Development of novel sulfuration reagents acting as a sulfur-atom donor
Project/Area Number |
23550045
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Organic chemistry
|
Research Institution | Saitama University |
Principal Investigator |
|
Project Period (FY) |
2011 – 2013
|
Project Status |
Completed (Fiscal Year 2013)
|
Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
|
Keywords | 硫化 / 一原子硫黄導入 / チイラン / ワンポット合成 / 固相チイラン化 / 水素結合 / 有機合成化学 / 有機典型元素化学 / 複素環化学 / 薬化学 |
Research Abstract |
Synthesis of sulfuration reagents acting as a sulfur-atom donor and their sulfuration ability were studied. As a result, we reveald that methoxycarbonylsulfenyl chloride is a suitable sulfur-atom donor for one-pot synthesis of thiiranes from alkenes, and hydrogen bonding of hydroxy groups in isolated silanols to reactants participates in solid-state thiiranation of alkenes with 3H-1,2-benzodithiole-3-one 1,1-dioxide and silica gel.
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Report
(4 results)
Research Products
(12 results)