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Establishment of photocarrier injection method by which electronic properties of strongly correlated materials can be controlled.

Research Project

Project/Area Number 23540410
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionOkayama University

Principal Investigator

MURAOKA Yuji  岡山大学, 自然科学研究科, 准教授 (10323635)

Co-Investigator(Renkei-kenkyūsha) YOKOYA Takayoshi  岡山大学, 大学院・自然科学研究科, 教授 (90311646)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords強相関系 / 界面 / VO2薄膜 / 軟X線照射 / 絶縁体金属転移 / TaO2 / 放射光照射 / 金属酸化物 / 光キャリア注入 / VO2 / 薄膜 / 放射光
Research Abstract

Photocarrier injection to transition metal oxide thin films and the electronic states of the films are investigated. We have observed an insulator-to-metal transition of VO2 thin films induced by soft X-ray irradiation. Electron carriers are injected into the V 3d band upon soft-X ray irradiation. We propose a simple model where the transition is driven by desorption of oxygen from the films. The Fermi surface topology of a metallic VO2 thin film is studied by angle-resolved photoemission spectroscopy (ARPES) and the nesting vector is found to be present. Near topmost layer of CrO2 thin films are revealed to be metallic by surface sensitive PES. Also, a single-phase TaO2 thin film and spinodally decomposed (V,Ti)O2 thin film are developed.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (52 results)

All 2014 2013 2012 2011 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (36 results) (of which Invited: 2 results) Remarks (3 results)

  • [Journal Article] Persistent insulator to metal transition of a VO2 thin film by soft x-ray irradiation2014

    • Author(s)
      Y. Muraoka, H. Nagao, S. Katayama, T. Wakita, M. Hirai, T. Yokoya, H. Kumigashira, and M. Oshima
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 53

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast photoinduced transition of an insulating VO2 thin film into a nonrutile metallic state2014

    • Author(s)
      R. Yoshida, T. Yamamoto, Y. Ishida, H. Nagao, T. Otsuka, K. Saeki, Y. Muraoka, R. Eguchi, K. Ishizaka, T. Kiss, S. Watanabe, T. Kanai, J. Itatani, and S. Shin
    • Journal Title

      Phys. Rev. B

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Persistent insulator to metal transition of a VO2 thin film by soft x-ray irradiation2014

    • Author(s)
      Y. Muraoka, H. Nagao, S. Katayama, T. Wakita, M. Hirai, T. Yokoya, H. Kumigashira, and M. Oshima
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast photoinduced transition of an insulating VO2 thin film into a nonrutile metallic state2014

    • Author(s)
      Rikiya Yoshida, Takashi Yamamoto, Yukiaki Ishida, Hiroki Nagao, Tsubasa Otsuka, Kuninari Saeki, Yuji Muraoka, Ritsuko Eguchi, Kyoko Ishizaka, Takayuki Kiss, Shuntaro Watanabe, Teruto Kanai, Jiro Itatani, and Shik Shin
    • Journal Title

      Phys. Rev. B

      Volume: in press

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spinodal decomposition in the TiO2-VO2 system2013

    • Author(s)
      Z. Hiroi, H. Hayamizu, T. Yoshida, Y. Muraoka, Y. Okamoto, J. Yamaura, and Y. Ueda
    • Journal Title

      Chem. Mater

      Volume: 25 Pages: 2202-2210

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spinodal decomposition in the TiO2-VO2 system2013

    • Author(s)
      Z. Hiroi, H. Hayamizu, T. Yoshida, Y. Muraoka, Y. Okamoto, J. Yamaura, and Y. Ueda
    • Journal Title

      Chem. Mater.

      Volume: 25 Pages: 2202-2210

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effectiveness of a hot-filament chemical vapor deposition method for preparation of a boron-doped superconducting diamond film with higher superconducting transition temperature2012

    • Author(s)
      T. Doi, T. Fukaishi, C. Hiramatsu, T. Wakita, M. Hirai, Y. Muraoka, T. Yokoya, Y. Kato, Y. Izumi, T. Muro, Y. Tamenori
    • Journal Title

      Diam. Relat. Mater.

      Volume: 25 Pages: 5-7

    • Related Report
      2012 Research-status Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Observation of two fine structures related to the hidden order in the spectral functions of URu2Si22012

    • Author(s)
      R. Yoshida, M. Fukui, Y. Haga, E. Yamamoto, Y. Onuki, M. Okawa, W. Malaeb,S. Shin, Y. Muraoka, and T. Yokoya
    • Journal Title

      Phys. Rev. B

      Volume: 85

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Comparative photoemission studies on the superconducting gap of the filled skutterudite superconductors LaPt4Ge12 and PrPt4Ge122012

    • Author(s)
      Y. Nakamura, H. Okazaki, R. Yoshida, T. Wakita, H. Takeya, K. Hirata, M. Hirai, Y. Muraoka, and T. Yokoya
    • Journal Title

      Phys. Rev. B

      Volume: 86

    • NAID

      120004724420

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Te concentration dependent photoemission and inverse-photoemission study of FeSe1-xTex2012

    • Author(s)
      T. Yokoya, Y. Muraoka et al.
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 13

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Surface physical property of the CrO2 thin films prepared using a closed chemical vapor deposition method, Materials Research Society online Proceedings library2011

    • Author(s)
      Y. Muraoka, S. Yoshida, T. Wakita, M. Hirai, T. Yokoya
    • Journal Title

      Function Metal-Oxide Nanostructures

      Volume: 1406

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic evidence of the formation of (V,Ti)O2 solid solution in VO2 thinner films grown on TiO2(001) substrates2011

    • Author(s)
      Y. Muraoka, K. Saeki, R. Eguchi, T. Wakita, M. Hirai, T. Yokoya, and S. Shin
    • Journal Title

      J. Appl. Phys.

      Volume: 109

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and physical properties of the hollandite-type titanium oxide KxTi8O162011

    • Author(s)
      Y. Muraoka, K. Noami, T. Wakita, M. Hirai, T. Yokoya, Y. Kato, T. Muro, and Y. Tamenori
    • Journal Title

      Phys.Status Solidi C

      Volume: 8 Pages: 555-557

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] VO2薄膜における軟X線誘起絶縁体金属転移2014

    • Author(s)
      村岡祐治, 長尾浩樹, 脇田高徳, 横谷尚睦, 組頭広志, 尾嶋正治
    • Organizer
      放射光科学による革新的イノベーションワークショップ
    • Place of Presentation
      岡山大学津島キャンパス
    • Year and Date
      2014-03-14
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] Spin-resolved Photoemission Spectroscopy of CrO2 thin films2014

    • Author(s)
      Y. Muraoka, M. Sunagawa, A. Mizutani, K. Miyamoto and T. Okuda
    • Organizer
      The 18th Hiroshima International Symposium on Synchrotron Radiation
    • Place of Presentation
      Hiroshima University
    • Year and Date
      2014-03-06
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocarrier injection to VO2 thin film2013

    • Author(s)
      Y. Muraoka, T. Wakita, and T. Yokoya
    • Organizer
      2013 JSAP-MRS joint symposia
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2013-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Photo-induced insulator to metal transition for VO2 thin films2013

    • Author(s)
      Y. Muraoka, H. Nagao, T. Wakita and T. Yokoya
    • Organizer
      The 17th Hiroshima International Symposium on Synchrotron Radiation
    • Place of Presentation
      Hiroshima University
    • Year and Date
      2013-02-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocarrier injection to VO2 thin films2013

    • Author(s)
      Yuji Muraoka, Takanori Wakita, and Takayoshi Yokoya
    • Organizer
      2013 JSAP-MRS joint symposia
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] VO2薄膜の金属相フェルミ面ネスティング2013

    • Author(s)
      村岡祐治、長尾浩樹、脇田高徳、横谷尚睦、組頭広志、尾嶋正治
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Photo-induced insulator to metal transition for VO2 thin films2013

    • Author(s)
      Y. Muraoka, H. Nagao, T. Wakita and T. Yokoya
    • Organizer
      The 17th Hiroshima International Symposium on Synchrotron Radiation
    • Place of Presentation
      Hiroshima Unversity, Hiroshima, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Surface physical property of the CrO2 thin films2012

    • Author(s)
      Y. Muraoka, S. Yoshida, T. Wakita, M. Hirai, T. Yokoya
    • Organizer
      International Symposium on Physics and Chemistry of Novel Superconductors and Related Materials
    • Place of Presentation
      岡山大学
    • Year and Date
      2012-10-02
    • Related Report
      2013 Final Research Report
  • [Presentation] VO2薄膜における光誘起絶縁体-金属転移とその電子状態の観測2012

    • Author(s)
      村岡祐治, 長尾浩樹, 脇田高徳, 横谷尚睦, 組頭広志, 尾嶋正治
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学常盤台キャンパス
    • Year and Date
      2012-09-20
    • Related Report
      2013 Final Research Report
  • [Presentation] Effectiveness of a closed CVD method for preparation of CrO2 thin films2012

    • Author(s)
      Y. Muraoka, S. Yoshida, T. Wakita, T. Yokoya, H. Kumugashira, and M. Oshima
    • Organizer
      2012年秋季第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学城北地区/松山大学文京キャンパス
    • Year and Date
      2012-09-12
    • Related Report
      2013 Final Research Report
  • [Presentation] CrO2単結晶薄膜作製における閉鎖系化学気相法の利点, 応用物理学会中国四国支部, 日本物理学会中国支部, 四国支部2012

    • Author(s)
      村岡祐治, 吉田祥, 脇田高徳, 横谷尚睦
    • Organizer
      2012年度支部学術講演会
    • Place of Presentation
      山口大学常盤キャンパス
    • Year and Date
      2012-07-28
    • Related Report
      2013 Final Research Report
  • [Presentation] VO2薄膜における放射光誘起絶縁体金属転移, 応用物理学会中国四国支部, 日本物理学会中国支部, 四国支部2012

    • Author(s)
      村岡祐治, 長尾浩樹, 脇田高徳, 横谷尚睦
    • Organizer
      2012年度支部学術講演会
    • Place of Presentation
      山口大学常盤キャンパス
    • Year and Date
      2012-07-28
    • Related Report
      2013 Final Research Report
  • [Presentation] 閉鎖系化学気相法により作製したCrO2薄膜の表面特性2012

    • Author(s)
      村岡祐治, 吉田祥, 脇田高徳, 平井正明, 横谷尚睦
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学西宮上ヶ原キャンパス
    • Year and Date
      2012-03-27
    • Related Report
      2013 Final Research Report
  • [Presentation] CrO2薄膜の表面特性2012

    • Author(s)
      村岡祐治, 吉田祥, 脇田高徳, 平井正明, 横谷尚睦
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学早稲田キャンパス
    • Year and Date
      2012-03-17
    • Related Report
      2013 Final Research Report
  • [Presentation] 光照射によるVO2薄膜への電子キャリア注入2012

    • Author(s)
      村岡祐治, 長尾浩樹, 大山卓郎, 脇田高徳, 平井正明, 横谷尚睦
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学早稲田キャンパス
    • Year and Date
      2012-03-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Metallic surface of the CrO2 thin films prepared using a closed chemical vapor deposition method2012

    • Author(s)
      Y. Muraoka, S. Yoshida, M. Hirai, T. Wakita and T. Yokoya
    • Organizer
      The 16th Hiroshima International Symposium on Synchrotron Radiation
    • Place of Presentation
      Hiroshima University
    • Year and Date
      2012-03-01
    • Related Report
      2013 Final Research Report
  • [Presentation] Surface physical property of the CrO2 thin films2012

    • Author(s)
      Y. Muraoka, S. Yoshida, T. Wakita, M. Hirai, T. Yokoya,
    • Organizer
      International Symposium on Physics and Chemistry of Novel Superconductors and Related Materials
    • Place of Presentation
      岡山大学理学部
    • Related Report
      2012 Research-status Report
  • [Presentation] VO2薄膜における光誘起 絶縁体-金属転移とその電子状態の観測2012

    • Author(s)
      村岡祐治、長尾浩樹、脇田高徳、横谷尚睦、組頭広志、尾嶋正治
    • Organizer
      日本物理学会 2012年秋季大会
    • Place of Presentation
      横浜国立大学常盤台キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Effectiveness of a closed CVD method for preparation of CrO2 thin films2012

    • Author(s)
      Y. Muraoka, S. Yoshida, T. Wakita, T. Yokoya, H. Kumugashira, and M. Oshima
    • Organizer
      2012年秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学城北地区/松山大学文京キャンパス
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] CrO2単結晶薄膜作製における閉鎖系化学気相法の利点2012

    • Author(s)
      村岡祐治、吉田祥、脇田高徳、横谷尚睦
    • Organizer
      応用物理学会中国四国支部、日本物理学会中国支部、四国支部、2012年度支部学術講演会
    • Place of Presentation
      山口大学常盤キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] VO2薄膜における放射光誘起絶縁体金属転移2012

    • Author(s)
      村岡祐治、長尾浩樹、脇田高徳、横谷尚睦
    • Organizer
      応用物理学会中国四国支部、日本物理学会中国支部、四国支部、2012年度支部学術講演会
    • Place of Presentation
      山口大学常盤キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] 閉鎖系化学気相法により作製したCrO2薄膜の表面特性2012

    • Author(s)
      村岡祐治,吉田祥,脇田高徳,平井正明,横谷尚睦
    • Organizer
      日本物理学会 第67回年次大会
    • Place of Presentation
      関西学院大学西宮上ヶ原キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] CrO2薄膜の表面特性2012

    • Author(s)
      村岡祐治, 吉田祥, 脇田高徳, 平井正明, 横谷尚睦
    • Organizer
      2012年春季 第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学 早稲田キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] 光照射によるVO2薄膜への電子キャリア注入2012

    • Author(s)
      村岡祐治, 長尾浩樹, 大山卓郎, 脇田高徳, 平井正明, 横谷尚睦
    • Organizer
      2012年春季 第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学 早稲田キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] Metallic surface of the CrO2 thin films prepared using a closed chemical vapor desposition method2012

    • Author(s)
      Y. Muraoka, S. Yoshida, M. Hirai, T. Wakita and T. Yokoya
    • Organizer
      The 16th Hiroshima International Symposium on Synchrotron Radiation
    • Place of Presentation
      Hiroshima Unversity
    • Related Report
      2011 Research-status Report
  • [Presentation] Surface physical property of the CrO2 thin films prepared using a closed chemical vapor deposition method2011

    • Author(s)
      Y. Muraoka, S. Yoshida, T. Wakita, M. Hirai, and T. Yokoya
    • Organizer
      2011 Fall Meeting of the Materials Research Society
    • Place of Presentation
      Hynes Convention Center, Boston, U.S.A
    • Year and Date
      2011-11-28
    • Related Report
      2013 Final Research Report
  • [Presentation] 放射光照射によるVO2薄膜への電子キャリア注入2011

    • Author(s)
      村岡祐治, 長尾浩樹, 脇田高徳, 平井正明, 横谷尚睦, 室隆桂之, 為則雄祐
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学五福キャンパス
    • Year and Date
      2011-09-21
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation of NbO2 thin films using a pulsed laser deposition method2011

    • Author(s)
      Y. Muraoka, Y. Fujimoto, C. Hiramatsu, T. Wakita, M. Hirai, T. Yokoya
    • Organizer
      2011年秋季第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Year and Date
      2011-08-31
    • Related Report
      2013 Final Research Report
  • [Presentation] VO2薄膜における放射光照射効果, 応用物理学会中国四国支部, 日本物理学会中国支部, 四国支部2011

    • Author(s)
      村岡祐治, 片山晋輔, 長尾浩樹, 脇田高徳, 平井正明, 横谷尚睦, 室隆桂之, 泉雄大, 為則雄祐
    • Organizer
      2011年度支部学術講演会
    • Place of Presentation
      鳥取大学鳥取キャンパス
    • Year and Date
      2011-07-30
    • Related Report
      2013 Final Research Report
  • [Presentation] Surface physical property of the CrO2 thin films prepared using a closed chemical vapor deposition method2011

    • Author(s)
      Y. Muraoka, S. Yoshida, T. Wakita, M. Hirai, and T. Yokoya
    • Organizer
      2011 Fall Meeting of the Materials Research Society
    • Place of Presentation
      Hynes Convention Center, Boston, U.S.A.
    • Related Report
      2011 Research-status Report
  • [Presentation] 放射光照射によるVO2薄膜への電子キャリア注入2011

    • Author(s)
      村岡祐治、長尾浩樹、脇田高徳、平井正明、横谷尚睦、室隆桂之、為則雄祐
    • Organizer
      日本物理学会 2011年秋季大会
    • Place of Presentation
      富山大学五福キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] Preparation of NbO2 thin films using a pulsed laser deposition method2011

    • Author(s)
      Y. Muraoka, Y. Fujimoto, C. Hiramatsu, T. Wakita, M. Hirai, T. Yokoya
    • Organizer
      2011年秋季 第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] 低キャリア濃度で高Tcを示すホウ素ドープ超伝導ダイヤダイヤモンド膜の作製2011

    • Author(s)
      村岡祐治、土居智彰、平松千明、脇田高徳、平井正明、横谷尚睦、室隆桂之、泉雄大、為則雄祐
    • Organizer
      2011年秋季 第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] VO2薄膜における放射光照射効果2011

    • Author(s)
      村岡祐治、片山晋輔、長尾浩樹、脇田高徳、平井正明、横谷尚睦、室隆桂之、泉雄大、為則雄祐
    • Organizer
      応用物理学会中国四国支部、日本物理学会中国支部、四国支部、2011年度支部学術講演会
    • Place of Presentation
      鳥取大学鳥取キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] ホットフィラメントCVD法により作製したホウ素ドープダイヤモンド膜の超伝導特性2011

    • Author(s)
      村岡祐治、土居智彰、平松千明、脇田高徳、平井正明、横谷尚睦、室隆桂之、泉雄大、為則雄祐
    • Organizer
      応用物理学会中国四国支部、日本物理学会中国支部、四国支部、2011年度支部学術講演会
    • Place of Presentation
      鳥取大学鳥取キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] 尾嶋正治VO2薄膜の金属相フェルミ面ネスティング

    • Author(s)
      村岡祐治, 長尾浩樹, 脇田高徳, 横谷尚睦, 組頭広志
    • Organizer
      日本物理学会, 2013年秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス
    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://film.rlss.okayama-u.ac.jp/~hakumaku/

    • Related Report
      2013 Final Research Report
  • [Remarks] 岡山大学理学部附属界面科学研究施設 薄膜物性学部門

    • URL

      http://film.rlss.okayama-u.ac.jp/~hakumaku/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 岡山大学理学部附属界面科学研究施設 薄膜物性学部門

    • URL

      http://film.rlss.okayama-u.ac.jp/~hakumaku/

    • Related Report
      2012 Research-status Report

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Published: 2011-08-05   Modified: 2020-05-15  

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