| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
|
|---|
| Research Abstract |
The C2H4 and CO adducts of novel Cu(I) coordination polymers and metallamacrocycles were self-assembled by the combinations of precursor Cu(I) complexes with different counter anions and the related 4,4'-bipyrimidine ligands. The roles of counter anions and reaction solvents were systematically proved in the formation processes. These new compounds are expected to become as a potential anion receptor. In addition, polymeric Cu(I)-{C2H4, CO} adducts should be contributed to study the chemical adsorption and the catalytic reaction sites.
|
