| Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Outline of Final Research Achievements |
With the aim of achieving porous network, trisilanol PhSi(C6H4SiiPr2OH)3 and tetrasilanol Si(C6H4SiiPr2OH)4 were prepared. Trisilanol revealed the first example of a silanol hydrogen bonding cyclic trimer in crystalline, while treatment of tetrasilanol with Ti(NMe2)4 as well as SiCl4 resulted in formation of porous materials for N2 and H2 adsorption.
With the aim of achieving molecular capsule, 1,3,5-triethylbenzene-based trisilanols 1,2,3-Et3C6H3(CH2SiR2OH)3 and calix[4]arene-based tetrasilanols were prepared. As a result it is disclosed the encapsulation of H2O in the crystalline and halogen anions in solution states.
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