Strict Reactivity Control of High-Valent Manganese-Oxo Complexes
| Project/Area Number |
23550086
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Institute for Molecular Science |
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Principal Investigator |
KURAHASHI Takuya 分子科学研究所, 生命・錯体分子科学研究領域, 助教 (90353432)
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| Project Period (FY) |
2011-04-28 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | 酸化反応 / 高原子価金属オキソ / サレン錯体 / ラジカル / 錯体化学 / 高原子価金属オキソ錯体 / サレンマンガン錯体 / ジオキソ架橋２核錯体 / マンガン(IV) / 酸化触媒反応 / ヨードシルアレーン / エナンチオ選択的エポキシ化 / 電子状態 / 酸化剤付加錯体 / 高原子価マンガンオキソ / フェノキシラジカル / 混合原子価錯体 / 電子移動 |
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| Outline of Final Research Achievements |
Oxidation reactions are widely utilized for production of chemicals and degradation of pollutants and so on. Although in most cases, it is required to oxidize only a certain position in a molecule, it is not necessarily an easy task to strictly control the selectivity of oxidation reactions. Here, the author focused on a catalyst molecule that is utilized to promote oxidation reactions, and investigated the redox properties of the catalyst molecule. The present study has shown that redox reactions readily occur on the organic moiety of the catalyst, which was previously thought to be inert for redox reactions, in addition to the transition-metal ion.
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Report
(5 results)
Research Products
(16 results)
