Spectroscopic study on the reactive transition-metal species developed by the chemical sputtering method at very low temperature
| Project/Area Number |
23550014
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Physical chemistry
|
|---|
| Research Institution | Shizuoka University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2011 – 2013
|
| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
|---|
| Keywords | 含遷移金属活性種 / 高分解能分光 / スパッタリング / 金属-硫黄間結合 / 金属ー硫黄間結合 / 金属－硫黄間結合 |
|---|
| Research Abstract |
Reactive transition-metal species, which were generated by the chemical sputtering method at very low temperature, were observed by millimeter-wave spectroscopy to reveal their physico-chemical properties. We mainly studied on the following species, (1) transition-metal monosulfides and monohydrosulfides as the first model for the thiorate-stabilized metal-nanocluster, (2) transition-metal monoacetilides as the simplest organometallics, (3) the group-10-metal monohalides as the simplest model for the single bond on the group-10-metalic catalyst. For these species, the physico-chemical properties, such as molecular structure, bond character, and unpaired electron distribution, were explored in detail.
|
Report
(4 results)
Research Products
(45 results)
