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Development and applications of spatial and temporal optimal control simulation with pulse propagation

Research Project

Project/Area Number 23550004
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

OHTSUKI Yukiyoshi  東北大学, 理学(系)研究科(研究院), 准教授 (40203848)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsコヒーレント制御 / レーザーパルス / 最適化 / パルス伝播 / 回転波束 / 偏光 / 量子干渉 / 同位体分離 / 分子配向 / 分子整列 / THzパルス / 最適制御
Research Abstract

We have developed control schemes that utilize Raman transitions, which can minimize undesirable effects due to absorption by using non-resonant laser pulses. Focusing on the rotational control, which is essential prior to molecular-fixed-frame experiments, we have proposed/developed the polarization control to align molecules in a specified direction, the molecular orientation control highly enhanced by alignment, isotope separation that utilize rotational wave packet motion, and pulse-amplitude/fluence-specified optimal control simulation algorithms. As an application of vibrational Raman transitions, quantum interference signals induced by strong laser pulses are also examined. We developed our own original codes to calculate pulse propagation, and clarified the effectiveness of the isotope separation after propagation when we use non-resonant laser pulses.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (26 results)

All 2014 2013 2012 2011 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (18 results) (of which Invited: 7 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Theoretical/numerical study on strong-laser-induced interference in the B state of I22014

    • Author(s)
      Y. Ohtsuki, H. Goto, H. Katsuki, K. Ohmori
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 16 Issue: 12 Pages: 5689-5697

    • DOI

      10.1039/c3cp54023e

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Optimal control simulation of field-free molecular orientation : Alignment-enhanced molecular orientation2012

    • Author(s)
      K. Nakajima, H. Abe, and Y. Ohtsuki
    • Journal Title

      J. Phys. Chem. A

      Volume: 116 Issue: 46 Pages: 11219-11227

    • DOI

      10.1021/jp3052054

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of nonresonant optimal control simulation to include polarization effects of laser pulses2012

    • Author(s)
      H. Abe and Y. Ohtsuki
    • Journal Title

      Chem. Phys

      Volume: 400 Pages: 13-13

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Development of nonresonant optimal control simulation to include polarization effects of laser pulses2012

    • Author(s)
      H. Abe and Y. Ohtsuki
    • Journal Title

      Chem. Phys.

      Volume: 400 Pages: 13-18

    • DOI

      10.1016/j.chemphys.2012.01.025

    • Related Report
      2012 Research-status Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Optimal control simulation with nonlinear interactions : A case study of molecular alignment/orientation as a prerequisite for attoscience2013

    • Author(s)
      Y. Ohtsuki
    • Organizer
      International Workshop on Attoscience: Challenges for Theoretical Research, POSCO International Center in POSTECH
    • Place of Presentation
      Pohang, Korea
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Optimal control simulation with nonlinear interactions: A case study of molecular alignment/orientation as a prerequisite for attoscience2013

    • Author(s)
      Y. Ohtsuki
    • Organizer
      International Workshop on Attoscience: Challenges for Theoretical Research
    • Place of Presentation
      POSCO International Center in POSTECH, Pohang, Korea
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Isotope-selective molecular alignment induced by optimally designed laser pulse2013

    • Author(s)
      Kaoru Nakashima, Yukiyoshi Ohtsuki, and Hirohiko Kono
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      Tohoku Univ. Sendai
    • Related Report
      2013 Annual Research Report
  • [Presentation] Numerical synthesis of microwave pulses for controlling KCs molecular qubits trapped in an optical lattice2013

    • Author(s)
      K. Arai, Y. Ohtsuki, and H. Kono
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      Tohoku Univ. Sendai
    • Related Report
      2013 Annual Research Report
  • [Presentation] 強レーザー誘起の量子干渉に関する理論・数値研究2013

    • Author(s)
      大槻幸義,後藤 悠,香月浩之,大森賢治
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都テルサ,京都市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Optimal control of molecular orientation by combining a femtosecond laser pulse with a THz pulse2013

    • Author(s)
      Masataka Yoshida, Kaoru Nakashima, Yukiyoshi Ohtsuki, Hirohiko Kono
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      Tohoku Univ. Sendai
    • Related Report
      2013 Annual Research Report
  • [Presentation] Optimal control study on quantum operations under the influence of dissipation, Symposium on Quantum Dissipation and Control2012

    • Author(s)
      Y. Ohtsuki
    • Organizer
      Weizmann Institute of Science
    • Place of Presentation
      Rehovot, Israel
    • Year and Date
      2012-07-11
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Optimal control study on quantum operations under the influence of dissipation2012

    • Author(s)
      Y. Ohtsuki
    • Organizer
      Symposium on Quantum Dissipation and Control
    • Place of Presentation
      Weizmann Institute of Science, Rehovot, Israel
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] レーザー誘起分子配向の最適制御シミュレーション:整列を経由する2段階の配向制御2012

    • Author(s)
      中嶋克宏,阿部弘哉,大槻幸義
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学本郷キャンパス,東京
    • Related Report
      2012 Research-status Report
  • [Presentation] アイソトポマー選択的なレーザー誘起分子整列の最適制御シミュレーション2012

    • Author(s)
      中島 薫,中嶋克宏,大槻幸義
    • Organizer
      平成24年度化学系学協会東北大会
    • Place of Presentation
      秋田大学手形キャンパス,秋田市
    • Related Report
      2012 Research-status Report
  • [Presentation] 同位体選択的なレーザー分子整列の最適化シミュレーション2012

    • Author(s)
      中島 薫,中嶋克宏,大槻幸義,河野裕彦
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学本郷キャンパス,東京
    • Related Report
      2012 Research-status Report
  • [Presentation] Optimal control approach for laser-induced molecular alignment/orientation2012

    • Author(s)
      Y. Ohtsuki
    • Organizer
      第25回光ナノサイエンスインフォーマルセミナー
    • Place of Presentation
      京都大学エネルギー理工学研究所,宇治市
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 超短レーザーパルスを用いた分子配向制御の最適制御シミュレーション2012

    • Author(s)
      中嶋克宏,阿部弘哉,大槻幸義
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] Path integral MD of quasi-free rotational motion of CO doped in a cluster2011

    • Author(s)
      Y. Ohtsuki
    • Organizer
      Matrix2011
    • Place of Presentation
      University of British Columbia, Vancouver, Canada
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Application of nonresonant optimal control simulation to molecular alignment / orientation2011

    • Author(s)
      Y. Ohtsuki
    • Organizer
      Gordon Research Conference "Quantum Control of Light and Matter"
    • Place of Presentation
      Mount Holyoke College, South Hadley, MA, USA
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Path integral MD of quasi-free rotational motion of CO doped in a cluster2011

    • Author(s)
      Y. Ohtsuki and Y. Mizumoto
    • Organizer
      Matrix 2011(招待講演)
    • Place of Presentation
      Univ. British Columbia,カナダ
    • Related Report
      2011 Research-status Report
  • [Presentation] Application of nonresonant optimal control simulation to molecular alignment/orientation2011

    • Author(s)
      Y. Ohtsuki
    • Organizer
      Gordon Research Conferences on Qauantum Control of Light and Matter(招待講演)
    • Place of Presentation
      Mt.Holyoke College,米国
    • Related Report
      2011 Research-status Report
  • [Presentation] 超短レーザーパルスを用いた分子整列・配向制御における周波数ネットワーク機構2011

    • Author(s)
      中嶋克宏,阿部弘哉,大槻幸義
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター
    • Related Report
      2011 Research-status Report
  • [Book] Laser control of ultrafast dynamics at conical intersections, (Chapter 14) in Conical Intersections: Theory, Computation and Experiment, Advanced Series in Physical Chemistry2011

    • Author(s)
      Y. Ohtsuki and W. Domcke
    • Publisher
      World Scientific, Singapore
    • Related Report
      2013 Final Research Report
  • [Book] Conical Intersections2011

    • Author(s)
      Y. Ohtsuki and W. Domcke
    • Publisher
      World Scientific
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.mcl.chem.tohoku.ac.jp/index-j.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 東北大学大学院理学研究科化学専攻 数理化学研究室

    • URL

      http://www.mcl.chem.tohoku.ac.jp/index-j.html

    • Related Report
      2012 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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