Efficient syntheses and functions of highly self-assembled metallamacrocycles
Project/Area Number |
23550085
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Inorganic chemistry
|
Research Institution | Kinki University |
Principal Investigator |
|
Project Period (FY) |
2011 – 2013
|
Project Status |
Completed (Fiscal Year 2013)
|
Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
|
Keywords | Cu(I)錯体 / エチレン付加体 / 配位高分子 / メタラマクロサイクリック / アニオンレセプター / 自己組織化 / 分子認識 / アニオンテンプレート / 銅錯体 / アニオン / X線構造解析 / 窒素配位子 |
Research Abstract |
The C2H4 and CO adducts of novel Cu(I) coordination polymers and metallamacrocycles were self-assembled by the combinations of precursor Cu(I) complexes with different counter anions and the related 4,4'-bipyrimidine ligands. The roles of counter anions and reaction solvents were systematically proved in the formation processes. These new compounds are expected to become as a potential anion receptor. In addition, polymeric Cu(I)-{C2H4, CO} adducts should be contributed to study the chemical adsorption and the catalytic reaction sites.
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Report
(4 results)
Research Products
(39 results)