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Development of spin polarized metastable atom source and application of surface magnetic analysis

Research Project

Project/Area Number 23540387
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionThe University of Tokyo

Principal Investigator

AOKI Masaru  東京大学, 総合文化研究科, 助教 (50302823)

Co-Investigator(Renkei-kenkyūsha) MASUDA Shigeru  東京大学, 大学院・総合文化研究科, 教授 (50173745)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords準安定原子 / 電子分光 / 表面磁性 / 準安定励起原子 / スピン偏極
Research Abstract

Electronic properties of potassium-doped dibenzopentacene thin films were studied by electron spectroscopy method using herium metastable atom as a probe. The spectra for KxDBP (0 < x < 3.5) films show three types of gap state in the HOMO-LUMO gap of pristine DBP. The threshold of electron emission for K1DBP is located ~0.1 eV below the Fermi level with no metallic feature, suggesting that K1DBP is a Mott-Hubbard insulator. At the formation of K2DBP, the film has a wide-gap insulator. Upon further deposition of K, the new gap state appears near Fermi level and is attributed to partial electron filling in the LUMO+1~LUMO+3 states, however, the leading edge of the gap state is located ~0.1 eV below Fermi level without a metallic feature. Therefore, the heavily doped species transfers to a Mott-Hubbard insulator again. The gap state plays a key role in superconductivity of K3.5DBP at low temperature.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (35 results)

All 2014 2013 2012 2011 Other

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (29 results) Remarks (1 results)

  • [Journal Article] Chemisorption-induced gap states at organic-metal interfaces : benzenethiol and benzeneselenol on metal surfaces2012

    • Author(s)
      M. Aoki, T. Kamada, K. Sasaki, S. Masuda, Y. Morikawa
    • Journal Title

      Phys.Chem.Chem.Phys

      Volume: 14 巻 Pages: 4101-4108

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Loal eletroni properties at organi-metal interfaes : Thiophene deri:ati:es on Pt(111)2012

    • Author(s)
      H. Sato, S. Ushiyama, M. Sogo, M. Aoki, K. Shudo, T. Sugawara, S. Yanagisawa, Y. Morikawa, S. Masuda
    • Journal Title

      Phys.Chem.Chem.Phys

      Volume: 14 巻 Pages: 15229-15608

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local electronic properties at organic-metal interfaces: thiophene derivatives on Pt (III)2012

    • Author(s)
      H. Sato, S. Ushiyama , M. Sogo, M. Aoki, K-i. Shudo, T. Sugawara, S. Yanagisawa, Y. Morikawa, S. Masuda,
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 14 Issue: 44 Pages: 15412-15420

    • DOI

      10.1039/c2cp42700a

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Chemisorption-induced gap states at organic-metal interfaces: benzenethiol and benzeneselenol on metal surfaces2012

    • Author(s)
      M. Aoki et al.
    • Journal Title

      Phys.Chem.Chem.Phys.

      Volume: 14 Issue: 12 Pages: 4101-4108

    • DOI

      10.1039/c2cp23206e

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Local Electronic States Induced at Thiolate-Metal Interfaces2011

    • Author(s)
      M. Aoki et al.
    • Journal Title

      Proceedings of "8th International Symposium on Atomic Level Characterizations for New Materials and Devices ’11"

      Volume: 2011 Pages: 248-249

    • Related Report
      2011 Research-status Report
  • [Presentation] ジベンゾペンタセン薄膜のカリウム添加による価電子構造変化2014

    • Author(s)
      青木優, 増田茂, 他
    • Organizer
      物理学会第69回年次大会
    • Place of Presentation
      東海大学(平塚)
    • Year and Date
      2014-03-27
    • Related Report
      2013 Final Research Report
  • [Presentation] ジベンゾペンタセン薄膜のカリウム添加による価電子構造変化2014

    • Author(s)
      青木 優 等
    • Organizer
      物理学会第69回年次大会
    • Place of Presentation
      東海大学(平塚)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Au(111)基板上ジベンゾペンタセンの振動・電子構造2014

    • Author(s)
      鈴木 敦 等
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(名古屋)
    • Related Report
      2013 Annual Research Report
  • [Presentation] カリウム添加ジベンゾペンタセン薄膜におけるギャップ電子準位の生成機構2014

    • Author(s)
      佐藤博史 等
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(名古屋)
    • Related Report
      2013 Annual Research Report
  • [Presentation] カリウム添加ジベンゾペンタセンの価電子構造2013

    • Author(s)
      佐藤博史, 青木優, 増田茂, 他
    • Organizer
      第7回分子科学討論会
    • Year and Date
      2013-09-27
    • Related Report
      2013 Final Research Report
  • [Presentation] Fractal Growth of Au Thin Films: Observation by Photoemission Electron Microscope2013

    • Author(s)
      M. Aoki et al.
    • Organizer
      Electron Microscopy and Analysis Group Conference 2013
    • Place of Presentation
      University of York (York, UK)
    • Related Report
      2013 Annual Research Report
  • [Presentation] カリウム添加ジベンゾペンタセン薄膜の価電子構造2013

    • Author(s)
      佐藤博史 等
    • Organizer
      第7回分子科学討論会 2013京都
    • Place of Presentation
      京都テルサ(京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] PEEMによるSiO2/Si(100)上金薄膜の二次元フラクタルパタン観測2013

    • Author(s)
      山口哲広 等
    • Organizer
      第7回分子科学討論会 2013京都
    • Place of Presentation
      京都テルサ(京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] カリウム添加ジベンゾペンタセン薄膜の価電子構造2013

    • Author(s)
      三原識文 等
    • Organizer
      表面界面スペクトロスコピー2013
    • Place of Presentation
      東レ総合研修センター(三島)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Gap states in Cs-doped organic films on Au substrate : A combined spectroscopic and theoretial study2012

    • Author(s)
      佐藤博史, 青木優, 増田茂, 他
    • Organizer
      14th Vibrations at Surface
    • Place of Presentation
      Nichii-Gakkan(Kobe)
    • Year and Date
      2012-09-25
    • Related Report
      2013 Final Research Report
  • [Presentation] セシウムドープされた有機薄膜におけるギャップ準位のキャラクタリゼーション2012

    • Author(s)
      青木優, 増田茂, 他
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学本郷キャンパス(東京)
    • Year and Date
      2012-09-21
    • Related Report
      2013 Final Research Report
  • [Presentation] Local electronic properties at organic-metal interface : Thiophene derivatives on Pt(111)2012

    • Author(s)
      佐藤博史, 青木優, 増田茂, 他
    • Organizer
      ICESS2012
    • Place of Presentation
      Palais des Congres(Saint-Malo)
    • Year and Date
      2012-09-18
    • Related Report
      2013 Final Research Report
  • [Presentation] グラファイト上に担持された金クラスターの価電子状態2012

    • Author(s)
      佐野 光 等
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜市・慶應義塾大学日吉キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] チオフェン誘導体-Pt(111)接合系における化学吸着誘起準位2011

    • Author(s)
      佐藤博史, 青木優, 増田茂, 他
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(札幌市)
    • Year and Date
      2011-09-21
    • Related Report
      2013 Final Research Report
  • [Presentation] Local Electronic States Induced at Thiolate-Metal Interfaces2011

    • Author(s)
      青木優, 増田茂, 他
    • Organizer
      8th International Symposium on Atomic Level Characterizations for New Materials and Devices '11
    • Place of Presentation
      Olympic Parktel(ソウル市)
    • Year and Date
      2011-05-23
    • Related Report
      2013 Final Research Report
  • [Presentation] Local Electronic States Induced at Thiolate-Metal Interfaces2011

    • Author(s)
      青木 優 等
    • Organizer
      8th International Symposium on Atomic Level Characterizations for New Materials and Devices ’11
    • Place of Presentation
      ソウル市・Olympic Parktel
    • Related Report
      2011 Research-status Report
  • [Presentation] チオフェン誘導体-Pt(111)接合系における化学吸着誘起準位2011

    • Author(s)
      佐藤博史 等
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌市・札幌コンベンションセンター
    • Related Report
      2011 Research-status Report
  • [Presentation] イオン衝撃によるグラファイト表面の半金属-金属転移2011

    • Author(s)
      牛山翔太 等
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山市・富山大学五福キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] 大環状アルカン分子・極薄膜の電子分光2011

    • Author(s)
      松本圭司 等
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば市・つくば国際会議場
    • Related Report
      2011 Research-status Report
  • [Presentation] カリウム添加ジベンゾペンタセン薄膜におけるギャップ電子準位の生成機構

    • Author(s)
      佐藤博史, 青木優, 増田茂, 他
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(名古屋)
    • Related Report
      2013 Final Research Report
  • [Presentation] Local electronic properties at organic-metal interface: Thiophene derivatives on Pt(111)

    • Author(s)
      H. Sato et al.
    • Organizer
      ICESS2012
    • Place of Presentation
      Palais des Congres(Saint-Malo)
    • Related Report
      2012 Research-status Report
  • [Presentation] グラファイト上に担持された金クラスターの価電子状態

    • Author(s)
      佐野 光 等
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学本郷キャンパス(東京)
    • Related Report
      2012 Research-status Report
  • [Presentation] セシウムドープされた有機薄膜におけるギャップ準位のキャラクタリゼーション

    • Author(s)
      青木 優 等
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学本郷キャンパス(東京)
    • Related Report
      2012 Research-status Report
  • [Presentation] Valence electronic states of Au clusters supported on graphite

    • Author(s)
      H. Sano et al.
    • Organizer
      14th Vibrations at Surface
    • Place of Presentation
      Nichii-Gakkan(Kobe)
    • Related Report
      2012 Research-status Report
  • [Presentation] Gap states in Cs-doped organic films on Au substrate: A combined spectroscopic and theoretical study

    • Author(s)
      H. Sato et al.
    • Organizer
      14th Vibrations at Surface
    • Place of Presentation
      Nichii-Gakkan(Kobe)
    • Related Report
      2012 Research-status Report
  • [Presentation] グラファイト上金クラスターの清浄面とCO吸着面の価電子状態

    • Author(s)
      佐野 光 等
    • Organizer
      第6回表面界面スペクトロスコピー
    • Place of Presentation
      ホテル阪急エキスポパーク(吹田)
    • Related Report
      2012 Research-status Report
  • [Presentation] SiO2/Si(100)上Au蒸着膜のフラクタルパタン‐光電子放射顕微鏡による観測

    • Author(s)
      母袋雄也 等
    • Organizer
      第6回表面界面スペクトロスコピー
    • Place of Presentation
      ホテル阪急エキスポパーク(吹田)
    • Related Report
      2012 Research-status Report
  • [Presentation] グラファイト上金クラスターのCO吸着面の価電子状態

    • Author(s)
      佐野 光 等
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(草津)
    • Related Report
      2012 Research-status Report
  • [Presentation] 光電子放射顕微鏡によるSiO2/Si(100)上Au蒸着膜のフラクタルパタン

    • Author(s)
      山口哲広 等
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(草津)
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://maildbs.c.u-tokyo.ac.jp/~masuda/index.html

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2020-05-15  

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