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Efficient syntheses and functions of highly self-assembled metallamacrocycles

Research Project

Project/Area Number 23550085
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionKinki University

Principal Investigator

MAEKAWA Masahiko  近畿大学, 理工学総合研究所, 教授 (70229293)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
KeywordsCu(I)錯体 / エチレン付加体 / 配位高分子 / メタラマクロサイクリック / アニオンレセプター / 自己組織化 / 分子認識 / アニオンテンプレート / 銅錯体 / アニオン / X線構造解析 / 窒素配位子
Research Abstract

The C2H4 and CO adducts of novel Cu(I) coordination polymers and metallamacrocycles were self-assembled by the combinations of precursor Cu(I) complexes with different counter anions and the related 4,4'-bipyrimidine ligands. The roles of counter anions and reaction solvents were systematically proved in the formation processes. These new compounds are expected to become as a potential anion receptor. In addition, polymeric Cu(I)-{C2H4, CO} adducts should be contributed to study the chemical adsorption and the catalytic reaction sites.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (39 results)

All 2014 2013 2012 2011 Other

All Journal Article (12 results) (of which Peer Reviewed: 6 results) Presentation (24 results) Remarks (3 results)

  • [Journal Article] The first copper(I) coordination polymers selfassembled by 4, 4'-biquinazoline2014

    • Author(s)
      M. Maekawa, A. Minamino, K. Sugimoto, T. Okubo, T. Kuroda- Sowa and M. Munakata
    • Journal Title

      Inorg. Chim. Acta

      Volume: 414 Pages: 257-263

    • Related Report
      2013 Final Research Report
  • [Journal Article] Preparations and structural diversity of copper(I) ethylene adducts with related 3, 6-bis(2- pyridyl)-1, 2, 4, 5-tetrazine ligands2014

    • Author(s)
      M. Maekawa, T. Miyazaki, K. Sugimoto, T. Okubo, T. Kuroda- Sowa, M. Munakata and S. Kitagawa
    • Journal Title

      Inorg. Chim. Acta

      Volume: 410 Pages: 46-53

    • Related Report
      2013 Final Research Report
  • [Journal Article] Preparations and structural diversity of copper(I) ethylene adducts with related 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine ligands2014

    • Author(s)
      M. Maekawa, T. Miyazaki, K. Sugimoto, T. Okubo, T. Kuroda-Sowa, M. Munakata and S. Kitagawa
    • Journal Title

      Inorg. Chim. Acta.

      Volume: 410 Pages: 46-53

    • DOI

      10.1016/j.ica.2013.10.015

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The first copper(I) coordination polymers self-assembled by 4,4'-biquinazoline2014

    • Author(s)
      M. Maekawa, A. Minamino, K. Sugimoto, T. Okubo, T. Kuroda-Sowa and M. Munakata
    • Journal Title

      Inorg. Chim. Acta.

      Volume: 414 Pages: 257-263

    • DOI

      10.1016/j.ica.2014.02.016

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural diversity among copper(I) ethylene adducts of 3, 6-bis(2-pyridyl)-1, 2, 4, 5-tetrazine2013

    • Author(s)
      M. Maekawa, T. Miyazaki, K. Sugimoto, T. Okubo, T. Kuroda-Sowa, M. Munakata and S. Kitagawa
    • Journal Title

      Dalton Trans

      Volume: 42 Pages: 4258-4266

    • Related Report
      2013 Final Research Report
  • [Journal Article] Structural diversity among copper(I) ethylene adducts of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine2013

    • Author(s)
      M. Maekawa, T. Miyazaki, K. Sugimoto, T. Okubo, T. Kuroda-Sowa, M. Munakata and S. Kitagawa
    • Journal Title

      Dalton Trans.

      Volume: 42 (12) Issue: 12 Pages: 4258-4266

    • DOI

      10.1039/c2dt32649c

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural controls of 2-D sheet copper(I) ethylene and carbonyl coordination polymers directed by anions and solvents2012

    • Author(s)
      M. Maekawa, T. Tominaga, K. Sugimoto, T. Okubo, T. Kuroda- Sowa, M. Munakata and S. Kitagawa
    • Journal Title

      CrystEngComm

      Volume: 14 Pages: 5955-5962

    • Related Report
      2013 Final Research Report
  • [Journal Article] Syntheses, crystal structures, spectroscopic characterization and unusual thermal robustness of mono- and dinuclear Iridium(III) hydride complexes of 2, 2'-bipyrimidine2012

    • Author(s)
      M. Maekawa, Y. Kubo, K. Sugimoto, T. Minematsu, T. Okubo, T. Kuroda-Sowa and M. Munakata
    • Journal Title

      Polyhedron

      Volume: 40 Pages: 145-152

    • Related Report
      2013 Final Research Report
  • [Journal Article] Framework dimensionality of copper(I) coordination polymers of 4, 4'-bipyrimidine controlled by anions and solvents2012

    • Author(s)
      M. Maekawa, T. Tominaga, K. Sugimoto, T. Okubo, T. Kuroda- Sowa, M. Munakata and S. Kitagawa
    • Journal Title

      CrystEngComm

      Volume: 14 Pages: 1345-1353

    • Related Report
      2013 Final Research Report
  • [Journal Article] Syntheses, crystal structures, spectroscopic characterization and unusual thermal robustness of mono- and dinuclear Iridium(III) hydride complexes of 2,2'-bipyrimidine2012

    • Author(s)
      M. Maekawa, Y. Kubo, K. Sugimoto, T. Minematsu, T. Okubo, T. Kuroda-Sowa and M. Munakata
    • Journal Title

      Polyhedron

      Volume: 40 (1) Issue: 1 Pages: 145-152

    • DOI

      10.1016/j.poly.2012.04.011

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural controls of 2-D sheet copper(I) ethylene and carbonyl coordination polymers directed by anions and solvents2012

    • Author(s)
      M. Maekawa, T. Tominaga, K. Sugimoto, T. Okubo, T. Kuroda-Sowa, M. Munakata and S. Kitagawa
    • Journal Title

      CrystEngComm

      Volume: 14 (18) Issue: 18 Pages: 5955-5962

    • DOI

      10.1039/c2ce25211b

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Framework dimensionality of copper(I) coordination polymers of 4,4’-bipyrimidine controlled by anions and solvents2012

    • Author(s)
      M. Maekawa, 他6名
    • Journal Title

      CrystEngComm

      Volume: 14 Issue: 4 Pages: 1345-1353

    • DOI

      10.1039/c1ce06328f

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 新規なヘテロ金属Ag(I)-Ir(III)ヒドリド配位高分子の合成および構造, (近畿大理工総研・近畿大理工)2013

    • Author(s)
      前川雅彦・久保有希実・大久保貴志・黒田孝義・宗像 恵
    • Organizer
      第63回錯体化学討論会
    • Place of Presentation
      那覇(琉球大学千原キャンパス)
    • Related Report
      2013 Final Research Report
  • [Presentation] 新規なヘテロ金属Ag(I)-Ir(III)ヒドリド配位高分子の合成および構造2013

    • Author(s)
      前川雅彦,久保有希実,大久保貴志,黒田孝義,宗像 恵
    • Organizer
      第63回錯体化学討論会
    • Place of Presentation
      那覇(琉球大学千原キャンパス)
    • Related Report
      2013 Annual Research Report
  • [Presentation] First Cu(I) coordination polymers of 4, 4'- biquinazoline and the C_2H_4 adduct2012

    • Author(s)
      A. Minamino, M. Maekawa, T. Okubo, T. Kuroda-Sowa, M. Munakata
    • Organizer
      The 40th International Conference on Coordination Chemistry (ICCC40)
    • Place of Presentation
      Valencia, Spain
    • Related Report
      2013 Final Research Report
  • [Presentation] Structural controls of Cu(I) C_2H_4 coordination polymers of 4, 4'-bipyrimidine2012

    • Author(s)
      M. Maekawa, K. Sugimoto, T. Okubo, T. Kuroda-Sowa, M. Munakata, S. Kitagawa
    • Organizer
      The 40th International Conference on Coordination Chemistry (ICCC40)
    • Place of Presentation
      Valencia, Spain
    • Related Report
      2013 Final Research Report
  • [Presentation] Novel mono- and dinuclear Iridium(III) hydride complexes of 2, 2'-bipyrimidine2012

    • Author(s)
      Y. Kubo, M. Maekawa, T. Okubo, T. Kuroda-Sowa, M. Munakata
    • Organizer
      The 40th International Conference on Coordination Chemistry (ICCC40)
    • Place of Presentation
      Valencia, Spain
    • Related Report
      2013 Final Research Report
  • [Presentation] Ir(III)ヒドリド錯体を連結した新規な一次元Ir(III)-Ag(I)配位高分子の合成および構造, (近畿大理工総研・近畿大理工)2012

    • Author(s)
      久保有希実・前川雅彦・大久保貴志・黒田孝義・宗像 恵
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山(富山大学五福キャンパス)
    • Related Report
      2013 Final Research Report
  • [Presentation] 多座窒素配位子を有する新規なCu(I)-エチレン錯体の合成, 構造および性質, (近畿大理工総研・近畿大理工)2012

    • Author(s)
      南野 愛・前川雅彦・大久保貴志・黒田孝義・宗像 恵
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山(富山大学五福キャンパス)
    • Related Report
      2013 Final Research Report
  • [Presentation] 多座窒素配位子を有する新規なIr(III)ヒドリド錯体の合成, 構造および性質, (近畿大理工総研・近畿大理工)2012

    • Author(s)
      久保有希実・前川雅彦・大久保貴志・黒田孝義・宗像 惠
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜(慶應大学日吉キャンパス)
    • Related Report
      2013 Final Research Report
  • [Presentation] 多座窒素配位子を用いた新規なCu(I)-エチレン錯体の合成, 構造および性質, (近畿大理工総研・近畿大理工)2012

    • Author(s)
      南野 愛・前川雅彦・大久保貴志・黒田孝義・宗像 惠
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜(慶應大学日吉キャンパス)
    • Related Report
      2013 Final Research Report
  • [Presentation] 3, 6-ビス(2-ピリジル)-1, 2, 4, 5-テトラジンを配位子とする様々なCu(I)-エチレン錯体の合成および構造, (近畿大理工総研・近畿大理工)2012

    • Author(s)
      前川雅彦・宮崎武志・大久保貴志・黒田孝義・宗像 惠
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜(慶應大学日吉キャンパス)
    • Related Report
      2013 Final Research Report
  • [Presentation] 3,6-ビス(2-ピリジル)-1,2,4,5-テトラジンを配位子とする様々なCu(I)-エチレン錯体の合成および構造2012

    • Author(s)
      前川雅彦,宮崎武志,大久保貴志,黒田孝義,宗像 惠
    • Organizer
      日本化学会第92春季年会(2012)
    • Place of Presentation
      慶應大学日吉キャンパス(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 多座窒素配位子を用いた新規なCu(I)-エチレン錯体の合成,構造および性質2012

    • Author(s)
      南野 愛,前川雅彦,大久保貴志,黒田孝義,宗像 惠
    • Organizer
      日本化学会第92春季年会(2012)
    • Place of Presentation
      慶應大学日吉キャンパス(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 多座窒素配位子を有する新規なIr(III)ヒドリド錯体の合成,構造および性質2012

    • Author(s)
      久保有希実,前川雅彦,大久保貴志,黒田孝義,宗像 惠
    • Organizer
      日本化学会第92春季年会(2012)
    • Place of Presentation
      慶應大学日吉キャンパス(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] Novel mono- and dinuclear Iridium(III) hydride complexes of 2,2’-bipyrimidine2012

    • Author(s)
      Y. Kubo, M. Maekawa, T. Okubo, T. Kuroda-Sowa, M. Munakata
    • Organizer
      The 40th International Conference on Coordination Chemistry (ICCC40)
    • Place of Presentation
      バレンシア国際会議場, Valencia, Spain
    • Related Report
      2012 Research-status Report
  • [Presentation] Structural controls of Cu(I) C2H4 coordination polymers of 4,4’-bipyrimidine2012

    • Author(s)
      M. Maekawa, K. Sugimoto, T. Okubo, T. Kuroda-Sowa, M. Munakata, S. Kitagawa
    • Organizer
      The 40th International Conference on Coordination Chemistry (ICCC40)
    • Place of Presentation
      バレンシア国際会議場, Valencia, Spain
    • Related Report
      2012 Research-status Report
  • [Presentation] First Cu(I) coordination polymers of 4,4’-biquinazoline and the C2H4 adduct2012

    • Author(s)
      A. Minamino, M. Maekawa, T. Okubo, T. Kuroda-Sowa, M. Munakata
    • Organizer
      The 40th International Conference on Coordination Chemistry (ICCC40)
    • Place of Presentation
      バレンシア国際会議場, Valencia, Spain
    • Related Report
      2012 Research-status Report
  • [Presentation] 多座窒素配位子を有する新規なCu(I)-エチレン錯体の合成,構造および性質2012

    • Author(s)
      南野 愛,前川 雅彦,大久保 貴志,黒田 孝義,宗像 恵
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山大学五福キャンパス(富山県)
    • Related Report
      2012 Research-status Report
  • [Presentation] Ir(III)ヒドリド錯体を連結した新規な一次元Ir(III)-Ag(I)配位高分子の合成および構造2012

    • Author(s)
      久保 有希実,前川 雅彦,大久保 貴志,黒田 孝義,宗像 恵
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山大学五福キャンパス(富山県)
    • Related Report
      2012 Research-status Report
  • [Presentation] ビピリミジン系多座窒素配位子を有する新規なイリジウム(III)ヒドリド錯体の合成と構造化学的特徴付け, (近畿大理工総研・近畿大理工)2011

    • Author(s)
      久保有希実・前川雅彦・大久保貴志・宗像 惠・黒田孝義
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山(岡山理科大学)
    • Related Report
      2013 Final Research Report
  • [Presentation] アニオンおよび溶媒に導かれた4, 4'-ビピリミジン類を配位子とする新規なCu(I)配位高分子の自己組織化, (近畿大理工総研・近畿大理工)2011

    • Author(s)
      南野 愛・前川雅彦・大久保貴志・宗像惠・黒田孝義
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山(岡山理科大学)
    • Related Report
      2013 Final Research Report
  • [Presentation] アニオンラジカルを配位子とする始めてのCu(I)-エチレン錯体の合成, 構造およびキャタクタリゼーション, (近畿大理工総研・近畿大理工)2011

    • Author(s)
      宮崎武志・前川雅彦・大久保貴志・宗像 惠・黒田孝義
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山(岡山理科大学)
    • Related Report
      2013 Final Research Report
  • [Presentation] ビピリミジン系多座窒素配位子を有する新規なイリジウム(III)ヒドリド錯体の合成と構造化学的特徴付け2011

    • Author(s)
      久保有希実、前川雅彦 他3名
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学(岡山)
    • Related Report
      2011 Research-status Report
  • [Presentation] アニオンおよび溶媒に導かれた4,4'-ビピリミジン類を配位子とする新規なCu(I)配位高分子の自己組織化2011

    • Author(s)
      南野 愛、前川雅彦 他3名
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学(岡山)
    • Related Report
      2011 Research-status Report
  • [Presentation] アニオンラジカルを配位子とする始めてのCu(I)-エチレン錯体の合成、構造およびキャタクタリゼーション2011

    • Author(s)
      宮崎 武志、前川雅彦 他3名
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学(岡山)
    • Related Report
      2011 Research-status Report
  • [Remarks] 近畿大学学術情報リポジトリ

    • URL

      http://kurepo.clib.kindai.ac.jp/modules/news/

    • Related Report
      2013 Final Research Report
  • [Remarks] Reaserchmap

    • URL

      http://researchmap.jp/read0159536/

    • Related Report
      2013 Final Research Report
  • [Remarks] researchmap

    • URL

      http://researchmap.jp/read0159536/

    • Related Report
      2013 Annual Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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