| Project/Area Number |
23550070
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kanazawa University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
SATO Wataru 金沢大学, 理工研究域物質化学系, 准教授 (90333319)
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| Co-Investigator(Renkei-kenkyūsha) |
TSUKADA Kazuaki 日本原子力機構, 先端基礎研究センター, サブリーダー (30343916)
HABA Hiromitsu 理化学研究所, 森田超重元素研究室, 専任研究員 (60360624)
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
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| Keywords | 超重元素 / 抽出クロマトグラフィー / ラザホージウム / 液液抽出 / 液液平衡 |
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| Research Abstract |
In order to elucidate relevant chemical species of Rf by means of reversed-phase extraction chromatography with 2-thenoyltrifluoroacetone (TTA) as a stationary phase, we measured the equilibration time and distribution ratios in extraction by batch method experiments with carrier-free radiotracers of Zr and Hf on TTA-resin in the HF/HNO3 solutions and optimized an appropriate experimental condition for Rf. An online experiment has been also performed for the reversed-phase chromatographic behaviors of Zr and Hf on the TTA resin to simulate the Rf experiments. The elution curves from columns with the resin in the on-line experiment using Zr and Hf short-lived isotopes were obtained to show the effective adsorption with TTA although the equilibrium has not been attained, yet. The Rf atoms appears to be adsorbed to TTA in the on-line experiment with Rf, but the analysis is still on the way to deriving conclusive results.
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