Developmet of Recyclable Cage-Type Phosphine Sulfide Complex Catalysts Storing Metal Center
| Project/Area Number |
23550068
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | University of Toyama |
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Principal Investigator |
AIZAWA Sen-ichi 富山大学, 大学院理工学研究部(工学), 教授 (60231099)
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| Co-Investigator(Kenkyū-buntansha) |
HORINO Yoshikazu 富山大学, 大学院・理工学研究部, 准教授 (30447651)
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | ホスフィンスルフィド / 炭素―炭素カップリング / 触媒 / リサイクル / かご型ホスフィン |
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| Research Abstract |
The purpose of this project is syntheses of the cage-type phosphine sulfide or oxide which can store the catalytically active metal in the cavity. The precursor ligands with protection groups were prepared and the deprotection is being carried out. Some dithiolato bridged dinuclear five-coordinate trigonal-bipyramidal Pd(II) complexes are ready for the template reaction by using Grubbs' catalyst to obtain the final products.
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Report
(4 results)
Research Products
(50 results)
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[Journal Article] Determination of α-hydroxy acids and their enantiomers in fruit juices by ligand exchange capillary electrophoresis with a dual central metal ion system2013
Author(s)
Kodama, S., Aizawa, S., Taga, A., Yamamoto, A., Honoda, Y., Suzuki, K., Kemmei, T., Hayakawa, K
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Journal Title
Electrophoresis
Volume: 34
Pages: 1327-1333
Related Report
Peer Reviewed
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[Journal Article] Enantioseparation of α-Hydroxy Acids by Chiral Ligand Exchange CE with a Dual Central Metal Ion System2012
Author(s)
Kodama, S., Yamamoto, A., Aizawa, S., Honda, Y., Suzuki, K., Kemmei, T., Taga, A
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Journal Title
Electrophoresis
Volume: 33(18)
Pages: 2920-2924
Related Report
Peer Reviewed
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[Journal Article] Direct Enantioseparation of Lipoic Acid in Dietary Supplements by Capillary Electrophoresis using Trimethyl-β-Cyclodextrin as a Chiral Selector2012
Author(s)
Kodama, S., Taga, A., Aizawa, S., Kemmei, T., Honda, Y., Suzuki, K., Yamamoto, A
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Journal Title
Electrophoresis
Volume: 33(15)
Pages: 2441-2445
Related Report
Peer Reviewed
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[Presentation] Enantioseparation of Galactose by Ligand-Exchange Capillary Electrophoresis Using Borate as a Central Ion of the Chiral Selector2011
Author(s)
Kodama, S., Aizawa, S., Taga, A., Suzuki, K., Honda, Y., Kemmei, T., Yamashita, T., Kamide, I., Yamamoto, A
Organizer
International Congress on Analytical Science 2011
Place of Presentation
Kyoto
Related Report
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