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Versatile structures of perovskite-type compounds containing rare-earth and their magnetic properties

Research Project

Project/Area Number 23550065
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionHokkaido University

Principal Investigator

HINATSU Yukio  北海道大学, 理学(系)研究科(研究院), 教授 (70271707)

Research Collaborator SAKASHITA Ryosuke  北海道大学, 大学院・理学院化学専攻, 修士課程
YAMAZAKI Takahiro  北海道大学, 大学院・理学院化学専攻, 修士課程
ENDO Takeshi  北海道大学, 大学院・理学院化学専攻, 博士課程
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords希土類 / ぺロブスカイト / 結晶構造 / 磁気的性質
Research Abstract

The perovskite-type compounds containing both rare earth and osmium Ba2LnOsO6 (Ln = Pr, Nd, Sm-Lu) have been prepared. Powder X-ray diffraction measurements and Rietveld analysis show that Ln3+ and Os5+ ions are structurally ordered at the M site of the perovskite BaMO3. Magnetic susceptibility and specific heat measurements show that an antiferromagnetic ordering of Os5+ ions has been observed for Ba2LnOsO6 (Ln = Pr, Nd, Sm, Eu, Lu) at 52-94 K. For Ba2TbOsO6 and Ba2YbOsO6, magnetic transitions due to the antiferromagnetic transition of the Tb3+ and Yb3+ are observed at 2.6 and 2.4 K, respectively. Neutron diffraction measurements for Ba2NdOsO6 show that the magnetic structure is of type I and the magnetic moments of Nd3+ and Os5+ ions are in the same direction in the ab-plane. Eu Mossbauer spectrum measurements show that the magnetic hyperfine field is 20 T.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (35 results)

All 2013 2012 2011 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (22 results) (of which Invited: 2 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Antiferromagnetic Transitions of Osmium-containing Rare Earth Double Perovskites Ba2LnOsO6 (Ln = Pr, Sm-Lu)2013

    • Author(s)
      Y. Hinatsu, Y. Doi and M. Wakeshima
    • Journal Title

      J. Solid State Chem.

      Volume: 206 Pages: 300-307

    • DOI

      10.1016/j.jssc.2013.08.020

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Physical Properties of Double Perovskite-type Barium Neodymium Osmate Ba2NdOsO62013

    • Author(s)
      M. Wakeshima, Y. Hinatsu and K. Ohoyama
    • Journal Title

      J. Solid State Chem.

      Volume: 197 Pages: 236-241

    • DOI

      10.1016/j.jssc.2012.08.059

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetic Properties and Structural Transitions of Fluorite-Related Osmates Ln3OsO7 (Ln = Pr, Tb)2013

    • Author(s)
      Y. Hinatsu and Y. Doi
    • Journal Title

      J. Solid State Chem.

      Volume: 198 Pages: 176-185

    • DOI

      10.1016/j.jssc.2012.09.039

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Giant Magnetoresistance Effect in the Metal - Insulator Transition of Pyrochlore Oxide Nd_2Ir_2O_72013

    • Author(s)
      K. Matsuhira, M. Tokunaga, M. Wakeshima, Y. Hinatsu, and S. Takagi
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 82 Issue: 2 Pages: 23706-23706

    • DOI

      10.7566/jpsj.82.023706

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystal Structures and Magnetic Properties of Lanthanide-containing Borates LnM(BO3)2 (Ln = Y, Ho-Lu; M = Sc, Cr)2013

    • Author(s)
      Y. Doi, T. Sato and Y. Hinatsu
    • Journal Title

      J. Solid State Chem.

      Volume: 206 Pages: 151-157

    • DOI

      10.1016/j.jssc.2013.08.015

    • NAID

      120005351801

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic order in the pyrochlore iridate Nd2Ir2O7 probed by muon spin relaxation2013

    • Author(s)
      H. Guo, K. Matsuhira, I. Kawasaki, M. Wakeshima, Y. Hinatsu, I. Watanabe, Z. Xu
    • Journal Title

      Physical Review B, Rapid Communication

      Volume: 88 Issue: 6 Pages: 60411-60411

    • DOI

      10.1103/physrevb.88.060411

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Defect-fluorite Oxides: Ln (Eu and Gd) Mössbauer Study Coupled with New Defect-crystal-chemistry Model2013

    • Author(s)
      A. Nakamura, N. Igawa, Y. Okamoto, J. Wang,Y. Hinatsu, M. Takahashi and M. Takeda
    • Journal Title

      Hyperfine Interactions (C)

      Volume: 217 Issue: 1-3 Pages: 17-26

    • DOI

      10.1007/s10751-012-0654-z

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic and Neutron Diffraction Study on Melilite-Type Oxides Sr_2MGe_2O_7 (M = Mn, Co)2012

    • Author(s)
      T. Endo, Y. Doi, Y. Hinatsu, and K. Ohoyama
    • Journal Title

      Inorg. Chem

      Volume: 51 Issue: 6 Pages: 3572-3578

    • DOI

      10.1021/ic202386h

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Emergence of Magnetic Long-range Order in Frustrated Pyrochlore Nd_2Ir_2O_7 with Metal-insulator Transitions2012

    • Author(s)
      K. Tomiyama, K. Matsuhira, K. Iwasa, M. Watahiki, S. Takagi, M. Wakeshima, Y. Hinatsu M. Yokoyama, K. Ohoyama and K. Yamada
    • Journal Title

      J. Phys. Soc. Japan

      Volume: 81

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Ordering of Divalent Europium in Double Perovskites Eu_2LnTaO_6 (Ln = Rare Earths). -Magnetic Interactions of Eu^<2+> Ions Determined by Magnetic Susceptibility, Specific Heat, and ^<151>Eu Mössbauer Spectrum Measurements2011

    • Author(s)
      T. Misawa, Y. Doi and Y. Hinatsu
    • Journal Title

      J. Solid State Chem

      Volume: 184 Issue: 6 Pages: 1478-1483

    • DOI

      10.1016/j.jssc.2011.04.017

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 四元系酸化物Ba_3LnFe_2O_<7.5>(Ln=希土類)の斜方晶‐単斜晶構造相転移とその磁気的性質2013

    • Author(s)
      坂下亮輔, 土井貴弘, 日夏幸雄
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      長野市
    • Year and Date
      2013-09-03
    • Related Report
      2013 Final Research Report
  • [Presentation] 層状化合物Na_2MnTeO_6 の結晶構造とその磁気的性質2013

    • Author(s)
      山崎貴裕, 土井貴弘, 日夏幸雄
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      長野市
    • Year and Date
      2013-09-03
    • Related Report
      2013 Final Research Report
  • [Presentation] Structures and Magnetic Properties of Quadruple Perovskites Ba_4LnM_3O_<12> (Ln = Rare Earths ; M = Ru, Ir)2013

    • Author(s)
      Y. Hinatsu, Y. Doi, and M. Wakeshima
    • Organizer
      14th European Conference on Solid State Chemistry
    • Place of Presentation
      ボルドー
    • Year and Date
      2013-07-07
    • Related Report
      2013 Final Research Report
  • [Presentation] 三元系希土類酸化物EuLn_2O_4(Ln=Gd-Lu)の結晶構造とその磁気的性質2013

    • Author(s)
      廣瀬慶一, 土井貴弘, 日夏幸雄
    • Organizer
      第30回希土類討論会
    • Place of Presentation
      北九州市
    • Year and Date
      2013-05-24
    • Related Report
      2013 Final Research Report
  • [Presentation] 希土類ケイ酸塩の磁気的性質2013

    • Author(s)
      分島亮, 日夏幸雄
    • Organizer
      第30回希土類討論会
    • Place of Presentation
      北九州市
    • Year and Date
      2013-05-24
    • Related Report
      2013 Final Research Report
  • [Presentation] 四元系酸化物Ba3LnFe2O7.5(Ln=希土類)の斜方晶‐単斜晶構造相転移とその磁気的性質2013

    • Author(s)
      坂下亮輔、土井貴弘、日夏幸雄
    • Organizer
      日本セラミックス協会2013年度秋季シンポジウム
    • Place of Presentation
      信州大学(長野市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 層状化合物Na2MnTeO6の構造とその磁気的性質2013

    • Author(s)
      山崎貴裕、土井貴弘、日夏幸雄
    • Organizer
      日本セラミックス協会2013年度秋季シンポジウム
    • Place of Presentation
      信州大学(長野市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 三元系希土類酸化物EuLn2O4(Ln=Gd-Lu)の結晶構造とその磁気的性質2013

    • Author(s)
      廣瀬慶一、土井貴弘、日夏幸雄
    • Organizer
      第30回希土類討論会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 希土類ケイ酸塩の磁気的性質2013

    • Author(s)
      分島亮、日夏幸雄
    • Organizer
      第30回希土類討論会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structures and magnetic properties of quadruple perovskites Ba4LnM3O12 (Ln=rare earths; M=Ru, Ir)2013

    • Author(s)
      Y. Hinatsu, Y. Doi, and M. Wakeshima
    • Organizer
      14th European Conference on Solid State Chemistry
    • Place of Presentation
      ボルドー大学(フランス)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 新規層状鉄オキシカルコゲナイドの結晶構造とその磁気的性質2013

    • Author(s)
      杉本陽慈 分島亮 日夏幸雄
    • Organizer
      第51回セラミックス基礎科学討論会
    • Place of Presentation
      仙台国際センター(仙台市)
    • Related Report
      2012 Research-status Report
  • [Presentation] 希土類含有無機化合物の多彩な構造とその磁気的性質2012

    • Author(s)
      日夏幸雄
    • Organizer
      日本セラミックス協会第46回基礎科学セミナー
    • Place of Presentation
      札幌市
    • Year and Date
      2012-07-26
    • Related Report
      2013 Final Research Report
  • [Presentation] 希土類含有無機化合物の多彩な構造とその磁気的性質の解明2012

    • Author(s)
      日夏幸雄
    • Organizer
      第29回希土類討論会
    • Place of Presentation
      札幌市
    • Year and Date
      2012-05-15
    • Related Report
      2013 Final Research Report
  • [Presentation] 希土類-遷移金属酸化物Ln3MO7 の磁気的性質と相転移2012

    • Author(s)
      日夏幸雄, 土井貴弘
    • Organizer
      セラミックス基礎科学討論会第50回記念大会
    • Place of Presentation
      東京都
    • Year and Date
      2012-01-12
    • Related Report
      2013 Final Research Report
  • [Presentation] 希土類無機化合物の多彩な構造とその磁気的性質の解明2012

    • Author(s)
      日夏幸雄
    • Organizer
      第29回希土類討論会
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 希土類含有無機化合物の多彩な構造とその磁気的性質2012

    • Author(s)
      日夏幸雄
    • Organizer
      日本セラミックス協会第46回基礎科学セミナー
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Structural Transitions and Magnetic Properties of Orthorhombic Fluorite-related Compounds Ln_3MO_7 (Ln = Rare Earths ; M = Transition Metals)2011

    • Author(s)
      Y. Hinatsu, Y. Doi, and M. Wakeshima
    • Organizer
      Terrae Rarae 2011
    • Place of Presentation
      カールスルーエ
    • Year and Date
      2011-10-11
    • Related Report
      2013 Final Research Report
  • [Presentation] トリプルペロブスカイトBa_3BiRu_2O_9 における相転移と電気, 磁気的性質2011

    • Author(s)
      福本清吾, 分島亮, 日夏幸雄
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      札幌市
    • Year and Date
      2011-09-09
    • Related Report
      2013 Final Research Report
  • [Presentation] 四元系希土類複合酸化物LnM_2Ge_4O_<12>(Ln=ランタノイド ; M=遷移金属)の新規合成とその結晶構造, 磁気的性質2011

    • Author(s)
      青柳遊大, 土井貴弘, 分島亮, 日夏幸雄
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      札幌市
    • Year and Date
      2011-09-09
    • Related Report
      2013 Final Research Report
  • [Presentation] Structural Transitions and Magnetic Properties of Orthorhombic Fluorite-related Compounds Ln3MO7 (Ln = Rare Earths, M = Transition Metals)2011

    • Author(s)
      Y. Hinatsu, Y. Doi and M. Wakeshima
    • Organizer
      Terrae Rarae 2011
    • Place of Presentation
      カールスルーエ工科大学(ドイツ)
    • Related Report
      2011 Research-status Report
  • [Presentation] トリプルペロブスカイトBa3BiRu2O9における相転移と電気、磁気的性質

    • Author(s)
      福本清吾、分島亮、日夏幸雄
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2011 Research-status Report
  • [Presentation] 四元系希土類複合酸化物LnM2Ge4O12(Ln = ランタノイド;M = 遷移金属)の新規合成とその結晶構造、磁気的性質

    • Author(s)
      青柳遊大、土井貴弘、日夏幸雄
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2011 Research-status Report
  • [Book] Mössbauer Spectroscopy : Applications in Chemistry, Biology, and Nanotechnology2013

    • Author(s)
      A. Nakamura, N. Igawa, Y. Okamoto, Y. Hinatsu, J. Wang, M. Takahashi and M. Takeda
    • Publisher
      John Wiley & Sons
    • Related Report
      2013 Final Research Report
  • [Book] Mossbauer Spectroscopy: Applications in Chemistry, Biology, and Nanotechnology2013

    • Author(s)
      A. Nakamura, N. Igawa, Y. Okamoto, Y. Hinatsu, J. Wang, M. Takahashi and M. Takeda
    • Total Pages
      631
    • Publisher
      John Wiley & Sons
    • Related Report
      2013 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://wwwchem.sci.hokudai.ac.jp/~inorg

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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