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Novel N-Containing pi-Conjugated Compounds: Synthesis, Physical Properties, and Functions

Research Project

Project/Area Number 23550062
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionKinki University

Principal Investigator

YAMAGUCHI Yoshihiro  近畿大学, 理工学部, 教授 (30200637)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords含窒素化合物 / π共役系 / 有機合成 / 物性 / 機能
Research Abstract

The creation of highly fluorescent materials should be an urgent and significant subject. For this purpose, we designed the novel pi-conjugated compounds having indro[3,2,1-jk]carbazole (IC) and 9,9'-diphenyl-4,4',5,5'-biscarbazole (DBC) as a framework, synthesized them, and elucidated their photophysical properties and functions.
We investigated the photophysical properties of synthesized compounds. As a result, the bathochromic shift of the fluorescence maximum and the increase of quantum yield in three IC derivatives were observed by comparison with those of IC in solution state. In solid state, although the further bathochromic shift of the fluorescence maximum of all IC derivatives were observed, the only one IC derivative showed the increase of quantum yield. On the other hand, neither of the bathochromic shift of the fluorescence maximum and the increase of quantum yield in two DBC derivatives were observed by comparison with those of DBC in solution and solid state.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (2 results)

All 2014

All Journal Article (2 results)

  • [Journal Article] 天然物有機化学者がなぜ有機発光体?2014

    • Author(s)
      山口仁宏
    • Journal Title

      化学(化学同人)

      Volume: 69巻, 2号 Pages: 32-37

    • Related Report
      2013 Final Research Report
  • [Journal Article] 天然物有機化学者がなぜ有機発光体?2014

    • Author(s)
      山口仁宏
    • Journal Title

      化学(化学同人)

      Volume: 69(2) Pages: 32-37

    • Related Report
      2013 Annual Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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