Development of Novel Silicon-Silicon Bond Formation Reaction with Transition Metal Complexes
| Project/Area Number |
23550044
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | オリゴシラン / ヒドロシラン / 有機ケイ素クラスター / Grignard試薬 / 部分還元反応 / プッシュ-プル型化合物 / グリニャール試薬 |
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| Research Abstract |
The transition metal-catalyzed monoreduction of dichlorooligosianes with alkyl Grignard reagents proceeds with high selectivity to afford the corresponding chloro(hydro)oligosilanes in good yields. The satisfactory results were obtained from the reactions with the primary or secondary alkyl Grignard reagents, whereas that with the tertiary alkyl Grignard reagents proceed very sluggishly. Thus obtained chloro(hydro)oligosilanes were successfully introduced a variety of organic substituents by means of the corresponding organolithium or Grignard reagents. These results shows the importance of this method to supply the building blocks for organosilicon clusters.
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Report
(4 results)
Research Products
(45 results)
