Nuclear magnetic resonance study of highly concentrated metallic and semiconducting single-walled carbon nanotubes
Project/Area Number |
23540420
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Condensed matter physics II
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Research Institution | Kanagawa University |
Principal Investigator |
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Project Period (FY) |
2011 – 2013
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Project Status |
Completed (Fiscal Year 2013)
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Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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Keywords | カーボンナノチューブ / 核磁気共鳴 / 1次元系 / 1次元電子系 / 朝永-ラッティンジャー液体 |
Research Abstract |
Single-walled carbon nanotubes (SWCNTs) can be metallic or semiconducting, depending on their structural parameters. Up to now, nuclear magnetic resonance (NMR) studies have been performed on samples with bundles of mixtures of metallic and semiconducting SWCNTs. In this study, we have succeeded in observing the distinct 13C NMR spectra in the metallic and semiconducting SWCNT bundles prepared by density gradient ultracentrifugation technique. We found substantial differences in the observed spectra between the metallic and semiconducting SWCNTs. These were explained by difference contributions from Knight shift and current shift for metallic and semiconducting SWCNTs. Furthermore, we studied the mechanism for transformation of SWCNTs encapsulating C60 fullerene into double-walled CNTs.
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Report
(4 results)
Research Products
(33 results)
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[Journal Article] Confined water inside single-walled carbon nanotubes: Global phase diagram and effect of finite length2011
Author(s)
H. Kyakuno, K. Matsuda, H. Yahiro, Y. Inami, T. Fukuoka, Y. Miyata, K. Yanagi, Y. Maniwa, H. Kataura, T. Saito, M. Yumura, and S. Iijima
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Journal Title
J. Chem. Phys.
Volume: 134
Issue: 24
Pages: 244501-244514
DOI
Related Report
Peer Reviewed
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[Presentation] 水・カーボンナノチューブ複合体の比熱2014
Author(s)
市村遼太, 塚田諒, 芹田昇, 客野遥, 中井祐介, 宮田耕充, 松田和之, 斎藤毅, 真庭豊
Organizer
日本物理学会第69回年次大会
Place of Presentation
東海大学, 神奈川県
Year and Date
2014-03-28
Related Report
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