山大学
    • Related Report
      2011 Research-status Report
  • [Presentation] フェムト秒光励起によるグラファイト表面構造相転移2011

    • Author(s)
      稲見栄一、金崎順一、谷村克己
    • Organizer
      励起ナノプロセス研究会
    • Place of Presentation
      ビッグ・アイ 国際障害者交流センター(大阪府)
    • Related Report
      2011 Research-status Report
  • [Presentation] Formation and Growth of interlayer sp3-bonded carbon nano-domains induced by femtosecond laser excitation of graphite2011

    • Author(s)
      E. Inami, J. Kanasaki, K. Tanimura
    • Organizer
      International Symposium on Surface Science - Towards Nano-, Bio-, and Green Innovation -
    • Place of Presentation
      Tower Hall Funabori, Funabori, Tokyo, Japan
    • Related Report
      2011 Research-status Report
  • [Presentation] Laser-induced modifications of Si(001)-(2x1) surface studied by means of Scanning Tunneling Microscope2011

    • Author(s)
      J. Kanasaki, K. Katoh, Y. Imanishi, K. Yasui
    • Organizer
      International Symposium on Surface Science - Towards Nano-, Bio-, and Green Innovation -
    • Place of Presentation
      Tower Hall Funabori, Funabori, Tokyo, Japan
    • Related Report
      2011 Research-status Report
  • [Presentation] Fs-laser induced exfoliation of intact graphene doubly-layers from graphite2011

    • Author(s)
      J. Kanasaki, H. Ohnishi, E. Inami, K. Tanimura, K. Nasu
    • Organizer
      International Symposium on Surface Science - Towards Nano-, Bio-, and Green Innovation -
    • Place of Presentation
      Tower Hall Funabori, Funabori, Tokyo, Japan
    • Related Report
      2011 Research-status Report
  • [Presentation] Angle-resolved low-energy photoemission study of electronic structureof Si(111)-7x72011

    • Author(s)
      J. Kanasaki, K. Tanimura, Y. Morikawa, T. Fauster
    • Organizer
      International Symposium on Surface Science - Towards Nano-, Bio-, and Green Innovation -
    • Place of Presentation
      Tower Hall Funabori, Funabori, Tokyo, Japan
    • Related Report
      2011 Research-status Report
  • [Presentation] 共有結合性半導体表面における光誘起構造変化-キャリア局在による構造不安定性-

    • Author(s)
      金崎順一
    • Organizer
      平成24 年度九州表面・真空研究会2012
    • Place of Presentation
      佐賀県立九州シンクロトロン光研究センター
    • Related Report
      2012 Research-status Report
    • Invited

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Published: 2011-08-05   Modified: 2020-05-15  

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