Orientational Ordering of Partially Deuterated Methanes and the Molecules with Partially Deuterated Methyl Groups in the Adsorbed Monolayers
| Project/Area Number |
23550015
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
INABA Akira 大阪大学, その他部局等, 名誉教授 (30135652)
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Keywords | 極低温精密熱測定 / 単分子吸着膜 / 重水素化 / 配向秩序化 |
|---|
| Research Abstract |
Heat capacity measurements were made for the monolayers of methane, methyl iodide, methanol, toluene, 4-methylpyridine, 2,6-dichlorotoluene, 2,6-dibromotoluene and their deuterated analogs, including the partially deuterated ones, in the temperature range from 0.7 K to 20 K. All the monolayers of the partially deuterated compounds showed a Schottky-type anomaly, indicating that the molecules (or methyl groups) are completely ordered in their orientation on the surface of graphite at such low temperatures. The results give some structural information that cannot be obtained from any structural/spectroscopic experiments.
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Report
(4 results)
Research Products
(70 results)
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[Journal Article] Bistable Multifunctionality and Switchable Strong Ferromagnetic-to-Anti ferromagnetic Coupling in a One-Dimen sional Rhodium(I)-Semiquinonato Complex2014
Author(s)
Mitsumi M., Nishitani T., Yamasaki S., Shimada N., Komatsu Y., Toriumi K., Kitagawa Y., Okumura M., Miyazaki Y., Gorska N., Inaba A., Kanda A., Hanasaki N
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Journal Title
J. Am. Chem. Soc
Volume: 136
Issue: 19
Pages: 7026-7037
DOI
Related Report
Peer Reviewed
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[Journal Article] Magnetic Systems at Criticality : Different Signatures of Scaling2013
Author(s)
Pelka R., Konieczny P., Fitta M., Czapla M., Zielinski P.M., Balanda M., Wasiutynski T., Miyazaki Y., Inaba A., Pinkowicz D., Sieklucka B
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Journal Title
Acta Phys. Polonica A
Volume: 124
Issue: 6
Pages: 977-989
DOI
Related Report
Peer Reviewed
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[Journal Article] (Nitronyl Nitroxide)- substituted Trioxytriphenylamine Radical Cation Tetrachlorogallate Salt: A 2p Electron-Based Weak Ferromagnet Composed of Triplet Diradical Cation2012
Author(s)
M. Kuratsu, S. Suzuki, M. Kozaki, D. Shiomi, K. Sato, T. Takui, T. Kanzawa, Y. Hosokoshi, X-Z. Lan, Y. Miyazaki, A. Inaba, K. Okada
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Journal Title
Chem. Asian. J.
Volume: 7
Issue: 7
Pages: 1604-1609
DOI
Related Report
Peer Reviewed
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[Journal Article] (Nitronyl Nitroxide)-Substituted Trioxytriphenylamine Radical Cation Tetrachlorogallate Salt: A 2p-Electron-Based Weak Ferromagnet Composed of a Triplet Diradical Cation2012
Author(s)
M. Kuratsu, S. Suzuki, M. Kozaki, D. Shiomi, K. Sato, T. Takui, T. Kanzawa, Y. Hosokoshi, X.-Z. Lan, Y. Miyazaki, A. Inaba, and K. Okada
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Journal Title
Chem. Asian J.
Volume: 7(7)
Pages: 1604-1609
Related Report
Peer Reviewed
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